IL45023A - Carbothiolates and thiocarbothiolates of alkyl-hexahydro-1hazepines their preparation and their use as herbicides - Google Patents
Carbothiolates and thiocarbothiolates of alkyl-hexahydro-1hazepines their preparation and their use as herbicidesInfo
- Publication number
- IL45023A IL45023A IL45023A IL4502374A IL45023A IL 45023 A IL45023 A IL 45023A IL 45023 A IL45023 A IL 45023A IL 4502374 A IL4502374 A IL 4502374A IL 45023 A IL45023 A IL 45023A
- Authority
- IL
- Israel
- Prior art keywords
- spp
- substituted
- carbothiolate
- hexahydroazepine
- dimethyl
- Prior art date
Links
- 239000004009 herbicide Substances 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- -1 thiol chloroformate ester Chemical class 0.000 claims abstract description 20
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 3
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 13
- 230000002363 herbicidal effect Effects 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 150000002367 halogens Chemical group 0.000 claims description 4
- 125000006283 4-chlorobenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1Cl)C([H])([H])* 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 239000011593 sulfur Chemical group 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 6
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- XYOVOXDWRFGKEX-UHFFFAOYSA-N azepine Chemical compound N1C=CC=CC=C1 XYOVOXDWRFGKEX-UHFFFAOYSA-N 0.000 abstract description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 2
- DUCSYPFWTRWGCC-UHFFFAOYSA-M CC1N(CCCCC1C)C(=S)[S-].[Na+] Chemical compound CC1N(CCCCC1C)C(=S)[S-].[Na+] DUCSYPFWTRWGCC-UHFFFAOYSA-M 0.000 abstract 1
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- 101710152694 Cysteine synthase 2 Proteins 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
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- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
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- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical class CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 150000001469 hydantoins Chemical group 0.000 description 1
- 150000002460 imidazoles Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
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- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- QNMLMAVEXUCXRG-UHFFFAOYSA-N oxadiazinane-4,5-dione Chemical group O=C1CONNC1=O QNMLMAVEXUCXRG-UHFFFAOYSA-N 0.000 description 1
- SDRLFDJOSQLRPB-UHFFFAOYSA-N oxadiazine-4,5-dione Chemical group O=C1CON=NC1=O SDRLFDJOSQLRPB-UHFFFAOYSA-N 0.000 description 1
- 150000004866 oxadiazoles Chemical group 0.000 description 1
- YDCVQGAUCOROHB-UHFFFAOYSA-N oxadiazolidine-4,5-dione Chemical group O=C1NNOC1=O YDCVQGAUCOROHB-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000001377 petroselinum spp. Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical group P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical group [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
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- 239000002798 polar solvent Substances 0.000 description 1
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- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 150000004892 pyridazines Chemical group 0.000 description 1
- 150000005299 pyridinones Chemical class 0.000 description 1
- 150000003230 pyrimidines Chemical group 0.000 description 1
- 150000008318 pyrimidones Chemical group 0.000 description 1
- NYCVCXMSZNOGDH-UHFFFAOYSA-N pyrrolidine-1-carboxylic acid Chemical group OC(=O)N1CCCC1 NYCVCXMSZNOGDH-UHFFFAOYSA-N 0.000 description 1
- 150000003235 pyrrolidines Chemical group 0.000 description 1
- 150000004040 pyrrolidinones Chemical group 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003440 styrenes Chemical group 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
- 229960000278 theophylline Drugs 0.000 description 1
