IN2014MN01000A - - Google Patents

Info

Publication number
IN2014MN01000A
IN2014MN01000A IN1000MUN2014A IN2014MN01000A IN 2014MN01000 A IN2014MN01000 A IN 2014MN01000A IN 1000MUN2014 A IN1000MUN2014 A IN 1000MUN2014A IN 2014MN01000 A IN2014MN01000 A IN 2014MN01000A
Authority
IN
India
Prior art keywords
oil
present
water emulsion
emulsion composition
emulsifier
Prior art date
Application number
Inventor
Yuki Sugiyama
Tomoko Sato
Ken Shoji
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Publication of IN2014MN01000A publication Critical patent/IN2014MN01000A/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/91—Graft copolymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00—Formulations or additives for perfume preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0052—Preparation of gels
    • B01J13/0065—Preparation of gels containing an organic phase
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
    • C08F220/286—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/062—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/34—Higher-molecular-weight carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/10—General cosmetic use
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/95—Involves in-situ formation or cross-linking of polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/005—Preparations for sensitive skin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Colloid Chemistry (AREA)

Abstract

The present invention is a core corona type microgel emulsifier formed from a copolymer obtained by polymerizing a polyethylene oxide macromonomer a hydrophobic monomer and a cross linking monomer under specific conditions. The present invention is also an oil in water emulsion composition characterized in that the core corona type microgel emulsifier is used to emulsify the oil in water emulsion composition. The purpose of the present invention is to provide a novel core corona type microgel emulsifier used for producing an oil in water emulsion composition which exhibits excellent emulsion stability and temporal stability causes little skin irritation or feeling of coarseness is not powdery or sticky when applied is fresh and exerts an aroma sustaining effect. Another purpose of the present invention is to provide an oil in water emulsion composition which is emulsified by means of the aforementioned emulsifier.
IN1000MUN2014 2011-12-22 2012-10-17 IN2014MN01000A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2011281294 2011-12-22
JP2012219957A JP5207424B1 (en) 2011-12-22 2012-10-02 Corona-core type microgel emulsifier and oil-in-water emulsion composition
PCT/JP2012/076781 WO2013094298A1 (en) 2011-12-22 2012-10-17 Core-corona type microgel emulsifier, and oil-in-water emulsion composition

Publications (1)

Publication Number Publication Date
IN2014MN01000A true IN2014MN01000A (en) 2015-05-22

Family

ID=48668199

Family Applications (1)

Application Number Title Priority Date Filing Date
IN1000MUN2014 IN2014MN01000A (en) 2011-12-22 2012-10-17

Country Status (12)

Country Link
US (2) US9539553B2 (en)
EP (1) EP2796193B1 (en)
JP (1) JP5207424B1 (en)
KR (1) KR101969984B1 (en)
CN (1) CN104159662B (en)
BR (1) BR112014013988B1 (en)
ES (1) ES2705999T3 (en)
HK (1) HK1200397A1 (en)
IN (1) IN2014MN01000A (en)
RU (1) RU2607088C1 (en)
TW (1) TWI558416B (en)
WO (1) WO2013094298A1 (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3082711B1 (en) 2013-12-18 2021-09-08 L'Oréal Composition of pickering emulsion comprising low amount of alcohol
US9987818B2 (en) 2014-01-16 2018-06-05 Research Foundation Of The City University Of New York Center-side method of producing superhydrophobic surface
JP6389047B2 (en) * 2014-03-10 2018-09-12 株式会社アリミノ Hair and skin cosmetics
JP5913475B2 (en) * 2014-08-06 2016-04-27 株式会社 資生堂 Raw materials for cosmetics
KR101757245B1 (en) * 2015-07-28 2017-07-13 한국과학기술원 Pickering emulsion and method for preparation thereof
CN108348443B (en) * 2015-09-30 2021-08-03 株式会社资生堂 Powder-in-oil-in-water type composition
JP7088830B2 (en) * 2016-04-28 2022-06-21 株式会社 資生堂 Underwater oil type emulsified cosmetic
KR102439974B1 (en) * 2016-09-27 2022-09-02 가부시키가이샤 시세이도 Cosmetic raw materials and oil-in-water emulsified cosmetics using core-corona microparticles
KR102251072B1 (en) * 2016-10-20 2021-05-11 가부시키가이샤 시세이도 Oil-in-water emulsion composition
JP6985025B2 (en) * 2017-03-29 2021-12-22 株式会社 資生堂 Underwater oil type cosmetics
JP7018723B2 (en) * 2017-07-28 2022-02-14 ポーラ化成工業株式会社 Emulsifying composition
JP6968628B2 (en) * 2017-09-04 2021-11-17 ポーラ化成工業株式会社 Emulsifying composition
JP7126345B2 (en) * 2017-11-20 2022-08-26 ポーラ化成工業株式会社 Emulsion composition, production method, evaluation method and design method thereof, and polymer emulsifier
WO2019182126A1 (en) * 2018-03-23 2019-09-26 株式会社 資生堂 Core-corona polymer particles
EP3770196A4 (en) * 2018-03-23 2021-12-15 Shiseido Company, Ltd. Cosmetic ingredient using core-corona polymer particles and oil-in-water emulsion cosmetic
CN111918895B (en) * 2018-03-23 2023-07-14 株式会社资生堂 Cosmetic raw material using core-shell polymer particles and oil-in-water emulsion cosmetic
CN111902441B (en) * 2018-03-23 2023-06-27 株式会社资生堂 Cosmetic raw material using core-shell polymer particles and oil-in-water emulsion cosmetic
JP7237463B2 (en) * 2018-05-24 2023-03-13 ポーラ化成工業株式会社 Pickering emulsion containing acrylic polymer
JP7356998B2 (en) * 2018-10-09 2023-10-05 株式会社 資生堂 Water-in-oil emulsion composition
JPWO2021125219A1 (en) * 2019-12-19 2021-06-24
JPWO2022210144A1 (en) * 2021-03-31 2022-10-06
CN115120520A (en) * 2022-05-06 2022-09-30 彭氏(惠州)实业发展有限公司 Cosmetic composition comprising myrtle ketone and cosmetic use thereof
WO2023219108A1 (en) * 2022-05-13 2023-11-16 株式会社 資生堂 Oil-in-water composition

