ITTO20120897A1 - MALTA FOR FILLING ROAD TRAINS. - Google Patents
MALTA FOR FILLING ROAD TRAINS. Download PDFInfo
- Publication number
- ITTO20120897A1 ITTO20120897A1 IT000897A ITTO20120897A ITTO20120897A1 IT TO20120897 A1 ITTO20120897 A1 IT TO20120897A1 IT 000897 A IT000897 A IT 000897A IT TO20120897 A ITTO20120897 A IT TO20120897A IT TO20120897 A1 ITTO20120897 A1 IT TO20120897A1
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- Prior art keywords
- binder
- overall content
- content
- blend according
- mixture
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims description 24
- 239000011230 binding agent Substances 0.000 claims description 17
- 239000004570 mortar (masonry) Substances 0.000 claims description 12
- 238000001218 confocal laser scanning microscopy Methods 0.000 claims description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000012615 aggregate Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 229910052925 anhydrite Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 235000010216 calcium carbonate Nutrition 0.000 claims description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 2
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000010881 fly ash Substances 0.000 claims description 2
- 229910052602 gypsum Inorganic materials 0.000 claims description 2
- 239000010440 gypsum Substances 0.000 claims description 2
- 229910003002 lithium salt Inorganic materials 0.000 claims description 2
- 159000000002 lithium salts Chemical class 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 230000007774 longterm Effects 0.000 description 5
- 239000004568 cement Substances 0.000 description 4
- 238000009412 basement excavation Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000007847 structural defect Effects 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
- C04B28/065—Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00663—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
- C04B2111/00706—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like around pipelines or the like
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/10—Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
Description
"Malta per riempimento di trincee stradali" "Mortar for filling road trenches"
DESCRIZIONE DESCRIPTION
La presente invenzione si riferisce ad una miscela per malta CLSM, in particolare per il riempimento di trincee stradali. The present invention refers to a mixture for CLSM mortar, in particular for filling road trenches.
Nella letteratura tecnica internazionale, l’acronimo CLSM sta per Controlled Low Strength Materials, ed à ̈ in particolare utilizzato con riferimento a malte cementizie a resistenza controllata con basso contenuto di legante ed elevata porosità , il cui impiego principale à ̈ la sostituzione di terre e misti granulari nel riempimento delle trincee stradali in cui si posano sottoservizi quali cavidotti, acquedotti, fognature. Più recentemente, le malte CLSM sono state anche impiegate nei riempimenti massivi per opere strutturali, quali i muri di contenimento, le spalle da ponte e le fondazioni superficiali. In international technical literature, the acronym CLSM stands for Controlled Low Strength Materials, and is in particular used with reference to controlled-strength cement mortars with low binder content and high porosity, whose main use is the replacement of earth and mixed granules in the filling of road trenches in which underground utilities such as cable ducts, aqueducts, sewers are laid. More recently, CLSM mortars have also been used in massive fillings for structural works, such as retaining walls, bridge abutments and surface foundations.
È noto che i materiali granulari tradizionali sono soggetti a generare cedimenti differenziali sia rispetto agli ammassi stabili presenti nell’intorno, sia nel corso del tempo complicando le operazioni di posa e allungando i tempi generali della lavorazione. Ciò si deve alla oggettiva difficoltà di costipare tali materiali in trincee e scavi di dimensione ridotte rispetto alle superfici su cui sono in grado di operare i mezzi di costipamento. Viceversa, in fase di posa le malte CLSM riempiono completamente lo scavo poiché fluide e non richiedono alcun costipamento. Inoltre, subito dopo la loro posa in opera, induriscono velocemente acquisendo quelle resistenze e rigidezze che consentono l’immediato completamento delle successive operazioni costruttive. It is known that traditional granular materials are subject to generating differential settlements both with respect to the stable masses present in the surroundings, and over time, complicating the laying operations and lengthening the general processing times. This is due to the objective difficulty of compacting these materials in trenches and excavations of reduced size compared to the surfaces on which the compacting vehicles are able to operate. Vice versa, during the laying phase, the CLSM mortars completely fill the excavation as they are fluid and do not require any tamping. Furthermore, immediately after their installation, they harden quickly acquiring those strengths and stiffnesses that allow the immediate completion of the subsequent construction operations.
