IT201600101785A1 - PHOTOPROTECTIVE PREPARATION AND INSECT-REPELLENT - Google Patents
PHOTOPROTECTIVE PREPARATION AND INSECT-REPELLENTInfo
- Publication number
- IT201600101785A1 IT201600101785A1 IT102016000101785A IT201600101785A IT201600101785A1 IT 201600101785 A1 IT201600101785 A1 IT 201600101785A1 IT 102016000101785 A IT102016000101785 A IT 102016000101785A IT 201600101785 A IT201600101785 A IT 201600101785A IT 201600101785 A1 IT201600101785 A1 IT 201600101785A1
- Authority
- IT
- Italy
- Prior art keywords
- composition
- extract
- essential oil
- insect
- component
- Prior art date
Links
- 239000000077 insect repellent Substances 0.000 title claims description 22
- 230000003711 photoprotective effect Effects 0.000 title description 13
- 239000000203 mixture Substances 0.000 claims description 73
- 230000000699 topical effect Effects 0.000 claims description 18
- 239000000341 volatile oil Substances 0.000 claims description 17
- 244000004281 Eucalyptus maculata Species 0.000 claims description 6
- 239000000284 extract Substances 0.000 claims description 6
- LMXFTMYMHGYJEI-UHFFFAOYSA-N p-menthane-3,8-diol Chemical compound CC1CCC(C(C)(C)O)C(O)C1 LMXFTMYMHGYJEI-UHFFFAOYSA-N 0.000 claims description 6
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 claims description 5
- KNUPSOXBESCJLY-UHFFFAOYSA-N 2-methoxy-1-phenylhexan-1-one Chemical compound CCCCC(OC)C(=O)C1=CC=CC=C1 KNUPSOXBESCJLY-UHFFFAOYSA-N 0.000 claims description 5
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 5
- 241000238631 Hexapoda Species 0.000 claims description 5
- 239000009854 citriodiol Substances 0.000 claims description 5
- 229940068171 ethyl hexyl salicylate Drugs 0.000 claims description 5
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 5
- 229960000601 octocrylene Drugs 0.000 claims description 5
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 5
- 244000178870 Lavandula angustifolia Species 0.000 claims description 4
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 4
- 244000062730 Melissa officinalis Species 0.000 claims description 4
- 235000010654 Melissa officinalis Nutrition 0.000 claims description 4
- 235000007303 Thymus vulgaris Nutrition 0.000 claims description 4
- 240000002657 Thymus vulgaris Species 0.000 claims description 4
- 239000001102 lavandula vera Substances 0.000 claims description 4
- 235000018219 lavender Nutrition 0.000 claims description 4
- 239000001585 thymus vulgaris Substances 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
- 244000166675 Cymbopogon nardus Species 0.000 claims description 3
- 235000018791 Cymbopogon nardus Nutrition 0.000 claims description 3
- 241000208152 Geranium Species 0.000 claims description 3
- 244000246386 Mentha pulegium Species 0.000 claims description 3
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 3
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 3
- 229940007062 eucalyptus extract Drugs 0.000 claims description 3
- 235000001050 hortel pimenta Nutrition 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 240000004784 Cymbopogon citratus Species 0.000 claims description 2
- 235000017897 Cymbopogon citratus Nutrition 0.000 claims description 2
- 239000012675 alcoholic extract Substances 0.000 claims description 2
- 239000000399 hydroalcoholic extract Substances 0.000 claims description 2
- 239000013505 freshwater Substances 0.000 claims 1
- 239000013535 sea water Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 210000004243 sweat Anatomy 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 230000000475 sunscreen effect Effects 0.000 description 14
- 239000000516 sunscreening agent Substances 0.000 description 14
- 239000002537 cosmetic Substances 0.000 description 8
- 239000004744 fabric Substances 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 5
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 230000004224 protection Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 4
- 229960001673 diethyltoluamide Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 3
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- 241000239223 Arachnida Species 0.000 description 2
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229940069521 aloe extract Drugs 0.000 description 2
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 2
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- FOYKKGHVWRFIBD-UHFFFAOYSA-N gamma-tocopherol acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 FOYKKGHVWRFIBD-UHFFFAOYSA-N 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 230000001846 repelling effect Effects 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- CENPSTJGQOQKKW-UHFFFAOYSA-N 2,4,6-tris(4-phenylphenyl)-1,3,5-triazine Chemical compound C1=CC=CC=C1C1=CC=C(C=2N=C(N=C(N=2)C=2C=CC(=CC=2)C=2C=CC=CC=2)C=2C=CC(=CC=2)C=2C=CC=CC=2)C=C1 CENPSTJGQOQKKW-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 239000006000 Garlic extract Substances 0.000 description 1