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DE59804248D1 (en) 1997-03-25 2002-07-04 Beiersdorf Ag EMULGATOR-FREE FINE DISPERSE SYSTEMS OF THE WATER-IN-OIL TYPE
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JP4267319B2 (en) * 2002-12-26 2009-05-27 株式会社資生堂 Oil-in-water emulsion composition
WO2004096422A1 (en) * 2003-04-30 2004-11-11 The University Of Sheffield Particulate emulsifiers, emulsions and uses thereof
JP2005015623A (en) * 2003-06-26 2005-01-20 Shiseido Co Ltd Organic solvent swelling microgel and its preparation method
JP2006036763A (en) 2004-06-25 2006-02-09 Kao Corp Water-in-oil emulsion composition
JP2006161026A (en) 2004-11-09 2006-06-22 Shiseido Co Ltd Organic solvent-swelling micro gel and method for producing the same
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JP2007238521A (en) * 2006-03-09 2007-09-20 Shiseido Co Ltd Clathrate and external preparation for skin containing the same
JP2007302566A (en) * 2006-05-08 2007-11-22 Shiseido Co Ltd Sebum adsorbent and skin preparation for external use blended with the same
JP2007302712A (en) * 2006-05-08 2007-11-22 Shiseido Co Ltd Foam quality-improver and detergent containing the same
JP5506130B2 (en) 2006-06-12 2014-05-28 株式会社 資生堂 Oil-in-water emulsion
KR101590646B1 (en) 2007-04-26 2016-02-01 가부시키가이샤 시세이도 Oil-in-water emulsion composition and method for producing the same

Also Published As

Publication number Publication date
US9539553B2 (en) 2017-01-10
JP5207424B1 (en) 2013-06-12
TW201334794A (en) 2013-09-01
KR20140113900A (en) 2014-09-25
CN104159662B (en) 2016-05-11
HK1200397A1 (en) 2015-08-07
TWI558416B (en) 2016-11-21
EP2796193B1 (en) 2018-12-05
JP2013147486A (en) 2013-08-01
EP2796193A4 (en) 2016-01-20
US9539554B2 (en) 2017-01-10
CN104159662A (en) 2014-11-19
WO2013094298A1 (en) 2013-06-27
EP2796193A1 (en) 2014-10-29
ES2705999T3 (en) 2019-03-27
BR112014013988A2 (en) 2017-06-13
US20160001244A1 (en) 2016-01-07
RU2607088C1 (en) 2017-01-10
KR101969984B1 (en) 2019-04-17
BR112014013988B1 (en) 2020-09-24
US20140343170A1 (en) 2014-11-20

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