IL32365A - פיגמנטים נוצצים העשויים פתיתי מיקה המצופים בדו-תחמוצת הטיטניום והכנתם - Google Patents

Info

Publication number

IL32365A

IL32365A IL32365A IL3236569A IL32365A IL 32365 A IL32365 A IL 32365A IL 32365 A IL32365 A IL 32365A IL 3236569 A IL3236569 A IL 3236569A IL 32365 A IL32365 A IL 32365A

Authority

IL

Israel

Prior art keywords

titanium dioxide

titanium

suspension

coated

nacreous

Prior art date

1969-06-09

Links

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• 239000010445 mica Substances 0.000 title claims description 22
• 229910052618 mica group Inorganic materials 0.000 title claims description 22
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title description 65
• 239000004408 titanium dioxide Substances 0.000 title description 30
• 239000000049 pigment Substances 0.000 title description 17
• 238000002360 preparation method Methods 0.000 title description 3
• 238000000034 method Methods 0.000 claims description 24
• 150000003608 titanium Chemical class 0.000 claims description 20
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 17
• 239000010936 titanium Substances 0.000 claims description 17
• 229910052719 titanium Inorganic materials 0.000 claims description 17
• 230000008569 process Effects 0.000 claims description 14
• 239000000463 material Substances 0.000 claims description 9
• 150000003839 salts Chemical class 0.000 claims description 5
• 239000000725 suspension Substances 0.000 description 36
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
• 239000000243 solution Substances 0.000 description 30
• 235000010215 titanium dioxide Nutrition 0.000 description 29
• 238000000576 coating method Methods 0.000 description 22
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 13
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
• 239000003086 colorant Substances 0.000 description 11
• 239000011521 glass Substances 0.000 description 11
• 239000002253 acid Substances 0.000 description 10
• 230000007062 hydrolysis Effects 0.000 description 10
• 238000006460 hydrolysis reaction Methods 0.000 description 10
• 239000002585 base Substances 0.000 description 9
• 239000012266 salt solution Substances 0.000 description 9
• TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 8
• 239000007788 liquid Substances 0.000 description 8
• 238000004519 manufacturing process Methods 0.000 description 8
• 239000011324 bead Substances 0.000 description 7
• IYVLHQRADFNKAU-UHFFFAOYSA-N oxygen(2-);titanium(4+);hydrate Chemical compound O.[O-2].[O-2].[Ti+4] IYVLHQRADFNKAU-UHFFFAOYSA-N 0.000 description 7
• 238000003756 stirring Methods 0.000 description 7
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
• 239000011248 coating agent Substances 0.000 description 6
• 239000000126 substance Substances 0.000 description 6
• 230000002378 acidificating effect Effects 0.000 description 5
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
• 230000000694 effects Effects 0.000 description 4
• 238000002474 experimental method Methods 0.000 description 4
• 239000010439 graphite Substances 0.000 description 4
• 229910002804 graphite Inorganic materials 0.000 description 4
• 239000002245 particle Substances 0.000 description 4
• 239000000047 product Substances 0.000 description 4
• 239000004952 Polyamide Substances 0.000 description 3
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
• 238000006243 chemical reaction Methods 0.000 description 3
• 239000013078 crystal Substances 0.000 description 3
• 238000000151 deposition Methods 0.000 description 3
• -1 for example Substances 0.000 description 3
• 238000010438 heat treatment Methods 0.000 description 3
• 239000003960 organic solvent Substances 0.000 description 3
• 229920002647 polyamide Polymers 0.000 description 3
• 239000000843 powder Substances 0.000 description 3
• XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
• CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
• UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
• WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
• FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
• 238000013019 agitation Methods 0.000 description 2
• 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
• 229910021529 ammonia Inorganic materials 0.000 description 2
• 239000007864 aqueous solution Substances 0.000 description 2
• 239000007900 aqueous suspension Substances 0.000 description 2
• 239000006227 byproduct Substances 0.000 description 2
• 230000000875 corresponding effect Effects 0.000 description 2
• 238000005260 corrosion Methods 0.000 description 2
• 230000007797 corrosion Effects 0.000 description 2
• 230000003247 decreasing effect Effects 0.000 description 2
• 230000008021 deposition Effects 0.000 description 2
• 239000010408 film Substances 0.000 description 2
• 238000001914 filtration Methods 0.000 description 2
• 239000007789 gas Substances 0.000 description 2
• 239000002932 luster Substances 0.000 description 2
• 229910052751 metal Inorganic materials 0.000 description 2
• 239000002184 metal Substances 0.000 description 2
• 239000000203 mixture Substances 0.000 description 2
• 238000012986 modification Methods 0.000 description 2
• 230000004048 modification Effects 0.000 description 2
• 230000003472 neutralizing effect Effects 0.000 description 2
• 239000007800 oxidant agent Substances 0.000 description 2