- 241000238889 Ixodidae Species 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000282376 Panthera tigris Species 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 230000037338 UVA radiation Effects 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000001941 cymbopogon citratus dc and cymbopogon flexuosus oil Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000001999 effect on insects Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
- 229940044949 eucalyptus oil Drugs 0.000 description 1
- 210000002683 foot Anatomy 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 235000020706 garlic extract Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 210000002414 leg Anatomy 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 231100000189 neurotoxic Toxicity 0.000 description 1
- 230000002887 neurotoxic effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000002165 photosensitisation Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/53—Lamiaceae or Labiatae (Mint family), e.g. thyme, rosemary or lavender
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/61—Myrtaceae (Myrtle family), e.g. teatree or eucalyptus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/75—Rutaceae (Rue family)
- A61K36/752—Citrus, e.g. lime, orange or lemon
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/88—Liliopsida (monocotyledons)
- A61K36/899—Poaceae or Gramineae (Grass family), e.g. bamboo, corn or sugar cane
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4966—Triazines or their condensed derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Medical Informatics (AREA)
- Alternative & Traditional Medicine (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Mycology (AREA)
- Pharmacology & Pharmacy (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Photometry And Measurement Of Optical Pulse Characteristics (AREA)
Description
Titolo Title
PREPARAZIONE FOTOPROTETTIV A E INSETTO-REPELLENTE PHOTOPROTECTIVE AND INSECT-REPELLENT PREPARATION
“PREPARAZIONE FOTOPROTETTIVA E INSETTO-REPELLENTE” "PHOTOPROTECTIVE AND INSECT REPELLENT PREPARATION"
La presente invenzione si riferisce al campo tecnico dei prodotti cosmetici e ha per oggetto una composizione ad azione foto-protettiva ed insettorepellente comprendente almeno un filtro solare a bassa tossicità e una miscela di oli essenziali ad azione insetto-repellente. The present invention relates to the technical field of cosmetic products and relates to a composition with a photo-protective and insect-repellent action comprising at least a low-toxicity solar filter and a mixture of essential oils with an insect-repellent action.
Stato dell’arte State of the art
I prodotti cosmetici contenenti filtri solari sono prodotti ampiamente diffusi sul mercato. I filtri solari per uso topico si suddividono sostanzialmente in filtri solari fisici e chimici. I filtri solari fisici sono generalmente costituiti da composti inorganici in grado di riflettere le radiazioni UV, proteggendo in questo modo la pelle dalle radiazioni solari potenzialmente dannose. Il meccanismo di azione dei filtri solari chimici consiste invece nell’assorbimento selettivo delle radiazioni solari con una determinata lunghezza d’onda (raggi UVA e UVB), convertendo queste radiazioni in altre forme di energia dispersa. I filtri solari ammessi per l'utilizzo cosmetico nell’Unione Europea sono elencati nell'Allegato VI del Regolamento No. 1223/2009 e successivi aggiornamenti tecnici. Dei 30 filtri solari attualmente presenti nell’Allegato VI, solamente biossido di titanio, zinco ossido e tris-bifenil triazina appartengono alla classe dei filtri solari fisici. Pertanto, la maggior parte dei prodotti cosmetici ad azione foto-protettiva destinati ad essere posti in commercio nell’Unione Europea dovrà contenere filtri solari chimici, eventualmente in associazione con i filtri solari fisici elencati sopra. Cosmetic products containing sunscreens are widely used on the market. Topical sunscreens are basically divided into physical and chemical sunscreens. Physical sunscreens are generally made up of inorganic compounds that can reflect UV radiation, thereby protecting the skin from potentially harmful solar radiation. The mechanism of action of chemical sunscreens, on the other hand, consists in the selective absorption of solar radiation with a certain wavelength (UVA and UVB rays), converting these radiations into other forms of dispersed energy. Sunscreens allowed for cosmetic use in the European Union are listed in Annex VI of Regulation No. 1223/2009 and subsequent technical updates. Of the 30 sunscreens currently present in Annex VI, only titanium dioxide, zinc oxide and tris-biphenyl triazine belong to the class of physical sunscreens. Therefore, most cosmetic products with photo-protective action intended to be placed on the market in the European Union must contain chemical sunscreens, possibly in association with the physical sunscreens listed above.