Tuttavia, le malte CLSM finora utilizzate presentano alcuni svantaggi che ne hanno condizionato la diffusione, ovvero: (a) scarso sviluppo delle resistenze a breve scadenza (1-2 giorni dopo il getto); (b) rigidezze e resistenze a lungo termine eccessive legate all’indurimento progressivo dovuto alla continua idratazione del cemento nel tempo. However, the CLSM mortars used up to now have some disadvantages that have affected their diffusion, namely: (a) poor development of short-term strengths (1-2 days after casting); (b) excessive long-term stiffness and strength due to progressive hardening due to the continuous hydration of the cement over time.
Nel lungo termine, infatti, si creano disomogeneità strutturali tra la malta CLSM all’interno della trincea e il materiale naturale che si trova nel suo intorno, alle quali si associano differenze di permeabilità e di conducibilità termica che possono portare alla formazione di difetti strutturali nelle opere. Inoltre l’eccessiva resistenza meccanica e rigidezza sviluppata nel tempo rende complessa la rimozione con i tradizionali macchinari da scavo, e rende necessario il ricorso ad attrezzature da scasso, quali martelli pneumatici e simili. In the long term, in fact, structural inhomogeneities are created between the CLSM mortar inside the trench and the natural material that is around it, which are associated with differences in permeability and thermal conductivity that can lead to the formation of structural defects in the works. Furthermore, the excessive mechanical strength and stiffness developed over time makes removal with traditional excavation machinery difficult, and makes it necessary to use burglary equipment, such as pneumatic hammers and the like.
Scopo della presente invenzione à ̈ dunque quello di ovviare agli inconvenienti sopra evidenziati della tecnica nota. The aim of the present invention is therefore to obviate the drawbacks highlighted above in the known art.
Secondo l’invenzione, tale scopo viene raggiunto grazie ad una miscela per malta CLSM comprendente acqua, aggregato e legante il quale à ̈ presente in quantità inferiore a 200 kg/m<3>, in cui detto legante à ̈ di tipo solfoalluminato ed ha un contenuto di C4A3S compreso tra 30 e 70% ed un contenuto globale di gesso, anidrite e solfato di calcio emidrato < 20%. According to the invention, this purpose is achieved thanks to a mixture for mortar CLSM comprising water, aggregate and binder which is present in quantities less than 200 kg / m <3>, in which said binder is of the sulphoaluminate type and it has a C4A3S content between 30 and 70% and an overall content of gypsum, anhydrite and calcium sulphate hemihydrate <20%.
Una tale miscela risulta di impiego particolarmente vantaggioso poiché à ̈ caratterizzata da rapidità nello sviluppo di resistenze a breve termine e scarso incremento a lungo termine di tali resistenze. Such a mixture is of particularly advantageous use since it is characterized by rapidity in the development of short-term resistances and a low long-term increase of such resistances.
Vantaggiosamente, il legante impiegato in una composizione dell’invenzione soddisfa una o più delle seguenti condizioni: Advantageously, the binder used in a composition of the invention satisfies one or more of the following conditions:
- un contenuto di C2S < 50%, preferibilmente pari a 20%; - a C2S content <50%, preferably equal to 20%;
- un contenuto globale di C4AF, CaO, MgO, C2AS e C5S2S < 15%, preferibilmente < 5%; - an overall content of C4AF, CaO, MgO, C2AS and C5S2S <15%, preferably <5%;
- un contenuto globale di CaCO3e MgCO3< 20%, preferibilmente 0%; - an overall content of CaCO3 and MgCO3 <20%, preferably 0%;
- un contenuto globale di pozzolana, loppa e ceneri volanti < 50%, preferibilmente 0%; - an overall content of pozzolan, slag and fly ash <50%, preferably 0%;
- un contenuto globale di acidi organici <1,5%, preferibilmente 0,5%; e - an overall content of organic acids <1.5%, preferably 0.5%; And
- un contenuto globale di sali di litio <0,5%, preferibilmente 0%. - an overall content of lithium salts <0.5%, preferably 0%.