- OLPRIZQBWZMBAS-UHFFFAOYSA-N thiadiazolidine 1,1-dioxide Chemical group O=S1(=O)CCNN1 OLPRIZQBWZMBAS-UHFFFAOYSA-N 0.000 description 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 1
- 150000003582 thiophosphoric acids Chemical class 0.000 description 1
- 150000003585 thioureas Chemical group 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 229940047183 tribulus Drugs 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
- C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
- C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19732333397 DE2333397A1 (de) | 1973-06-30 | 1973-06-30 | Carbothiolate substituierter azepine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL45023A0 IL45023A0 (en) | 1974-09-10 |
| IL45023A true IL45023A (en) | 1977-10-31 |
Family
ID=5885606
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL45023A IL45023A (en) | 1973-06-30 | 1974-06-12 | Carbothiolates and thiocarbothiolates of alkyl-hexahydro-1hazepines their preparation and their use as herbicides |
Country Status (19)
| Country | Link |
|---|---|
| JP (1) | JPS5036632A (en, 2012) |
| AT (1) | AT334681B (en, 2012) |
| BE (1) | BE817009A (en, 2012) |
| BG (1) | BG21369A3 (en, 2012) |
| BR (1) | BR7405279D0 (en, 2012) |
| DD (1) | DD111780A5 (en, 2012) |
| DE (1) | DE2333397A1 (en, 2012) |
| DK (1) | DK348674A (en, 2012) |
| ES (1) | ES427821A1 (en, 2012) |
| FR (1) | FR2235120B1 (en, 2012) |
| GB (1) | GB1465112A (en, 2012) |
| HU (1) | HU168731B (en, 2012) |
| IL (1) | IL45023A (en, 2012) |
| IT (1) | IT1049293B (en, 2012) |
| NL (1) | NL7408697A (en, 2012) |
| OA (1) | OA04732A (en, 2012) |
| PL (1) | PL89746B1 (en, 2012) |
| SE (1) | SE7408583L (en, 2012) |
| ZA (1) | ZA744040B (en, 2012) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS607628B2 (ja) * | 1976-01-30 | 1985-02-26 | クミアイ化学工業株式会社 | チオールカルバミン酸エステル |
| DE2632676A1 (de) * | 1976-07-16 | 1978-01-19 | Schering Ag | Trimethylperhydroazepin-1-thiocarbonsaeure-s-aethylester, verfahren zur herstellung dieser verbindungen sowie diese enthaltendes herbizides mittel |
| JPS5823602A (ja) * | 1981-08-04 | 1983-02-12 | Asahi Chem Ind Co Ltd | チオ−ルカ−バメ−ト系水田用除草剤組成物 |
-
1973
- 1973-06-30 DE DE19732333397 patent/DE2333397A1/de active Pending
-
1974
- 1974-06-12 IL IL45023A patent/IL45023A/en unknown
- 1974-06-18 JP JP49068798A patent/JPS5036632A/ja active Pending
- 1974-06-24 ZA ZA00744040A patent/ZA744040B/xx unknown
- 1974-06-26 BG BG27082A patent/BG21369A3/xx unknown
- 1974-06-27 BR BR5279/74A patent/BR7405279D0/pt unknown
- 1974-06-27 OA OA55233A patent/OA04732A/xx unknown
- 1974-06-27 NL NL7408697A patent/NL7408697A/xx unknown
- 1974-06-28 DD DD179577A patent/DD111780A5/xx unknown
- 1974-06-28 ES ES427821A patent/ES427821A1/es not_active Expired
- 1974-06-28 IT IT51823/74A patent/IT1049293B/it active
- 1974-06-28 GB GB2875374A patent/GB1465112A/en not_active Expired
- 1974-06-28 AT AT536774A patent/AT334681B/de not_active IP Right Cessation
- 1974-06-28 PL PL1974172259A patent/PL89746B1/xx unknown
- 1974-06-28 HU HUBA3098A patent/HU168731B/hu unknown
- 1974-06-28 DK DK348674A patent/DK348674A/da unknown
- 1974-06-28 BE BE146007A patent/BE817009A/xx unknown
- 1974-06-28 SE SE7408583A patent/SE7408583L/xx unknown
- 1974-06-28 FR FR7422693A patent/FR2235120B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT1049293B (it) | 1981-01-20 |
| NL7408697A (nl) | 1975-01-02 |
| FR2235120B1 (en, 2012) | 1978-01-13 |
| AT334681B (de) | 1976-01-25 |
| IL45023A0 (en) | 1974-09-10 |
| ZA744040B (en) | 1975-07-30 |
| ES427821A1 (es) | 1976-08-01 |
| FR2235120A1 (en, 2012) | 1975-01-24 |
| DK348674A (en, 2012) | 1975-02-24 |
| DE2333397A1 (de) | 1975-01-23 |
| DD111780A5 (en, 2012) | 1975-03-12 |
| SE7408583L (en, 2012) | 1975-01-02 |
| OA04732A (fr) | 1980-08-31 |
| HU168731B (en) | 1976-07-28 |
| PL89746B1 (en, 2012) | 1976-12-31 |
| BE817009A (fr) | 1974-12-30 |
| BR7405279D0 (pt) | 1975-01-07 |
| GB1465112A (en) | 1977-02-23 |
| BG21369A3 (en, 2012) | 1976-05-20 |
| JPS5036632A (en, 2012) | 1975-04-05 |
| ATA536774A (de) | 1976-05-15 |
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