IT202100020819A1 - Processo ed apparato per la produzione di bioetanolo senza emissioni di co2 mediante conversione di syngas ottenuto dalla conversione termica ad alta temperatura di rifiuti - Google Patents

Processo ed apparato per la produzione di bioetanolo senza emissioni di co2 mediante conversione di syngas ottenuto dalla conversione termica ad alta temperatura di rifiuti Download PDF

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Publication number
IT202100020819A1
IT202100020819A1 IT102021000020819A IT202100020819A IT202100020819A1 IT 202100020819 A1 IT202100020819 A1 IT 202100020819A1 IT 102021000020819 A IT102021000020819 A IT 102021000020819A IT 202100020819 A IT202100020819 A IT 202100020819A IT 202100020819 A1 IT202100020819 A1 IT 202100020819A1
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IT
Italy
Prior art keywords
conversion
phase
fermentation
waste
syngas
Prior art date
Application number
IT102021000020819A
Other languages
English (en)
Italian (it)
Inventor
Pierroberto Folgiero
Gaetano Iaquaniello
Giacomo Rispoli
Annarita Salladini
Alessia Borgogna
Original Assignee
Nextchem S P A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nextchem S P A filed Critical Nextchem S P A
Priority to IT102021000020819A priority Critical patent/IT202100020819A1/it
Priority to PCT/IB2022/057126 priority patent/WO2023012644A1/en
Priority to EP22758022.2A priority patent/EP4363532B8/en
Priority to US18/294,972 priority patent/US20240344092A1/en
Priority to PL22758022.2T priority patent/PL4363532T3/pl
Priority to JP2024506514A priority patent/JP2024531104A/ja
Priority to MYPI2024000631A priority patent/MY210541A/en
Priority to ES22758022T priority patent/ES3033156T3/es
Publication of IT202100020819A1 publication Critical patent/IT202100020819A1/it

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00—Combinations of bioreactors or fermenters with other apparatus
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00—Combinations of bioreactors or fermenters with other apparatus
    • C12M43/02—Bioreactors or fermenters combined with devices for liquid fuel extraction; Biorefineries
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C12P7/065—Ethanol, i.e. non-beverage with microorganisms other than yeasts
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0989—Hydrocarbons as additives to gasifying agents to improve caloric properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1618—Modification of synthesis gas composition, e.g. to meet some criteria
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1681—Integration of gasification processes with another plant or parts within the plant with biological plants, e.g. involving bacteria, algae, fungi
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1684—Integration of gasification processes with another plant or parts within the plant with electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Sustainable Development (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Coke Industry (AREA)
IT102021000020819A 2021-08-02 2021-08-02 Processo ed apparato per la produzione di bioetanolo senza emissioni di co2 mediante conversione di syngas ottenuto dalla conversione termica ad alta temperatura di rifiuti IT202100020819A1 (it)

Priority Applications (8)

Application Number Priority Date Filing Date Title
IT102021000020819A IT202100020819A1 (it) 2021-08-02 2021-08-02 Processo ed apparato per la produzione di bioetanolo senza emissioni di co2 mediante conversione di syngas ottenuto dalla conversione termica ad alta temperatura di rifiuti
PCT/IB2022/057126 WO2023012644A1 (en) 2021-08-02 2022-08-01 Process and apparatus for producing bioethanol without co2 emissions by conversion of syngas obtained from the thermal conversion of waste at high temperature
EP22758022.2A EP4363532B8 (en) 2021-08-02 2022-08-01 Process and apparatus for producing bioethanol without co2 emissions by conversion of syngas obtained from the thermal conversion of waste at high temperature
US18/294,972 US20240344092A1 (en) 2021-08-02 2022-08-01 Process and apparatus for producing bioethanol without co2 emissions by conversion of syngas obtained from the thermal conversion of waste at high temperature
PL22758022.2T PL4363532T3 (pl) 2021-08-02 2022-08-01 Sposób i aparatura do wytwarzania bioetanolu bez emisji co2 poprzez konwersję gazu syntezowego uzyskanego z termicznej konwersji odpadów w wysokiej temperaturze
JP2024506514A JP2024531104A (ja) 2021-08-02 2022-08-01 高温での廃棄物の熱変換から得られた合成ガスの変換によって、ｃｏ２排出のないバイオエタノールを生成するためのプロセス及び装置。
MYPI2024000631A MY210541A (en) 2021-08-02 2022-08-01 Process and apparatus for producing bioethanol without co2 emissions by conversion of syngas obtained from the thermal conversion of waste at high temperature
ES22758022T ES3033156T3 (en) 2021-08-02 2022-08-01 Process and apparatus for producing bioethanol without co2 emissions by conversion of syngas obtained from the thermal conversion of waste at high temperature