La presenza di filtri solari chimici in una formulazione cosmetica ad azione foto-protettiva pone il problema della compatibilità tra i prodotti derivanti dall’assorbimento delle radiazioni UVB e/o UVA da parte del filtro solare e gli ulteriori componenti presenti nella formulazione stessa. The presence of chemical sunscreens in a cosmetic formulation with a photo-protective action poses the problem of compatibility between the products resulting from the absorption of UVB and / or UVA radiation by the sun filter and the other components present in the formulation itself.
A causa principalmente della diffusione alle latitudini europee di insetti nocivi e/o fastidiosi per l’uomo attivi durante il giorno (si pensi ad esempio alla zanzara tigre), è sentita l’esigenza di disporre di prodotti cosmetici nei quali all’azione foto-protettiva è associata un’azione insetto-repellente. Esistono in commercio prodotti insetto-repellenti a base di dietiltoluamide (DEET) contenenti anche filtri solari. Tuttavia, oltre ad avere un odore particolarmente sgradevole, la dietiltoluamide è un principio attivo non privo di effetti collaterali (ad esempio è un sospetto neurotossico), in grado di penetrare attraverso la pelle. Secondo alcuni studi inoltre, è sconsigliata l’associazione tra dietiltoluamide e filtri solari, poiché questi ultimi aumenterebbero la penetrazione cutanea della dietiltoluamide stessa. Sono noti e commercialmente disponibili molteplici prodotti insettorepellenti a base di principi attivi naturali, tipicamente a base di oli essenziali, anche piuttosto concentrati. Tuttavia, alcuni di questi prodotti contengono oli essenziali ad azione insetto-repellente con un odore sgradevole (eg. estratto di aglio), ed inoltre alcuni oli essenziali ad azione insetto-repellente hanno un effetto foto-sensibilizzante sulla pelle, potendo causare la comparsa di macchie a seguito dell’esposizione al sole. Mainly due to the spread in European latitudes of harmful and / or annoying insects for humans active during the day (think for example of the tiger mosquito), there is a need to have cosmetic products in which the photo- protective action is associated with an insect-repellent action. There are insect repellent products based on diethyltoluamide (DEET) on the market, which also contain sunscreens. However, in addition to having a particularly unpleasant odor, diethyltoluamide is an active ingredient not without side effects (for example, it is a suspected neurotoxic), able to penetrate through the skin. Furthermore, according to some studies, the association between diethyltoluamide and sunscreens is not recommended, since the latter would increase the skin penetration of diethyltoluamide itself. Many insect repellent products based on natural active ingredients, typically based on essential oils, even if they are quite concentrated, are known and commercially available. However, some of these products contain essential oils with an insect-repellent action with an unpleasant odor (eg garlic extract), and also some essential oils with an insect-repellent action have a photo-sensitizing effect on the skin, being able to cause the appearance of spots following exposure to the sun.
