IL35167A - Polyalkylene terephthalate molding resin and process for making the same - Google Patents

Polyalkylene terephthalate molding resin and process for making the same

Info

Publication number
IL35167A
IL35167A IL35167A IL3516770A IL35167A IL 35167 A IL35167 A IL 35167A IL 35167 A IL35167 A IL 35167A IL 3516770 A IL3516770 A IL 3516770A IL 35167 A IL35167 A IL 35167A
Authority
IL
Israel
Prior art keywords
terephthalate
polyalkylene terephthalate
composition
reinforcing filler
resin
Prior art date
Application number
IL35167A
Other languages
Hebrew (he)
Other versions
IL35167A0 (en
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25318174&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=IL35167(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Celanese Corp filed Critical Celanese Corp
Publication of IL35167A0 publication Critical patent/IL35167A0/en
Publication of IL35167A publication Critical patent/IL35167A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

RESIN AND PROCESS FOR THE SAME This relates to a resin d to method of producing The invention is directed to improved molding resin comprising an intimate blend of a reinforcing filler and a polybutylene terep e or a polypropylene The resin of this invention has significant processing and property advantages over an e filled molding Polyethylene terephthalate polymer containing reinforcing fillers have been used as molding resins for various end The use of filled polyethylene terephthalate polymer for molding purposes has processing disadvantages in requiring high processing high mold long cycle times in the mold and usually requires a nucleating or other additive to provide an adequate polymer flow in the The preparation of polyethylene terep late polymers as well as polypropylene terep and polybutylene polymers are described in entitled Polymeric Linear Tereph Polyethylene tereph thalie have been use for film products and molding It area of their outstanding physical properties to the exclusion of the other linear terephthalic esters especially polypropylene terep thal te and terephthalate It has now been discovered that molding resins are provided by the intimate blending of reinforcing fillers with polypropylene terephthalate or The improved molding resins of this invention have been found to require lover processing lower mold shorter cycle time and no nucleating agent when compared with equivalent filled polyethylene terep the excellent processability of the molding resins of this invention is accorapanied by a balance of properties it even more desirable than polyethylene For glass filled polybutylene terephthalate resin has almost identical strength compared to the equivalent glass filled polyethylene phthalate but substantially higher lower water better creep properties and desirable The molding resins of this invention the processing problems with the equivalent filled polyethylene terephthalate molding resin as well viding a balance of properties w ch are significantly improved over those of polyethylene The base of the molding resins of this invention is a polyalkylene terephthalate polymer selected from the group consisting of polypropylene terephthalate and the reaction product of or a ester of terephthalic acid dimethyl and glycols having 3 and 4 carbon Suitable include trime hylene butylene glycol and the In the production of the polymers of this invention polypropylene or polybutylene the appropriate bis terephthalate is produced as the The monomeric bis terephthalate can be prepared by at least tvro different In one the dialkyl ester of terephthalic acid in the alkyl radicals can contain from 1 to 7 carbon atoms can generally be reacted with about two molecular proportions of the glycols It is preferred to use higher proportions of the in excess of two molecular proportions of the glycol per molecular proportion of the terephthalate since by using such the initial transesterification caused to take place more rapidly and The reaction for the transes erification i3 conducted conditions of elevated temperatures and subat or super eric the desired tures of the reaction can from about the boiling temperature of the reaction mixture to as high as if After the polymer base is the reinforcing types of If the reinforcing fillers can be blended with the monomers in polymerization reaction long as the polymerization reaction is not The types of fillers which can be used include among others glass fibers or continuous asbestos cellulosic cotton fabric synthetic metallic powders and the The amount of reinforcing filler can range from about 2 to about 80 weight per preferably from about 5 to about 60 weight per cent based on the total molding Other additives for appearance and property improvements can be incorporated into the molding resins of this invention such as hardeners and the The following examples will serve to illustrate the invention without limiting the EXAMPLE I Fifteen pounds of polybutylene terephthalate having an intrinsic viscosity of was added to pounds of glass tumble blended for 1 minute and then extrusion blended by force feeding through a one inch single screw extruder with a strand The temperatures of the extruder and die were set at 510 and barrel to The strands were ground in a milling type mixer to pass through a large screen mesh or Polypropylene terephthalate was blended with glass fibers and extruded in a similar For comparative purposes polyethylene terephthalate facilitate the crystallization of polyethylene terephthalat in the weight per cent of talc was added to the Processing of the polyethylene terephthalate mold ing resin was exactly identical to the polybutylene thalate molding resin above except for slightly higher temperature requirements in the extrusion blending The above molding resins were molded into test specimens and tested for the following properties as described in the Tables TABLE I PROPERTIES OF GLASS FILLED POLYBUTYLENE GLASS FILLED POLYETHYLENE TEREPH Material Polyethylene Glass Content Processing Temperature 260 Cycle Time 52 Mold Temperature Base Molded Bar Notched Izod Tensile Impact 28 Deflection 264 psi 432 Tensile Strength Strength Flexural Modulus x Material Polyethylene Terephthalate 24 Water saturation Colo Hardness Rockwell MAT Gla Pro Cyc Not Hea Tensile Strength Strength Flexural ate resins have significant over the equivalent glass Compared to polyethylene polypropylene and polybutylene terephthalate can 5 be processed at lower at a significantly lower cycle and a lower mold It has significantly high notched and tensile less shrinkage and lower water All of these improved properties of the glass filled polypropylene and polybutylene terephthalate resins are highly 10 desirable and significant when compared to equivalent glass polyethylene terephthalate EXAMPLES similar manner as in Example polybutylene was blended with glass fibers in various 15 The properties of molded bars were obtained as described in III 0 20 30 Specific G y Intrinsic Viscosity Tensile 8300 Tensile 13 Flexural psi Flexural psi x 105 x 105 x 10 Tensile psi 8100 Tensile 13 12 Impact psi a no ched b Rockwell M 88 83 Distortion a 66 psi b 264 psi 73 209 213 a b of which variations by those skilled in art the scope of the following without departing from the spirit insufficientOCRQuality