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT102021000020819A IT202100020819A1 (it) 2021-08-02 2021-08-02 Processo ed apparato per la produzione di bioetanolo senza emissioni di co2 mediante conversione di syngas ottenuto dalla conversione termica ad alta temperatura di rifiuti

Publications (1)

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IT202100020819A1 true IT202100020819A1 (it) 2023-02-02

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IT102021000020819A IT202100020819A1 (it) 2021-08-02 2021-08-02 Processo ed apparato per la produzione di bioetanolo senza emissioni di co2 mediante conversione di syngas ottenuto dalla conversione termica ad alta temperatura di rifiuti

Country Status (8)

Country Link
US (1) US20240344092A1 (https=)
EP (1) EP4363532B8 (https=)
JP (1) JP2024531104A (https=)
ES (1) ES3033156T3 (https=)
IT (1) IT202100020819A1 (https=)
MY (1) MY210541A (https=)
PL (1) PL4363532T3 (https=)
WO (1) WO2023012644A1 (https=)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9518237B2 (en) 2012-04-05 2016-12-13 Synata Bio, Inc. Integrated processes for refining syngas and bioconversion to oxygenated organic compound
CA3013354A1 (en) * 2016-02-01 2017-08-10 Lanzatech New Zealand Limited Integrated fermentation and electrolysis process
US9926196B2 (en) * 2011-11-28 2018-03-27 Synata Bio Inc. Processes for the conversion of biomass to oxygenated organic compound, apparatus therefor and compositions produced thereby
WO2018066013A1 (en) 2016-10-07 2018-04-12 Processi Innovativi S.R.L. Method and equipment to produce a syngas from wastes, preferably industrial or municipal wastes and their deliverables
US20190078121A1 (en) 2017-09-08 2019-03-14 Lanzatech, Inc. Processes and systems for metabolite production using hydrogen rich c1-containing substrates
CA3090411A1 (en) * 2018-02-12 2019-08-15 Lanzatech, Inc. A process for improving carbon conversion efficiency
US20190323042A1 (en) 2018-04-20 2019-10-24 Lanzatech, Inc. Intermittent electrolysis streams

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008109122A1 (en) * 2007-03-05 2008-09-12 Novus Energy, Llc Efficient use of biogas carbon dioxie in liquid fuel synthesis
US10619173B2 (en) * 2014-07-22 2020-04-14 Iogen Corporation Process for using biogenic carbon dioxide derived from non-fossil organic material
CA2971889A1 (en) * 2014-12-23 2016-06-30 Greenfield Specialty Alcohols Inc. Conversion of biomass, organic waste and carbon dioxide into synthetic hydrocarbons
DE102017200435A1 (de) * 2017-01-12 2018-07-12 Siemens Aktiengesellschaft Verfahren und Vorrichtung zur Herstellung von Kohlenwasserstoffen
WO2021006995A1 (en) * 2019-07-11 2021-01-14 Lanzatech, Inc. Methods for optimizing gas utilization

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9926196B2 (en) * 2011-11-28 2018-03-27 Synata Bio Inc. Processes for the conversion of biomass to oxygenated organic compound, apparatus therefor and compositions produced thereby
US9518237B2 (en) 2012-04-05 2016-12-13 Synata Bio, Inc. Integrated processes for refining syngas and bioconversion to oxygenated organic compound
CA3013354A1 (en) * 2016-02-01 2017-08-10 Lanzatech New Zealand Limited Integrated fermentation and electrolysis process
WO2018066013A1 (en) 2016-10-07 2018-04-12 Processi Innovativi S.R.L. Method and equipment to produce a syngas from wastes, preferably industrial or municipal wastes and their deliverables
US20190078121A1 (en) 2017-09-08 2019-03-14 Lanzatech, Inc. Processes and systems for metabolite production using hydrogen rich c1-containing substrates
CA3090411A1 (en) * 2018-02-12 2019-08-15 Lanzatech, Inc. A process for improving carbon conversion efficiency
US20190323042A1 (en) 2018-04-20 2019-10-24 Lanzatech, Inc. Intermittent electrolysis streams

Also Published As

Publication number Publication date
PL4363532T3 (pl) 2025-09-08
JP2024531104A (ja) 2024-08-29
EP4363532B1 (en) 2025-03-26
ES3033156T3 (en) 2025-07-31
MY210541A (en) 2025-09-30
US20240344092A1 (en) 2024-10-17
EP4363532B8 (en) 2025-08-06
EP4363532C0 (en) 2025-03-26
EP4363532A1 (en) 2024-05-08
WO2023012644A1 (en) 2023-02-09

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