In questo contesto, scopo precipuo della presente invenzione è fornire un prodotto cosmetico foto-protettivo avente proprietà insetto-repellenti, il quale non presenti gli svantaggi sopra evidenziati. In this context, the main object of the present invention is to provide a photo-protective cosmetic product having insect-repellent properties, which does not have the disadvantages highlighted above.
Sommario dell’invenzione Summary of the invention
In un suo primo aspetto, la presente invenzione ha ad oggetto una composizione per uso topico ad azione foto-protettiva e insetto-repellente comprendente: In a first aspect, the present invention relates to a composition for topical use with a photo-protective and insect-repellent action comprising:
(a) circa 0,01 – 15% in peso di almeno un componente ad azione insetto repellente scelto tra p-mentan-3,8-diolo, estratto di eucalipto, di citronella, di eucalipto citrato, di lavanda, di geranio, di timo, di melissa, di menta piperita, e loro miscele; (a) about 0.01 - 15% by weight of at least one component with an insect repellent action selected from p-mentan-3,8-diol, eucalyptus extract, citronella, eucalyptus citrate, lavender, geranium, thyme, lemon balm, peppermint, and their mixtures;
(b) circa 0,1 – 50% in peso di almeno un filtro solare scelto tra octocrilene, etilesil salicilato, butil metossidibenzoilmetano, dietilesil butamido triazone e loro miscele; e (b) about 0.1 - 50% by weight of at least one solar filter selected from octocrylene, ethylhexyl salicylate, butyl methoxybenzoylmethane, diethylhexyl butamido triazone and mixtures thereof; And
(c) almeno un eccipiente cosmeticamente accettabile. (c) at least one cosmetically acceptable excipient.
In un suo ulteriore aspetto, la presente invenzione ha ad oggetto un metodo per prevenire le scottature solari della pelle e respingere gli insetti comprendente l’uso della composizione secondo l’invenzione. In a further aspect, the present invention relates to a method for preventing sunburn of the skin and repelling insects comprising the use of the composition according to the invention.
Descrizione dettagliata dell’invenzione Detailed description of the invention
Nella presente descrizione e nelle rivendicazioni allegate, le percentuali sono espresse in peso, salvo diversamente indicato. In the present description and in the attached claims, the percentages are expressed by weight, unless otherwise indicated.
Il termine “pelle” si riferisce nella presente descrizione e nelle rivendicazioni allegate al tessuto che riveste esternamente il corpo umano, ivi compreso il cuoio capelluto, oppure ad una qualunque porzione di esso. Ad esempio, il termine pelle comprende la pelle di faccia, collo, braccia, mani, torso, schiena, natiche, gambe, piedi e cuoio capelluto. Il termine “composizione”, come usato nella presente descrizione e nelle rivendicazioni allegate, si riferisce ad una composizione per uso topico che può essere applicata sulla pelle. The term "skin" refers in the present description and in the attached claims to the tissue that covers the human body externally, including the scalp, or to any portion of it. For example, the term skin includes the skin of the face, neck, arms, hands, torso, back, buttocks, legs, feet, and scalp. The term "composition", as used in the present description and in the appended claims, refers to a composition for topical use that can be applied to the skin.
Il termine “fattore di protezione” (SPF) indica il grado di protezione contro i raggi solari UVB, i quali hanno una lunghezza d’onda di 290-320 nm. Il fattore di protezione nei confronti dei raggi solari UVA (lunghezza d’onda 320-400 nm) è generalmente indicato come UVA-PF. The term "protection factor" (SPF) indicates the degree of protection against UVB sun rays, which have a wavelength of 290-320 nm. The protection factor against UVA sun rays (wavelength 320-400 nm) is generally referred to as UVA-PF.
Con il termine “composizione ad azione foto-protettiva” ci si riferisce nella presente descrizione e nelle rivendicazioni allegate ad una composizione che presenta un SPF ≥ 5. The term "photo-protective action composition" refers in the present description and in the attached claims to a composition which has an SPF ≥ 5.