Claims (10)

CLAIMS: ■WHAT IS CLAIMED IS
1. A molding resin comprising an intimaite blend of from about 2 to about 80 weight per cent of the total composition of a reinforcing filler and from about 20 to about 98 weight. per P cent of the total composition of a polyalkylene terephthalate polymer .having an intrinsic viscosity in the range from about 0.2 to about 1.2 wherein said polyalkylene terephthalate is selected from the group consisting of polypropylene terephthalate and polybutylene terephthalate.
2. The composition of claim 1 wherein the intrinsic viscosity of said polyalkylene terephthalate ranges from about 0.5 to about 1.0..
3. The composition of claim 2 wherein the reinforcing filler is present in amounts ranging from 5 to 60 weight per cent of the total resin.
4. The composition of claim 3 wherein the polyalkylene terephthalate is polybutylene terephthalate.
5. The composition of claim 4 wherein the reinforcing filler is glass fiber.
6. A method for producing an improved resin comprising intimately blending from about 2 to about 80 weight per cent of the total composition of a reinforcing filler with from about 20 to about 98 weight per cent of the total composition of a polyalkylene terephthalate polymer having an intrinsic viscosity in the range from about 0.2 to about 1.2 wherein said polyalkylene terephthalate is selected from the group consisting of polypropylene terephthalate and polybutylene terephthalate.
7. The process of claim 6 wherein the intrinsic viscosity ranges from about 0.5 to about 1.0.
8. process of claim 7 wherein the reinforcing filler is present in amounts ranging from about 5 to about 60 weight percent of the total resin.
9. The process of claim 8 wherein the polyalkylene terephthalate is polybutylene terephthalate.
10. The process of claim 9 wherein the reinforcing filler is glass fiber. Attorkey for Applicants
IL35167A 1969-08-29 1970-08-25 Polyalkylene terephthalate molding resin and process for making the same IL35167A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US85425969A 1969-08-29 1969-08-29

Publications (2)

Publication Number Publication Date
IL35167A0 IL35167A0 (en) 1970-10-30
IL35167A true IL35167A (en) 1974-09-10

Family

ID=25318174

Family Applications (1)

Application Number Title Priority Date Filing Date
IL35167A IL35167A (en) 1969-08-29 1970-08-25 Polyalkylene terephthalate molding resin and process for making the same

Country Status (14)

