IT1317896B1 - CONTINUOUS ELECTROLYTIC PICKLING METHOD OF METAL PRODUCTS CONCELLS POWERED BY ALTERNATING CURRENT. - Google Patents
CONTINUOUS ELECTROLYTIC PICKLING METHOD OF METAL PRODUCTS CONCELLS POWERED BY ALTERNATING CURRENT.Info
- Publication number
- IT1317896B1 IT1317896B1 IT2000RM000456A ITRM20000456A IT1317896B1 IT 1317896 B1 IT1317896 B1 IT 1317896B1 IT 2000RM000456 A IT2000RM000456 A IT 2000RM000456A IT RM20000456 A ITRM20000456 A IT RM20000456A IT 1317896 B1 IT1317896 B1 IT 1317896B1
- Authority
- IT
- Italy
- Prior art keywords
- pickling method
- concells
- powered
- alternating current
- metal products
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
- C25F1/02—Pickling; Descaling
- C25F1/04—Pickling; Descaling in solution
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
- C25F1/02—Pickling; Descaling
- C25F1/04—Pickling; Descaling in solution
- C25F1/06—Iron or steel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Continuous electrolytic pickling method for steels, Nickel, superalloys, Titanium and alloys thereof, characterised in that the material to be treated , for a time comprised between 3 sec and 60 sec, is immersed into or passes through at least one electrolytic cell with an electrolytic solution consisting of a neutral or acid aqueous solution, at a temperature comprised between 20 DEG C. and 95 DEG C., with at least one pair of electrodes connected to an alternate current power supply having a frequency ranging from 1 Hz to 1000 Hz, the electrolysis being carried out at a current density having an effective amplitude ranging from 10 A/dm2 to 250 A/dm2. The Figure depicts the progress of the weight loss of an AISI 409 (X6CrTil2) steel as a function of the application time of an embodiment of the pickling method according to the present invention.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2000RM000456A IT1317896B1 (en) | 2000-08-10 | 2000-08-10 | CONTINUOUS ELECTROLYTIC PICKLING METHOD OF METAL PRODUCTS CONCELLS POWERED BY ALTERNATING CURRENT. |
US10/344,254 US20040031696A1 (en) | 2000-08-10 | 2001-08-06 | Continous electrolytic pickling method for metallic products using alternate current supplied cells |
PCT/IT2001/000435 WO2002012596A2 (en) | 2000-08-10 | 2001-08-06 | Continuous electrolytic pickling method for metallic products using alternate current supplied cells |
EP01961136A EP1307609B1 (en) | 2000-08-10 | 2001-08-06 | Continuous electrolytic pickling method for metallic products using alternate current supplied cells |
AU2001282513A AU2001282513A1 (en) | 2000-08-10 | 2001-08-06 | Continuous electrolytic pickling method for metallic products using alternate current supplied cells |
ES01961136T ES2220795T3 (en) | 2000-08-10 | 2001-08-06 | CONTINUOUS PROCEDURE OF ELECTROLYTIC DECAPING FOR METAL PRODUCTS, IN WHICH CELLS TO WHICH ARE SUPPLIED ALTERNATE CURRENT SUPPLY ARE USED. |
AT01961136T ATE262057T1 (en) | 2000-08-10 | 2001-08-06 | METHOD FOR CONTINUOUS ELECTROLYTIC PICKLING OF METALS USING ALTERNATING CURRENT CELLS |
CNB018150063A CN1318652C (en) | 2000-08-10 | 2001-08-06 | Continuous electrolytic pickling method for metallic products using alternate current suplied cells |
DE60102387T DE60102387T2 (en) | 2000-08-10 | 2001-08-06 | METHOD FOR CONTINUOUS ELECTROLYTICIZING OF METALS USING AC-SUSTAINED CELLS |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2000RM000456A IT1317896B1 (en) | 2000-08-10 | 2000-08-10 | CONTINUOUS ELECTROLYTIC PICKLING METHOD OF METAL PRODUCTS CONCELLS POWERED BY ALTERNATING CURRENT. |