• 230000003647 oxidation Effects 0.000 description 2
• 238000007254 oxidation reaction Methods 0.000 description 2
• 239000004033 plastic Substances 0.000 description 2
• 229920003023 plastic Polymers 0.000 description 2
• 229920000136 polysorbate Polymers 0.000 description 2
• 239000002244 precipitate Substances 0.000 description 2
• 230000000750 progressive effect Effects 0.000 description 2
• IHCCLXNEEPMSIO-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 IHCCLXNEEPMSIO-UHFFFAOYSA-N 0.000 description 1
• QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
• VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
• 238000004438 BET method Methods 0.000 description 1
• 229910000906 Bronze Inorganic materials 0.000 description 1
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
• 229910052684 Cerium Inorganic materials 0.000 description 1
• KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
• 229910019142 PO4 Inorganic materials 0.000 description 1
• WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
• 150000007513 acids Chemical class 0.000 description 1
• 238000005054 agglomeration Methods 0.000 description 1
• 230000002776 aggregation Effects 0.000 description 1
• 229910052783 alkali metal Inorganic materials 0.000 description 1
• 150000001340 alkali metals Chemical class 0.000 description 1
• 239000000908 ammonium hydroxide Substances 0.000 description 1
• 150000001450 anions Chemical class 0.000 description 1
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
• MQTOGLILUNWLRT-UHFFFAOYSA-M azanium sodium dihydroxide Chemical compound [NH4+].[OH-].[OH-].[Na+] MQTOGLILUNWLRT-UHFFFAOYSA-M 0.000 description 1
• WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
• 229910001626 barium chloride Inorganic materials 0.000 description 1
• 230000003796 beauty Effects 0.000 description 1
• 238000009835 boiling Methods 0.000 description 1
• 239000010974 bronze Substances 0.000 description 1
• 239000000872 buffer Substances 0.000 description 1
• 239000006172 buffering agent Substances 0.000 description 1
• 230000003139 buffering effect Effects 0.000 description 1
• 229910052793 cadmium Inorganic materials 0.000 description 1
• KSUWPYXSYBTWFG-UHFFFAOYSA-N cadmium(2+);diborate Chemical class [Cd+2].[Cd+2].[Cd+2].[O-]B([O-])[O-].[O-]B([O-])[O-] KSUWPYXSYBTWFG-UHFFFAOYSA-N 0.000 description 1
• 238000001354 calcination Methods 0.000 description 1
• 229910052791 calcium Inorganic materials 0.000 description 1
• 239000011575 calcium Substances 0.000 description 1
• GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
• 230000008859 change Effects 0.000 description 1
• 239000012295 chemical reaction liquid Substances 0.000 description 1
• 229910000423 chromium oxide Inorganic materials 0.000 description 1
• 239000011362 coarse particle Substances 0.000 description 1
• 239000008199 coating composition Substances 0.000 description 1
• 229910000428 cobalt oxide Inorganic materials 0.000 description 1
• IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
• KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
• 230000002596 correlated effect Effects 0.000 description 1
• 239000008367 deionised water Substances 0.000 description 1
• 229910021641 deionized water Inorganic materials 0.000 description 1
• 230000001419 dependent effect Effects 0.000 description 1
• 238000011161 development Methods 0.000 description 1
• 238000010586 diagram Methods 0.000 description 1
• YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
• 238000001035 drying Methods 0.000 description 1
• 150000002148 esters Chemical class 0.000 description 1
• 238000001704 evaporation Methods 0.000 description 1
• 230000012010 growth Effects 0.000 description 1
• 230000001788 irregular Effects 0.000 description 1
• 230000002045 lasting effect Effects 0.000 description 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
• 150000002739 metals Chemical class 0.000 description 1
• 229910052627 muscovite Inorganic materials 0.000 description 1
• 230000007935 neutral effect Effects 0.000 description 1
• 229910000480 nickel oxide Inorganic materials 0.000 description 1
• 230000003287 optical effect Effects 0.000 description 1
• GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
• 239000001301 oxygen Substances 0.000 description 1
• 229910052760 oxygen Inorganic materials 0.000 description 1
• DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
• 239000010452 phosphate Substances 0.000 description 1
• NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
• 239000001103 potassium chloride Substances 0.000 description 1
• 235000011164 potassium chloride Nutrition 0.000 description 1
• 238000001556 precipitation Methods 0.000 description 1
• 230000002035 prolonged effect Effects 0.000 description 1
• 239000000376 reactant Substances 0.000 description 1
• 239000013049 sediment Substances 0.000 description 1
• 239000011780 sodium chloride Substances 0.000 description 1
• 238000003892 spreading Methods 0.000 description 1
• 230000007480 spreading Effects 0.000 description 1
• 238000012360 testing method Methods 0.000 description 1
• 239000010409 thin film Substances 0.000 description 1
• LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
• 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
• 230000000007 visual effect Effects 0.000 description 1