Con il termine “insetto-repellente” ci si riferisce nella presente descrizione e nelle rivendicazioni allegate ad una composizione avente un effetto repellente su insetti, aracnidi e ixodida, in particolare su insetti, aracnidi e zecche. The term "insect-repellent" refers in the present description and in the attached claims to a composition having a repellent effect on insects, arachnids and ixodidae, in particular on insects, arachnids and ticks.
In un suo primo aspetto, la presente invenzione si riferisce ad una composizione per uso topico ad azione foto-protettiva e insetto-repellente comprendente: In a first aspect, the present invention refers to a composition for topical use with a photo-protective and insect-repellent action comprising:
(a) circa 0,01 – 15% in peso di almeno un componente ad azione insetto repellente scelto tra p-mentan-3,8-diolo, estratto di eucalipto, di citronella, di eucalipto citrato, di lavanda, di geranio, di timo, di melissa, di menta piperita e loro miscele; (a) about 0.01 - 15% by weight of at least one component with an insect repellent action selected from p-mentan-3,8-diol, eucalyptus extract, citronella, eucalyptus citrate, lavender, geranium, thyme, lemon balm, peppermint and their mixtures;
(b) circa 0,1 – 50% in peso di almeno un filtro solare scelto tra octocrilene, etilesil salicilato, butil metossidibenzoilmetano, dietilesil butamido triazone e loro miscele; e (b) about 0.1 - 50% by weight of at least one solar filter selected from octocrylene, ethylhexyl salicylate, butyl methoxybenzoylmethane, diethylhexyl butamido triazone and mixtures thereof; And
(c) almeno un eccipiente cosmeticamente accettabile q.b. a 100% in peso. (c) at least one cosmetically acceptable excipient q.b. at 100% by weight.
Il componente (a) ad azione insetto-repellente può essere almeno un estratto ottenuto dal materiale vegetale sopra indicato, generalmente da specifiche parti delle piante sopra indicate, che differiscono a seconda del tipo di pianta. The component (a) with insect-repellent action can be at least one extract obtained from the plant material indicated above, generally from specific parts of the plants indicated above, which differ according to the type of plant.
Il componente (a) può essere un estratto delle piante sopra elencate scelto tra estratto idroalcolico, estratto alcolico, estratto secco, olio essenziale e loro miscele, preferibilmente olio essenziale. Component (a) can be an extract of the plants listed above selected from hydroalcoholic extract, alcoholic extract, dry extract, essential oil and their mixtures, preferably essential oil.
Ad esempio, l’olio essenziale di timo e di lavanda può essere generalmente ottenuto dalle sommità fiorite della pianta; gli oli essenziali di eucalipto e melissa dalle foglie; l’olio di citronella dalle foglie e dagli steli. For example, the essential oil of thyme and lavender can generally be obtained from the flowering tops of the plant; the essential oils of eucalyptus and lemon balm from the leaves; lemongrass oil from the leaves and stems.
Il p-mentan-3,8-diolo (CAS RN: 42822-86-6) è un principio attivo di origine naturale presente nell’olio di eucalipto citrato e si presenta sotto forma di miscela complessa dei possibili isomeri di questo composto. Il p-mentan-3,8-diolo è disponibile in commercio come Citriodiol<®>. Secondo una forma di attuazione, il p-mentan-3,8-diolo può essere aggiunto alla composizione secondo l’invenzione come Citriodiol<®>. P-mentan-3,8-diol (CAS RN: 42822-86-6) is an active ingredient of natural origin present in citrated eucalyptus oil and is presented in the form of a complex mixture of the possible isomers of this compound. The p-mentan-3,8-diol is commercially available as Citriodiol <®>. According to one embodiment, the p-mentan-3,8-diol can be added to the composition according to the invention as Citriodiol <®>.
Secondo una variante preferita pertanto, il componente (a) può essere una miscela comprendente Citriodiol<®>, olio essenziale di eucalipto e olio essenziale di citronella. According to a preferred variant, therefore, component (a) can be a mixture comprising Citriodiol <®>, eucalyptus essential oil and lemongrass essential oil.