Publications (3)
Publication Number | Publication Date |
---|---|
ITRM20000456A0 ITRM20000456A0 (en) | 2000-08-10 |
ITRM20000456A1 ITRM20000456A1 (en) | 2002-02-10 |
IT1317896B1 true IT1317896B1 (en) | 2003-07-15 |
Family
ID=11454885
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT2000RM000456A IT1317896B1 (en) | 2000-08-10 | 2000-08-10 | CONTINUOUS ELECTROLYTIC PICKLING METHOD OF METAL PRODUCTS CONCELLS POWERED BY ALTERNATING CURRENT. |
Country Status (9)
Country | Link |
---|---|
US (1) | US20040031696A1 (en) |
EP (1) | EP1307609B1 (en) |
CN (1) | CN1318652C (en) |
AT (1) | ATE262057T1 (en) |
AU (1) | AU2001282513A1 (en) |
DE (1) | DE60102387T2 (en) |
ES (1) | ES2220795T3 (en) |
IT (1) | IT1317896B1 (en) |
WO (1) | WO2002012596A2 (en) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10160318A1 (en) * | 2001-12-07 | 2003-06-18 | Henkel Kgaa | Process for pickling martensitic or ferritic stainless steel |
DE102008057151A1 (en) * | 2008-11-13 | 2010-05-27 | Henkel Ag & Co. Kgaa | Process for producing an electrolytically galvanized high strength steel sheet |
CN102260899B (en) * | 2010-05-25 | 2013-04-03 | 宝山钢铁股份有限公司 | Method for removing scale on surface of titanium/titanium alloy strip |
US20120168320A1 (en) * | 2010-12-30 | 2012-07-05 | Monique Chauntia Bland | System and method for scale removal from a nickel-based superalloy component |
JP6144006B2 (en) * | 2011-01-17 | 2017-06-07 | Jfeスチール株式会社 | Method for producing stainless steel for fuel cell separator, stainless steel for fuel cell separator, fuel cell separator, and fuel cell |
CN103014824A (en) * | 2011-09-21 | 2013-04-03 | 李文志 | Low carbon type alternating current electrochemical degreasing process method |
ITMI20130494A1 (en) | 2013-03-29 | 2014-09-30 | Tenova Spa | METHOD OF TREATING CONTINUOUSLY THE SURFACE OF A STAINLESS STEEL LAMINATE IN A CHLORIDRID ACID-BASED SOLUTION |
ITMI20130493A1 (en) * | 2013-03-29 | 2014-09-30 | Tenova Spa | METHOD TO PROCESS THE SURFACE OF A STAINLESS STEEL LAMINATE IN A CONTINUOUS SOLFORIC ACID SOLUTION |
DE102015202963A1 (en) * | 2015-02-18 | 2016-08-18 | Ulrich Schekulin | Method and device for chemically removing material by opening edge structuring |
CN107525061A (en) * | 2017-08-23 | 2017-12-29 | 大唐东北电力试验研究所有限公司 | A kind of power plant boiler boiler tube dirt, which measures, determines system and method |
CN107525062A (en) * | 2017-08-23 | 2017-12-29 | 大唐东北电力试验研究所有限公司 | A kind of thermal power plant's superheater tube sample dirt, which measures, determines system and method |
JP7177425B2 (en) * | 2017-12-28 | 2022-11-24 | 株式会社日本科学エンジニアリング | Electropolishing liquid for stainless steel |
CN110512217A (en) * | 2019-09-23 | 2019-11-29 | 中冶南方工程技术有限公司 | A kind of 201 austenitic stainless steel of cold rolling is without nitric acid acidwashing technique |
CN110592600A (en) * | 2019-09-23 | 2019-12-20 | 中冶南方工程技术有限公司 | Nitric acid-free pickling process for cold-rolled 430 ferrite stainless steel |
CN110528009A (en) * | 2019-09-23 | 2019-12-03 | 中冶南方工程技术有限公司 | A kind of 304 austenitic stainless steel of cold rolling is without nitric acid acidwashing technique |
KR102286367B1 (en) * | 2019-11-11 | 2021-08-05 | 주식회사 포스코 | Manufacturing method of stainless steel for polymer fuel cell seperator |
CN111621840A (en) * | 2020-05-26 | 2020-09-04 | 大连理工大学 | Bipolar electrochemical removal method for iron pollution on surface of titanium alloy |