Preferibilmente, una miscela secondo l’invenzione comprende: Preferably, a mixture according to the invention comprises:
- legante solfoalluminato in quantità compresa tra 50 e 200 kg/m<3>, - sulphoaluminate binder in quantities between 50 and 200 kg / m <3>,
- aggregato in quantità compresa tra 1200 e 1800 kg/m<3>, - aggregate in a quantity between 1200 and 1800 kg / m <3>,
- acqua in quantità compresa tra 200 e 400 kg/m<3>, e - additivo aerante in quantità compresa tra 0,1 e 1 kg/m<3>. - water in a quantity between 200 and 400 kg / m <3>, and - aerating additive in a quantity between 0.1 and 1 kg / m <3>.
Tale miscela può inoltre comprendere un filler in una quantità fino a 500 kg/m<3>. This mixture can also include a filler in an amount up to 500 kg / m <3>.
Esempi di realizzazione dell’invenzione vengono ora forniti a titolo meramente illustrativo e non limitativo con l’ausilio del disegno allegato in cui: Examples of realization of the invention are now provided for illustrative and non-limiting purposes with the aid of the attached drawing in which:
la figura unica à ̈ un diagramma che illustra lo sviluppo nel tempo della resistenza meccanica di una miscela di malta CLSM secondo l’invenzione ed una miscela di confronto. the single figure is a diagram illustrating the development over time of the mechanical strength of a mixture of CLSM mortar according to the invention and a comparison mixture.
ESEMPI EXAMPLES
Sono state preparate una miscela di malta CLSM secondo l’invenzione ed una miscela di malta CLSM di confronto aventi le composizioni riportate nella Tabella I che segue. Tale tabella riporta anche i dati relativi allo sviluppo temporale della rispettiva resistenza meccanica ed ai tempi del processo di presa ed indurimento. A mixture of CLSM mortar according to the invention and a mixture of comparative CLSM mortar were prepared having the compositions reported in the following Table I. This table also shows the data relating to the temporal development of the respective mechanical resistance and to the times of the setting and hardening process.
TABELLA I TABLE I
MIX TRADI- MIX IN-ZIONALE VENZIONE TRADITIONAL MIX IN-TIONAL MIX VENTION
Dosaggio cemento Cement dosage
kg/m<3>160 -Portland II B-LL kg / m <3> 160 -Portland II B-LL
Dosaggio legante Binder dosage
kg/m<3>- 100 solfoalluminato kg / m <3> - 100 sulfoaluminate
H<3>H <3>
2O kg/m 245 220 Additivo aerante kg/m<3>0,5 0,5 Sabbia kg/m<3>1300 1500 2O kg / m 245 220 Air-entraining additive kg / m <3> 0.5 0.5 Sand kg / m <3> 1300 1500
RES. 7H kPa - 150 RES. 24H kPa 520 241 RES 5 GG kPa 1196 272 RES. 28 GG kPa 1596 391 RES. 90 GG kPa 1863 413 RES. 360 GG kPa 4250 450 RES. 7H kPa - 150 RES. 24H kPa 520 241 RES 5 GG kPa 1196 272 RES. 28 days kPa 1596 391 RES. 90 days kPa 1863 413 RES. 360 days kPa 4250 450
Contenuto aria in- Air content in
% 18 23 % 18 23
globata globata
Perdita di lavoramin 480 160 bilità Loss of labor min 480 160 bility
Inizio presa min 660 465 Fine presa min 900 705 Start setting min 660 465 End setting min 900 705
Come risulta dai dati riportati in tabella I, la miscela dell’invenzione risulta decisamente vantaggiosa rispetto a quella convenzionale, poiché sviluppa più rapidamente una resistenza a breve termine. Inoltre, dopo un periodo di transitorio, tale resistenza resta sostanzialmente stabile tendendo ad un valore asintotico piuttosto basso, mentre la resistenza della miscela convenzionale continua a crescere sensibilmente al passare del tempo anche a lungo termine. As can be seen from the data reported in table I, the mixture of the invention is decidedly advantageous with respect to the conventional one, since it develops a short-term resistance more rapidly. Moreover, after a transient period, this resistance remains substantially stable tending to a rather low asymptotic value, while the resistance of the conventional mixture continues to increase significantly with the passage of time even in the long term.
