IL28029A - Process for rendering cellulosic fibers flame-resistant - Google Patents
Process for rendering cellulosic fibers flame-resistantInfo
- Publication number
- IL28029A IL28029A IL28029A IL2802967A IL28029A IL 28029 A IL28029 A IL 28029A IL 28029 A IL28029 A IL 28029A IL 2802967 A IL2802967 A IL 2802967A IL 28029 A IL28029 A IL 28029A
- Authority
- IL
- Israel
- Prior art keywords
- resistant
- methylolamide
- flame
- value
- aqueous preparation
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 11
- 238000009877 rendering Methods 0.000 title claims description 3
- 239000000835 fiber Substances 0.000 title description 2
- 238000002360 preparation method Methods 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 8
- -1 phosphorus compound Chemical group 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- XMYQHJDBLRZMLW-UHFFFAOYSA-N methanolamine Chemical compound NCO XMYQHJDBLRZMLW-UHFFFAOYSA-N 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 18
- 235000011167 hydrochloric acid Nutrition 0.000 description 9
- 229960000443 hydrochloric acid Drugs 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 239000004744 fabric Substances 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 4
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 3
- MCONGYNHPPCHSD-UHFFFAOYSA-N 3-dimethoxyphosphoryl-n-(hydroxymethyl)propanamide Chemical compound COP(=O)(OC)CCC(=O)NCO MCONGYNHPPCHSD-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 2
- 230000004992 fission Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- VGCXGMAHQTYDJK-UHFFFAOYSA-N Chloroacetyl chloride Chemical compound ClCC(Cl)=O VGCXGMAHQTYDJK-UHFFFAOYSA-N 0.000 description 1
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical compound NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical compound NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- TXTCTCUXLQYGLA-UHFFFAOYSA-L calcium;prop-2-enoate Chemical compound [Ca+2].[O-]C(=O)C=C.[O-]C(=O)C=C TXTCTCUXLQYGLA-UHFFFAOYSA-L 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- OHZZTXYKLXZFSZ-UHFFFAOYSA-I manganese(3+) 5,10,15-tris(1-methylpyridin-1-ium-4-yl)-20-(1-methylpyridin-4-ylidene)porphyrin-22-ide pentachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Mn+3].C1=CN(C)C=CC1=C1C(C=C2)=NC2=C(C=2C=C[N+](C)=CC=2)C([N-]2)=CC=C2C(C=2C=C[N+](C)=CC=2)=C(C=C2)N=C2C(C=2C=C[N+](C)=CC=2)=C2N=C1C=C2 OHZZTXYKLXZFSZ-UHFFFAOYSA-I 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
- Y10S428/921—Fire or flameproofing
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH794166A CH473937A (de) | 1966-06-01 | 1966-06-01 | Verfahren zum Flammfestmachen von cellulosehaltigen Textilmaterialien |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL28029A true IL28029A (en) | 1970-09-17 |
Family
ID=4332720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL28029A IL28029A (en) | 1966-06-01 | 1967-05-23 | Process for rendering cellulosic fibers flame-resistant |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3577270A (xx) |
| JP (1) | JPS5136394B1 (xx) |
| AT (1) | AT269058B (xx) |
| BE (1) | BE699289A (xx) |
| CH (1) | CH473937A (xx) |
| CS (1) | CS153452B2 (xx) |
| DE (1) | DE1594974C3 (xx) |
| GB (1) | GB1139380A (xx) |
| IL (1) | IL28029A (xx) |
| NL (1) | NL156769B (xx) |
| SE (1) | SE326683B (xx) |
| SU (1) | SU400117A3 (xx) |
| YU (1) | YU34440B (xx) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH880770A4 (xx) * | 1970-06-11 | 1972-03-15 | ||
| US3899453A (en) * | 1970-07-13 | 1975-08-12 | Stauffer Chemical Co | Hydroxyalkylcarbamylalkylphosphonate flame retardants for polyurethanes |
| JPS5341278B1 (xx) * | 1971-02-27 | 1978-11-01 | ||
| US4026808A (en) * | 1972-03-30 | 1977-05-31 | Hooker Chemicals & Plastics Corporation | Flame retardant textile finishes |
| US4028053A (en) * | 1972-12-13 | 1977-06-07 | United Merchants And Manufacturers, Inc. | Fire retardant fabrics and method for preparation thereof |
| US3903337A (en) * | 1974-04-04 | 1975-09-02 | Mitsui Toatsu Chemicals | Method for processing cellulose containing material to impart flame resistance |
| US4007318A (en) * | 1975-05-21 | 1977-02-08 | General Electric Company | Phosphorylated polystyrene and method for forming same |