KR102497442B1 (en) * | 2020-11-25 | 2023-02-08 | 주식회사 포스코 | Austenitic stainless steel for polymer fuel cell separator with improved contact resistance and manufacturing method thereof |
CN113788520A (en) * | 2021-10-08 | 2021-12-14 | 北京首钢吉泰安新材料有限公司 | Iron-chromium-aluminum pickling process, wastewater treatment method and wastewater treatment device |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE19773E (en) * | 1935-12-03 | Euectrocleanuxg process | ||
US2115005A (en) * | 1936-10-15 | 1938-04-26 | Samuel J Blaut | Electrochemical treatment of metal |
US2408424A (en) * | 1940-06-15 | 1946-10-01 | Monsanto Chemicals | Pickling steels |
US4214961A (en) * | 1979-03-01 | 1980-07-29 | Swiss Aluminium Ltd. | Method and apparatus for continuous electrochemical treatment of a metal web |
GB8517606D0 (en) * | 1985-07-12 | 1985-08-21 | Bekaert Sa Nv | Cleaning by electrochemical pickling |
US4813395A (en) * | 1987-04-27 | 1989-03-21 | Allied Corporation | Two-cycle engine and method of operation |
SU1723209A1 (en) * | 1988-11-30 | 1992-03-30 | Уральский научно-исследовательский институт трубной промышленности | Method for electrochemical pickling of steel articles |
JPH0726240B2 (en) * | 1989-10-27 | 1995-03-22 | ペルメレック電極株式会社 | Electrolytic pickling or electrolytic degreasing method for steel sheet |
AT399167B (en) * | 1991-06-10 | 1995-03-27 | Andritz Patentverwaltung | METHOD AND DEVICE FOR ELECTROLYTICALLY STICKING CONTINUOUSLY CONTINUOUS ELECTRICALLY CONDUCTIVE GOODS |
SE501561C2 (en) * | 1993-05-09 | 1995-03-13 | Swedish Pickling Ab | Method and apparatus for machining stainless steel wherein the current is passed through the steel strip in its thickness direction |
AT401183B (en) * | 1995-02-15 | 1996-07-25 | Andritz Patentverwaltung | METHOD FOR REGENERATING ELECTROLYTES, ESPECIALLY NA2SO4 FROM STAINLESS STEEL, IN PARTICULAR STAINLESS STEEL TAPES |
IT1276955B1 (en) * | 1995-10-18 | 1997-11-03 | Novamax Itb S R L | PICKLING AND PASSIVATION PROCESS OF STAINLESS STEEL WITHOUT THE USE OF NITRIC ACID |
IT1302202B1 (en) * | 1998-09-11 | 2000-07-31 | Henkel Kgaa | ELECTROLYTIC PICKLING PROCESS WITH SOLUTIONS FREE FROM ACIDONITRICO. |
GB2358194B (en) * | 2000-01-17 | 2004-07-21 | Ea Tech Ltd | Electrolytic treatment |
-
2000
- 2000-08-10 IT IT2000RM000456A patent/IT1317896B1/en active
-
2001
- 2001-08-06 AU AU2001282513A patent/AU2001282513A1/en not_active Abandoned
- 2001-08-06 AT AT01961136T patent/ATE262057T1/en not_active IP Right Cessation
- 2001-08-06 CN CNB018150063A patent/CN1318652C/en not_active Expired - Lifetime
- 2001-08-06 US US10/344,254 patent/US20040031696A1/en not_active Abandoned
- 2001-08-06 WO PCT/IT2001/000435 patent/WO2002012596A2/en active IP Right Grant
- 2001-08-06 EP EP01961136A patent/EP1307609B1/en not_active Expired - Lifetime
- 2001-08-06 DE DE60102387T patent/DE60102387T2/en not_active Expired - Lifetime
- 2001-08-06 ES ES01961136T patent/ES2220795T3/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
WO2002012596A9 (en) | 2002-11-28 |
ITRM20000456A1 (en) | 2002-02-10 |
CN1318652C (en) | 2007-05-30 |
ATE262057T1 (en) | 2004-04-15 |
CN1451058A (en) | 2003-10-22 |
ITRM20000456A0 (en) | 2000-08-10 |
EP1307609A2 (en) | 2003-05-07 |
US20040031696A1 (en) | 2004-02-19 |
DE60102387T2 (en) | 2005-03-24 |
DE60102387D1 (en) | 2004-04-22 |
ES2220795T3 (en) | 2004-12-16 |
AU2001282513A1 (en) | 2002-02-18 |
EP1307609B1 (en) | 2004-03-17 |
WO2002012596A2 (en) | 2002-02-14 |
WO2002012596A3 (en) | 2002-04-25 |
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