Country Link
JP (1) JPS4812412B1 (en)
BE (1) BE755317A (en)
CH (1) CH513941A (en)
CS (1) CS166741B2 (en)
DE (1) DE2042447B2 (en)
ES (1) ES383013A1 (en)
FR (1) FR2059758A1 (en)
GB (1) GB1285828A (en)
IL (1) IL35167A (en)
NL (1) NL7012685A (en)
PL (1) PL81035B1 (en)
RO (1) RO63299A2 (en)
SE (1) SE380032C (en)
ZA (1) ZA705180B (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3763109A (en) 1971-08-19 1973-10-02 Du Pont Segmented thermoplastic copolyesters
US4013613A (en) * 1971-10-01 1977-03-22 General Electric Company Reinforced intercrystalline thermoplastic polyester compositions
US3953394A (en) * 1971-11-15 1976-04-27 General Electric Company Polyester alloys and molding compositions containing the same
JPS5518743B2 (en) * 1972-08-03 1980-05-21
JPS5547057B2 (en) * 1973-03-26 1980-11-27
DE2340559B2 (en) 1973-08-10 1979-11-08 Bayer Ag, 5090 Leverkusen Manufacture of high molecular weight polyesters of butanediol (1,4)
DE2365934C3 (en) * 1973-08-10 1983-12-15 Faserwerke Hüls GmbH, 4370 Marl Production of high molecular weight polyesters
DE2501988B2 (en) * 1975-01-18 1981-08-06 Basf Ag, 6700 Ludwigshafen Process for the packaging and processing of polybutylene terephthalate
CH595416A5 (en) * 1975-04-18 1978-02-15 Ciba Geigy Ag
JPS588420B2 (en) * 1975-10-27 1983-02-16 三井化学株式会社 Glass glass polyester plastic
DE2627869C2 (en) * 1976-06-22 1982-10-21 Dynamit Nobel Ag, 5210 Troisdorf Process for the production of filler-reinforced polyalkylene terephthalate molding compositions
US4435546A (en) 1976-11-23 1984-03-06 Bayer Aktiengesellschaft Polyesters compositions which crystallize rapidly
US4223125A (en) 1976-11-23 1980-09-16 Bayer Aktiengesellschaft Polyester compositions which crystallize rapidly
US4222928A (en) * 1977-11-09 1980-09-16 Teijin Limited Polyester composition
US4533679A (en) * 1982-06-28 1985-08-06 Mobay Chemical Corporation Reinforced polyester composition having an improved strength
JPS617351A (en) * 1984-06-22 1986-01-14 Toray Ind Inc Blow molded article
US4837254A (en) * 1988-03-02 1989-06-06 Eastman Kodak Company Poly(1,4-cyclohexylene dimethylene terephthalate) molding compositions

Also Published As

Publication number Publication date
ES383013A1 (en) 1973-04-16
ZA705180B (en) 1972-03-29
IL35167A0 (en) 1970-10-30
NL7012685A (en) 1971-03-02
SE380032C (en) 1985-10-28
CS166741B2 (en) 1976-03-29
DE2042447A1 (en) 1971-04-15
BE755317A (en) 1971-02-26
PL81035B1 (en) 1975-08-30
RO63299A2 (en) 1978-10-16
CH513941A (en) 1971-10-15
JPS4812412B1 (en) 1973-04-20
DE2042447B2 (en) 1973-05-30
SE380032B (en) 1975-10-27
FR2059758A1 (en) 1971-06-04
GB1285828A (en) 1972-08-16

Similar Documents

Publication Publication Date Title
US3814725A (en) Polyalkylene terephthalate molding resin
IL35167A (en) Polyalkylene terephthalate molding resin and process for making the same
US4157325A (en) PBT molding compositions
US4140670A (en) PBT Injection molding composition
DE69512218T2 (en) HIGH IMPACT RESISTANT OBJECTS MADE OF POLYESTER BLENDS
US3218372A (en) Molding material and molded articles
DE3011561C2 (en) Copolyether ester derived from terephthalic acid or its ester-forming equivalent
US4530953A (en) Polyester resin composition having an improved mold release property
DE2920246A1 (en) POLYESTER COMPOUND FOR THE MANUFACTURE OF MOLDED BODIES AND THE MOLDED BODIES MADE FROM THEM
US4168259A (en) Glass reinforced PBT resins
EP0391981B1 (en) Reinforced molding compositions based on poly(1,4-cyclohexylene dimethylene terephthalate) having improved crystallization characteristics
US3819759A (en) Polyester molding compositions with triaryl phosphate and a polyphenylene oxide or a polycarbonate of bisphenol a
US3903042A (en) Stabilized polyalkylene terephthalate resin composition
US4161469A (en) Polyalkylene terephthalate and organopolysiloxane-polycarbonate block copolymer blends
EP0020693B1 (en) Copolyesters of polybutylene terephthalate
JPH0430422B2 (en)
US3642683A (en) Polymer compositions containing unsaturated polyester vinyl monomer polyester plasticizer and thermoplastic polymer
DE69122433T2 (en) Flame retardant thermotropic polyester mixture containing polybromostyrene and molded parts thereof
US4283326A (en) PBT Molding compositions containing mica and a composite polymer
US6461698B1 (en) Polyester compositions
US4368283A (en) Reinforced resin composition
US3787530A (en) Crystal-clear thermoplastic moulding compositions of linear polyester and styrene-acrylonitrilic copolymer mixtures
US4351751A (en) Glass fiber reinforced polyethylene terephthalate resin composition
GB2038344A (en) Hydrolytically stable polyester resin compositions
DE3040999A1 (en) THERMOPLASTIC MOLDS