IN2012DN03089A - - Google Patents

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Publication number
IN2012DN03089A
IN2012DN03089A IN3089DEN2012A IN2012DN03089A IN 2012DN03089 A IN2012DN03089 A IN 2012DN03089A IN 3089DEN2012 A IN3089DEN2012 A IN 3089DEN2012A IN 2012DN03089 A IN2012DN03089 A IN 2012DN03089A
Authority
IN
India
Prior art keywords
reactive diluent
monomers
blend
diluent monomer
photoinitiator
Prior art date
Application number
Inventor
Xiaosong Wu
Timothy Edward Bishop
John Monroe Zimmerman
Long Han
Original Assignee
Dsm Ip Assets Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dsm Ip Assets Bv filed Critical Dsm Ip Assets Bv
Publication of IN2012DN03089A publication Critical patent/IN2012DN03089A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/104—Coating to obtain optical fibres
    • C03C25/1065—Multiple coatings
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/326—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
    • C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Wood Science & Technology (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The invention relates to radiation curable compositions. The invention provides radiation curable optical fiber primary coating compositions comprising an oligomer, a reactive diluent monomer blend comprising at least two reactive diluents monomers, and at least one photoinitiator, wherein each of said monomers in said blend has the formula (I) wherein x is an integer of from 1 to 6; n is an integer of from 1 to 5; and each Y, which may be the same or different, is independently selected from the group consisting of hydrogen, a C1 to C12 alkyl group and an alkarylalkoxylated acrylate radical; and at least one photoinitiator; said reactive diluent monomer blend being substantially free of non-aryl reactive diluent monomers; wherein when an aryl reactive diluent monomer is present that has a molecular weight less than about 300, it is present at no more than about 10 wt. % of the total formulation.
IN3089DEN2012 2009-10-09 2010-10-08 IN2012DN03089A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US27259609P 2009-10-09 2009-10-09
US25032909P 2009-10-09 2009-10-09
PCT/US2010/002718 WO2011049607A1 (en) 2009-10-09 2010-10-08 Radiation curable coating for optical fiber

Publications (1)

Publication Number Publication Date
IN2012DN03089A true IN2012DN03089A (en) 2015-07-31

Family

ID=43446791

Family Applications (1)

Application Number Title Priority Date Filing Date
IN3089DEN2012 IN2012DN03089A (en) 2009-10-09 2010-10-08

Country Status (10)

Country Link
US (1) US20120128313A1 (en)
EP (1) EP2473455B1 (en)
JP (1) JP5625186B2 (en)
KR (1) KR101515691B1 (en)
CN (1) CN102471149B (en)
BR (1) BR112012008214B1 (en)
DK (1) DK2473455T3 (en)
IN (1) IN2012DN03089A (en)
RU (1) RU2604227C2 (en)
WO (1) WO2011049607A1 (en)

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WO2013181484A1 (en) 2012-05-31 2013-12-05 Corning Incorporated Stiff interlayers for laminated glass structures
WO2014088926A1 (en) * 2012-12-03 2014-06-12 Dsm Ip Assets Bv D1530 radiation curable primary coatings for optical fiber
JP2014118319A (en) * 2012-12-14 2014-06-30 Sumitomo Electric Ind Ltd Resin composition for coating optical fiber, optical fiber strand and method for manufacturing optical fiber strand
US9383511B2 (en) * 2013-05-02 2016-07-05 Corning Incorporated Optical fiber with large mode field diameter and low microbending losses
US9810838B2 (en) * 2013-09-12 2017-11-07 Corning Incorporated Fiber coatings with low young's modulus and high tear strength
US9244221B1 (en) * 2013-12-10 2016-01-26 Corning Incorporated Low modulus primary coatings for optical fibers
US10689521B2 (en) * 2014-11-18 2020-06-23 Ofs Fitel, Llc Low density UV-curable optical fiber coating, fiber made therewith, and method of fiber manufacture
US10350861B2 (en) 2015-07-31 2019-07-16 Corning Incorporated Laminate structures with enhanced damping properties
US10598881B2 (en) 2015-12-16 2020-03-24 Prysmian S.P.A Optical fibre with enhanced high temperature resistance
JP6750463B2 (en) 2016-11-07 2020-09-02 住友電気工業株式会社 Optical fiber core
US20180127593A1 (en) * 2016-11-08 2018-05-10 Corning Incorporated Fiber coatings with low modulus and high critical stress
JP2018077303A (en) * 2016-11-08 2018-05-17 住友電気工業株式会社 Coated optical fiber
WO2018220605A1 (en) * 2017-06-02 2018-12-06 Dsm Ip Assets Bv Thermally resistant radiation curable coatings for optical fiber
NL2020771B1 (en) 2018-04-16 2019-10-23 Artofil Coatings B V Optical fibre coating composition, a method for applying the same, and an optical fibre comprising the same
CN112203995B (en) * 2018-06-01 2023-02-21 科思创(荷兰)有限公司 Radiation curable compositions for coating optical fibers via alternating oligomers and coatings produced therefrom
JP7139432B2 (en) * 2018-08-31 2022-09-20 日本特殊コーティング株式会社 Radiation curable resin composition
JPWO2022138119A1 (en) 2020-12-21 2022-06-30
JPWO2022168476A1 (en) 2021-02-04 2022-08-11
US20220411563A1 (en) * 2021-06-28 2022-12-29 Covestro Llc Novel dual cure 3d printing resins
WO2023139898A1 (en) 2022-01-20 2023-07-27 住友電気工業株式会社 Resin composition, optical fiber, optical fiber manufacturing method, optical fiber ribbon, and optical fiber cable
WO2023162570A1 (en) 2022-02-24 2023-08-31 住友電気工業株式会社 Resin composition, optical fiber, optical fiber manufacturing method, optical fiber ribbon, and optical fiber cable
WO2023162569A1 (en) 2022-02-24 2023-08-31 住友電気工業株式会社 Resin composition, optical fiber, optical fiber manufacturing method, optical fiber ribbon, and optical fiber cable
CN117209168B (en) * 2023-05-12 2024-03-15 上海飞凯材料科技股份有限公司 Optical fiber coating composition, optical fiber and preparation method thereof

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KR101105083B1 (en) * 2006-12-14 2012-01-16 디에스엠 아이피 어셋츠 비.브이. D1379 p radiation curable primary coating on optical fiber
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JP5194264B2 (en) 2006-12-14 2013-05-08 ディーエスエム アイピー アセッツ ビー．ブイ． Radiation curable secondary coating for D1369D optical fiber
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Also Published As

Publication number Publication date
DK2473455T3 (en) 2016-08-01
JP2013501125A (en) 2013-01-10
JP5625186B2 (en) 2014-11-19
WO2011049607A1 (en) 2011-04-28
RU2012112929A (en) 2013-10-10
KR101515691B1 (en) 2015-04-27
US20120128313A1 (en) 2012-05-24
CN102471149B (en) 2015-11-25
EP2473455A1 (en) 2012-07-11
BR112012008214B1 (en) 2019-11-19
KR20120066033A (en) 2012-06-21
BR112012008214A2 (en) 2016-03-08
RU2604227C2 (en) 2016-12-10
EP2473455B1 (en) 2016-06-29
CN102471149A (en) 2012-05-23

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