Senza essere legati ad una specifica teoria, si può asserire che le miscele realizzate con leganti tradizionali (leganti portland) non raggiungono le prestazioni di quelle dell’invenzione, poiché, in caso di bassissimi dosaggi di cemento, la malta non indurisce nelle prime 24-36h, mentre, se si aumenta notevolmente il dosaggio di cemento, si raggiungono resistenze meccaniche elevatissime a lungo termine. Without being tied to a specific theory, it can be asserted that the mixtures made with traditional binders (Portland binders) do not reach the performance of those of the invention, since, in the case of very low doses of cement, the mortar does not harden in the first 24-36h, while, if the cement dosage is considerably increased, very high mechanical strengths are achieved in the long term.
Naturalmente, fermo restando il principio dell'invenzione, i particolari di realizzazione e le forme di attuazione potranno ampiamente variare rispetto a quanto descritto a puro titolo esemplificativo, senza per questo uscire dall’ambito dell’invenzione come definito nelle rivendicazioni annesse. Naturally, the principle of the invention remaining the same, the details of construction and the embodiments may vary widely with respect to those described purely by way of example, without thereby departing from the scope of the invention as defined in the attached claims.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000897A ITTO20120897A1 (en) | 2012-10-15 | 2012-10-15 | MALTA FOR FILLING ROAD TRAINS. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000897A ITTO20120897A1 (en) | 2012-10-15 | 2012-10-15 | MALTA FOR FILLING ROAD TRAINS. |
Publications (1)
Publication Number | Publication Date |
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ITTO20120897A1 true ITTO20120897A1 (en) | 2014-04-16 |
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IT000897A ITTO20120897A1 (en) | 2012-10-15 | 2012-10-15 | MALTA FOR FILLING ROAD TRAINS. |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2181973A1 (en) * | 2008-10-29 | 2010-05-05 | Tassullo S.p.A. | Powdered preparation for making mortars for plastering and filling chases |
FR2943339A1 (en) * | 2009-03-23 | 2010-09-24 | Francais Ciments | CEMENTITIOUS BINDER AND CEMENTITIOUS COMPOSITION FOR AUTONIVELANTE FLUID CAP, AND SELF-LEVELING FLUID CAP AS MADE |
-
2012
- 2012-10-15 IT IT000897A patent/ITTO20120897A1/en unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2181973A1 (en) * | 2008-10-29 | 2010-05-05 | Tassullo S.p.A. | Powdered preparation for making mortars for plastering and filling chases |
FR2943339A1 (en) * | 2009-03-23 | 2010-09-24 | Francais Ciments | CEMENTITIOUS BINDER AND CEMENTITIOUS COMPOSITION FOR AUTONIVELANTE FLUID CAP, AND SELF-LEVELING FLUID CAP AS MADE |
Non-Patent Citations (2)
Title |
---|
GUANGYIN ZHEN ET AL: "Performance Appraisal of Controlled Low-strength Material Using Sewage Sludge and Refuse Incineration Bottom Ash", CHINESE JOURNAL OF CHEMICAL ENGINEERING, vol. 20, no. 1, 1 February 2012 (2012-02-01), pages 80 - 88, XP055067309, ISSN: 1004-9541, DOI: 10.1016/S1004-9541(12)60366-8 * |
LANDWERMEYER JOHN S ET AL: "Comparing quick-set and regular CLSM", CONCRETE INTERNATIONAL, AMERICAN CONCRETE INSTITUTE, US, vol. 19, no. 5, 1 May 1997 (1997-05-01), pages 34 - 39, XP008163152, ISSN: 0162-4075 * |
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