Il Citriodiol<®>e gli oli essenziali utili alla realizzazione della composizione secondo l’invenzione sono disponibili in commercio come singoli oli essenziali, oppure come miscele. Citriodiol <®> and essential oils useful for making the composition according to the invention are commercially available as individual essential oils, or as mixtures.
La composizione secondo l’invenzione può contenere quantità molto variabili del componente (a), in funzione dell’attività insetto-repellente di ciascun estratto presente nella composizione. The composition according to the invention may contain very variable quantities of component (a), depending on the insect-repellent activity of each extract present in the composition.
Secondo una variante preferita, la composizione secondo l’invenzione può comprendere circa 0,1 – 30% in peso, preferibilmente circa 1-30%, più preferibilmente circa 1-20%, di almeno un filtro solare (b). According to a preferred variant, the composition according to the invention can comprise about 0.1 - 30% by weight, preferably about 1-30%, more preferably about 1-20%, of at least one solar filter (b).
Secondo una ulteriore variante, il componente (b) della composizione per uso topico secondo l’invenzione può comprendere una miscela di octocrilene, etilesil salicilato, butil metossidibenzoilmetano, dietilesil butamido triazone. According to a further variant, the component (b) of the composition for topical use according to the invention can comprise a mixture of octocrylene, ethylhexyl salicylate, butyl methoxybenzoylmethane, diethylhexyl butamido triazone.
In funzione della concentrazione del componente (b), la composizione dell’invenzione può avere un fattore di protezione 5 ≤ SPF ≤ 50, preferibilmente 10 ≤ SPF ≤ 50, più preferibilmente 20 ≤ SPF ≤ 40. Depending on the concentration of component (b), the composition of the invention may have a protection factor of 5 ≤ SPF ≤ 50, preferably 10 ≤ SPF ≤ 50, more preferably 20 ≤ SPF ≤ 40.
I filtri solari presenti nella composizione secondo l’invenzione hanno inoltre un buon fattore di protezione anche nei confronti dei raggi solari UVA. The sunscreens present in the composition according to the invention also have a good protection factor even against UVA sun rays.
La composizione per uso topico secondo l’invenzione comprende quantità variabili di almeno un eccipiente cosmeticamente accettabile (c), preferibilmente scelto tra: The composition for topical use according to the invention includes variable amounts of at least one cosmetically acceptable excipient (c), preferably chosen from:
- antiossidanti: composti che inibiscono le reazioni promosse dall’ossigeno prevenendo l’ossidazione dei componenti compresi nella composizione secondo l’invenzione. Tra i composti antiossidanti, particolarmente preferiti sono il idrossitoluene butilato (BHT), tocoferil acetato, vitamina E e loro miscele; e/o - antioxidants: compounds that inhibit the reactions promoted by oxygen by preventing oxidation of the components included in the composition according to the invention. Among the antioxidant compounds, particularly preferred are butylated hydroxytoluene (BHT), tocopheryl acetate, vitamin E and their mixtures; and / or
- emollienti: composti che rendono la pelle soffice e liscia; tra questi ad esempio cicloesasilossano, C12-15 alchil benzoato, C16-17 alchil benzoato, estratto di aloe e loro miscele. In particolare la presenza di cicloesasilossano nella composizione secondo l’invenzione garantisce la lunga permanenza della composizione sulla pelle; e/o - emollients: compounds that make the skin soft and smooth; among these, for example, cyclohexasiloxane, C12-15 alkyl benzoate, C16-17 alkyl benzoate, aloe extract and their mixtures. In particular, the presence of cyclohexasiloxane in the composition according to the invention guarantees the long permanence of the composition on the skin; and / or
- emulsionanti: promuovono la compatibilità di liquidi altrimenti tra loro immiscibili. Gli emulsionanti possono essere ionici, sia anionici che cationici; e/o - emulsifiers: they promote the compatibility of otherwise immiscible liquids. The emulsifiers can be ionic, both anionic and cationic; and / or
- addensanti: che permettono di regolare opportunamente la viscosità della composizione; e/o - thickeners: which allow the viscosity of the composition to be suitably adjusted; and / or
- idratanti; e/o - moisturizers; and / or
- profumi e fragranze: tra cui ad esempio aldeide esil cinnamica, che contribuisce a migliorare la compliance della composizione secondo l’invenzione; e/o - perfumes and fragrances: including for example hexyl cinnamic aldehyde, which helps to improve the compliance of the composition according to the invention; and / or
- pigmenti e/o coloranti; - pigments and / or dyes;
- veicoli: tra cui preferibilmente acqua e/o lanolina; e - vehicles: preferably including water and / or lanolin; And
- loro miscele. - their blends.
