IT1190017B - PROCESS FOR THE SYNTHESIS OF ETERIMETILTERALCHILICI WITH CORROSION SUPPRESSION - Google Patents
PROCESS FOR THE SYNTHESIS OF ETERIMETILTERALCHILICI WITH CORROSION SUPPRESSIONInfo
- Publication number
- IT1190017B IT1190017B IT20573/86A IT2057386A IT1190017B IT 1190017 B IT1190017 B IT 1190017B IT 20573/86 A IT20573/86 A IT 20573/86A IT 2057386 A IT2057386 A IT 2057386A IT 1190017 B IT1190017 B IT 1190017B
- Authority
- IT
- Italy
- Prior art keywords
- synthesis
- methanol
- unreacted hydrocarbons
- eterimetilteralchilici
- azeotropic mixture
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 3
- 238000003786 synthesis reaction Methods 0.000 title abstract 3
- 238000005260 corrosion Methods 0.000 title abstract 2
- 230000007797 corrosion Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 230000001629 suppression Effects 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 9
- 229930195733 hydrocarbon Natural products 0.000 abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
Abstract
Methyl-tert-alkyl ethers coming from a synthesis section are separated from unreacted hydrocarbons by means of a rectification operation, in which the unreacted hydrocarbons are drawn as overhead fraction, in the form of an azeotropic mixture with methanol. To the purpose of removing methanol, and of therefore allowing a suitable use of said unreacted hydrocarbons, the azeotropic mixture is washed with water inside a washing column, which gets very rapidly corroded. The invention solves the corrosion problem by resorting to the removal of oxygen from the hydrocarbon charge and/or of methanol, before these are sent to the synthesis.
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT20573/86A IT1190017B (en) | 1986-05-27 | 1986-05-27 | PROCESS FOR THE SYNTHESIS OF ETERIMETILTERALCHILICI WITH CORROSION SUPPRESSION |
EP87903869A EP0311614A1 (en) | 1986-05-27 | 1987-05-07 | Process for the synthesis of methyl-tert-alkyl ethers with suppression of corrosion |
HU873325A HUT47892A (en) | 1986-05-27 | 1987-05-07 | Process for producing methyl-terc.alkyl-ethers without corrosion |
JP62503688A JPH01502748A (en) | 1986-05-27 | 1987-05-07 | Synthesis method of methyl tertiary alkyl ether that suppresses corrosion |
PCT/EP1987/000257 WO1987007260A1 (en) | 1986-05-27 | 1987-05-07 | Process for the synthesis of methyl-tert-alkyl ethers with suppression of corrosion |
BR8707693A BR8707693A (en) | 1986-05-27 | 1987-05-07 | PROCESS FOR THE SYNTHESIS OF METHYLTERALKYL ETHERS WITH CORROSION SUPPRESSION |
GR870748A GR870748B (en) | 1986-05-27 | 1987-05-13 | Process for the synthesis of methyl - tert alkyl ethers with suppression of corrosion |
CS354287A CS273639B2 (en) | 1986-05-27 | 1987-05-15 | Method of methyl-tertiary alkylethers synthesis |
ES8701707A ES2006491A6 (en) | 1986-05-27 | 1987-05-22 | Process for the synthesis of methyl-tert-alkyl ethers with suppression of corrosion. |
PL1987265892A PL150602B1 (en) | 1986-05-27 | 1987-05-25 | A method of methyl-tetriary-alkyl ethers production |
DD87303104A DD260924A5 (en) | 1986-05-27 | 1987-05-25 | PROCESS FOR THE PREPARATION OF METHYL TERT. alkyl ethers |
YU00952/87A YU95287A (en) | 1986-05-27 | 1987-05-26 | Process for synthesis of methyl-tert-alkyl-ethers with corosion suppresion |
NO880344A NO167198C (en) | 1986-05-27 | 1988-01-27 | PROCEDURE FOR THE SYNTHESIS OF METHYL-TERT-ALKYLETERS. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT20573/86A IT1190017B (en) | 1986-05-27 | 1986-05-27 | PROCESS FOR THE SYNTHESIS OF ETERIMETILTERALCHILICI WITH CORROSION SUPPRESSION |
Publications (2)
Publication Number | Publication Date |
---|---|
IT8620573A0 IT8620573A0 (en) | 1986-05-27 |
IT1190017B true IT1190017B (en) | 1988-02-10 |
Family
ID=11169005
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT20573/86A IT1190017B (en) | 1986-05-27 | 1986-05-27 | PROCESS FOR THE SYNTHESIS OF ETERIMETILTERALCHILICI WITH CORROSION SUPPRESSION |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP0311614A1 (en) |
JP (1) | JPH01502748A (en) |
BR (1) | BR8707693A (en) |
CS (1) | CS273639B2 (en) |
DD (1) | DD260924A5 (en) |
ES (1) | ES2006491A6 (en) |
GR (1) | GR870748B (en) |
HU (1) | HUT47892A (en) |
IT (1) | IT1190017B (en) |
PL (1) | PL150602B1 (en) |
WO (1) | WO1987007260A1 (en) |
YU (1) | YU95287A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5237109A (en) * | 1991-10-10 | 1993-08-17 | Phillips Petroleum Company | Etherification process |
RU2544553C1 (en) * | 2013-12-25 | 2015-03-20 | Открытое акционерное общество "Газпромнефть-Московский НПЗ" (ОАО "Газпромнефть-МНПЗ") | Method of obtaining high-octane additive to automobile petrol |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1259337A (en) * | 1982-09-20 | 1989-09-12 | Joe Van Pool | Combined ether and alkylate production |
-
1986
- 1986-05-27 IT IT20573/86A patent/IT1190017B/en active
-
1987
- 1987-05-07 WO PCT/EP1987/000257 patent/WO1987007260A1/en not_active Application Discontinuation
- 1987-05-07 JP JP62503688A patent/JPH01502748A/en active Pending
- 1987-05-07 BR BR8707693A patent/BR8707693A/en unknown
- 1987-05-07 HU HU873325A patent/HUT47892A/en unknown
- 1987-05-07 EP EP87903869A patent/EP0311614A1/en not_active Ceased
- 1987-05-13 GR GR870748A patent/GR870748B/en unknown
- 1987-05-15 CS CS354287A patent/CS273639B2/en unknown
- 1987-05-22 ES ES8701707A patent/ES2006491A6/en not_active Expired
- 1987-05-25 DD DD87303104A patent/DD260924A5/en not_active IP Right Cessation
- 1987-05-25 PL PL1987265892A patent/PL150602B1/en unknown
- 1987-05-26 YU YU00952/87A patent/YU95287A/en unknown
Also Published As
Publication number | Publication date |
---|---|
HUT47892A (en) | 1989-04-28 |
IT8620573A0 (en) | 1986-05-27 |
GR870748B (en) | 1987-09-23 |
JPH01502748A (en) | 1989-09-21 |
CS273639B2 (en) | 1991-03-12 |
EP0311614A1 (en) | 1989-04-19 |
DD260924A5 (en) | 1988-10-12 |
CS354287A2 (en) | 1990-08-14 |
BR8707693A (en) | 1989-08-15 |
PL150602B1 (en) | 1990-06-30 |
WO1987007260A1 (en) | 1987-12-03 |
PL265892A1 (en) | 1988-07-21 |
YU95287A (en) | 1988-06-30 |
ES2006491A6 (en) | 1989-05-01 |
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