Secondo una forma di attuazione preferita, la composizione per uso topico secondo l’invenzione può comprendere come componente (c) una miscela comprendente idrossitoluene butilato (BHT), tocoferil acetato, cicloesasilossano, C12-15 alchil benzoato, aldeide esil cinnamica, estratto di aloe e acqua. According to a preferred embodiment, the composition for topical use according to the invention can comprise as component (c) a mixture comprising butylated hydroxytoluene (BHT), tocopheryl acetate, cyclohexasiloxane, C12-15 alkyl benzoate, hexyl cinnamic aldehyde, aloe extract and water.
I composti di cui ai componenti (b) e (c) sono normalmente disponibili in commercio. La composizione per uso topico secondo l’invenzione può essere preparata per miscelazione a temperatura ambiente dei diversi componenti in qualsivoglia ordine. Preferibilmente, possono essere inizialmente miscelati tra loro gli eccipienti, successivamente può essere aggiunto il componente (b) e infine il componente (a). The compounds referred to in components (b) and (c) are normally commercially available. The composition for topical use according to the invention can be prepared by mixing the different components at room temperature in any order. Preferably, the excipients can be initially mixed together, then component (b) and finally component (a) can be added.
La composizione per uso topico secondo l’invenzione può essere preferibilmente una composizione destinata a rimanere sulla pelle (cosiddette composizioni “leave-on”). La composizione secondo l’invenzione può essere in forma solida (es. stick oppure polvere) oppure, e preferibilmente, in forma di siero, crema, lozione, unguento, schiuma, emulsione oppure gel, preferibilmente lozione. The composition for topical use according to the invention can preferably be a composition intended to remain on the skin (so-called "leave-on" compositions). The composition according to the invention can be in solid form (eg stick or powder) or, and preferably, in the form of serum, cream, lotion, ointment, foam, emulsion or gel, preferably lotion.
Secondo una forma di attuazione, la composizione secondo l’invenzione può essere una composizione spray, ovvero una composizione confezionata in un contenitore in grado erogare la composizione stessa sotto forma di spruzzo e/o nebbia oppure sotto forma di schiuma. According to an embodiment, the composition according to the invention can be a spray composition, or a composition packaged in a container capable of delivering the composition itself in the form of a spray and / or mist or in the form of foam.
Secondo una ulteriore forma di attuazione, la presente invenzione si riferisce ad un tessuto comprendente la composizione come precedentemente descritta, in cui la composizione per uso topico è liquida ed è impregnata sul tessuto. Il tessuto può essere costituito da fibre naturali (es. cotone) oppure da fibre di origine sintetica (es. nylon, PET, etc.); quando il tessuto è costituito da fibre di origine sintetica, può essere un tessuto a trama e ordito oppure un tessuto-non-tessuto. Secondo questa forma di attuazione, il tessuto può essere impregnato della composizione liquida secondo l’invenzione e posto in commercio sotto forma di “salvietta umidificata”. According to a further embodiment, the present invention relates to a fabric comprising the composition as described above, in which the composition for topical use is liquid and is impregnated on the fabric. The fabric can be made up of natural fibers (eg cotton) or of synthetic fibers (eg nylon, PET, etc.); when the fabric consists of fibers of synthetic origin, it can be a warp and weft fabric or a non-woven fabric. According to this embodiment, the fabric can be impregnated with the liquid composition according to the invention and placed on the market in the form of a "wet wipe".
La composizione per uso topico secondo l’invenzione associa alla efficace azione insetto-repellente, dovuta alla presenza del componente (a), ottime caratteristiche di foto-protezione dai raggi solari, e una serie di vantaggi ulteriori, tra cui: The composition for topical use according to the invention combines the effective insect-repellent action, due to the presence of component (a), with excellent photo-protection characteristics from the sun, and a series of further advantages, including:
- compliance elevata: grazie alla presenza degli oli essenziali, la composizione secondo l’invenzione ha un odore gradevole, che permane a lungo anche dopo la prima applicazione sulla pelle; - high compliance: thanks to the presence of essential oils, the composition according to the invention has a pleasant odor, which persists for a long time even after the first application on the skin;
- scarsi effetti collaterali, in particolare nessun rischio di comparsa di macchie iperpigmentarie a seguito dell’esposizione al sole; - few side effects, in particular no risk of the appearance of hyperpigmentary spots following exposure to the sun;
- assenza di sostanze insetto-repellenti la cui presenza è sconsigliata in formulazioni cosmetiche destinate ad essere applicate sulla pelle prima dell’esposizione al sole, quali ad esempio la DEET. - absence of insect-repellent substances whose presence is not recommended in cosmetic formulations intended to be applied to the skin before exposure to the sun, such as DEET.
In un suo ulteriore aspetto, la presente invenzione ha ad oggetto un metodo per schermare la pelle dai raggi solari UVB e/o UVA e respingere gli insetti comprendente l’uso della composizione per uso topico come precedentemente descritta oppure del tessuto come precedentemente descritto. In a further aspect, the present invention relates to a method for shielding the skin from UVB and / or UVA rays and repelling insects comprising the use of the composition for topical use as previously described or of the fabric as previously described.
Le modalità di applicazione della composizione alla cute dipendono forma con la quale la composizione secondo l’invenzione viene posta in commercio, nonché dalla concentrazione dei principi attivi foto-protettivi e insetto-repellenti presenti. The methods of application of the composition to the skin depend on the form in which the composition according to the invention is placed on the market, as well as on the concentration of the photo-protective and insect-repellent active ingredients present.
Vantaggiosamente, la composizione secondo l’invenzione può essere applicata sulla pelle almeno due volte al giorno, preferibilmente distanziando tra loro le applicazioni nell’arco della giornata, a seconda del tipo di attività svolta. Advantageously, the composition according to the invention can be applied to the skin at least twice a day, preferably spacing the applications apart throughout the day, depending on the type of activity performed.
La composizione secondo l’invenzione può essere formulata specificatamente per uso in condizioni di esposizione estrema ai raggi The composition according to the invention can be formulated specifically for use in conditions of extreme exposure to rays
Claims (6)
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HUP9903897A2 (en) * | 1996-06-26 | 2000-03-28 | S.C. Johnson & Son, Inc. | Insect repellent sunscreen |
WO2002043656A2 (en) * | 2000-11-28 | 2002-06-06 | Avon Products, Inc. | Water-in-oil insect repellent composition and method of application to the skin |
CN104042486A (en) * | 2014-05-31 | 2014-09-17 | 青岛博泓海洋生物技术有限公司 | Refreshing and whitening sunscreen cream |
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WO1997049380A1 (en) * | 1996-06-26 | 1997-12-31 | S.C. Johnson & Son, Inc. | Insect repellent sunscreen |
HUP9903897A2 (en) * | 1996-06-26 | 2000-03-28 | S.C. Johnson & Son, Inc. | Insect repellent sunscreen |
WO2002043656A2 (en) * | 2000-11-28 | 2002-06-06 | Avon Products, Inc. | Water-in-oil insect repellent composition and method of application to the skin |
CN104042486A (en) * | 2014-05-31 | 2014-09-17 | 青岛博泓海洋生物技术有限公司 | Refreshing and whitening sunscreen cream |
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