| CH618563B (de) * | 1976-08-27 | 1900-01-01 | Ciba Geigy Ag | Verfahren zum flammfestmachen von mit kupfer-komplexazofarbstoffen gefaerbtem, cellulosehaltigem textilmaterial. |
| JPS58157133U (ja) * | 1982-04-15 | 1983-10-20 | 瑞穂産業有限会社 | 小型指圧器 |
| CA1279428C (en) * | 1985-02-27 | 1991-01-22 | Tsutomu Imai | Fire retardant for woody materials |
| JPH0651946B2 (ja) * | 1985-06-25 | 1994-07-06 | 丸菱油化工業株式会社 | セルロ−ス系繊維材料の防炎加工法 |
| GB9004633D0 (en) * | 1990-03-01 | 1990-04-25 | Albright & Wilson | Flame retardant composition and method of use |
| IL98728A0 (en) * | 1990-08-03 | 1992-07-15 | Pfersee Chem Fab | Flameproofing compositions containing phosphono compounds and organic acids |
| DE4208235A1 (de) * | 1992-03-14 | 1993-09-16 | Pfersee Chem Fab | Umsetzungsprodukte von phosphiten, chinonen und isocyanaten enthaltende zusammensetzungen |
-
1966
- 1966-06-01 CH CH794166A patent/CH473937A/de not_active IP Right Cessation
-
1967
- 1967-05-23 IL IL28029A patent/IL28029A/en unknown
- 1967-05-23 DE DE1594974A patent/DE1594974C3/de not_active Expired
- 1967-05-24 GB GB24222/67A patent/GB1139380A/en not_active Expired
- 1967-05-30 YU YU1081/67A patent/YU34440B/xx unknown
- 1967-05-31 BE BE699289D patent/BE699289A/xx not_active IP Right Cessation
- 1967-05-31 CS CS397967A patent/CS153452B2/cs unknown
- 1967-05-31 SE SE07623/67*A patent/SE326683B/xx unknown
- 1967-05-31 NL NL6707573.A patent/NL156769B/xx not_active IP Right Cessation
- 1967-05-31 AT AT506967A patent/AT269058B/de active
- 1967-06-01 JP JP42034567A patent/JPS5136394B1/ja active Pending
- 1967-06-01 SU SU1160547A patent/SU400117A3/ru active
-
1969
- 1969-10-29 US US872361A patent/US3577270A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| YU108167A (en) | 1978-12-31 |
| SU400117A3 (xx) | 1973-10-03 |
| GB1139380A (en) | 1969-01-08 |
| CS153452B2 (xx) | 1974-02-25 |
| BE699289A (xx) | 1967-11-30 |
| CH794166A4 (xx) | 1969-02-28 |
| US3577270A (en) | 1971-05-04 |
| CH473937A (de) | 1969-07-31 |
| JPS5136394B1 (xx) | 1976-10-08 |
| DE1594974C3 (de) | 1974-08-01 |
| NL156769B (nl) | 1978-05-16 |
| YU34440B (en) | 1979-07-10 |
| DE1594974B2 (de) | 1974-01-03 |
| NL6707573A (xx) | 1967-12-04 |
| AT269058B (de) | 1969-03-10 |
| SE326683B (xx) | 1970-08-03 |
| DE1594974A1 (de) | 1969-08-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1331826C (en) | Catalysts and processes for formaldehyde-free durable press finishing of cotton textiles with polycarboxylic acids | |
| US5705475A (en) | Non-formaldehyde durable press finishing for cellulosic textiles with phosphonoalkylpolycarboxylic | |
| IL28029A (en) | Process for rendering cellulosic fibers flame-resistant | |
| US5695528A (en) | Treating agent for cellulosic textile material and process for treating cellulosic textile material | |
| US3897584A (en) | Rendering fibrous material flame retardant with cyan amide/halomethyl phosphonic acid systems | |
| US3969437A (en) | Cyclic phosphorus esters | |
| WO1989012714A1 (en) | Catalysts and processes for formaldehyde-free durable press finishing of cotton textiles with polycarboxylic acids | |
| US3574521A (en) | Modification of cellulosic textile materials with divinyl sulfone precursors | |
| Welch | Glyoxal as a Formaldehyde-Free Durable Press Reagent for Mild Curing Applications' | |
| US3220869A (en) | Process for improving textile fabrics | |
| US3597147A (en) | Modification of cellulosic textile materials with pyrimidones | |
| US5352242A (en) | Formaldehyde-free easy care finishing of cellulose-containing textile material | |
| US3676052A (en) | Polypropylene glycols and substituted polypropylene glycols are used in conjunction with crosslinking agents to produce durable press fabrics with improved soil release performance | |
| US5205836A (en) | Formaldehyde-free textile finish | |
| US3622261A (en) | Buffered aldehyde fixation composition | |
| US2828228A (en) | Textile fire retardant treatment | |
| US3695925A (en) | Process for flameproofing textiles | |
| US4295847A (en) | Finishing process for textiles | |
| US3050419A (en) | Process for fixing aminoplasts in the wet state on cellulosic fibrous materials | |
| US3476581A (en) | Treatment of textiles with cross-linkable acrylic polymers and the resulting products | |
| GB1118742A (en) | Novel aqueous formaldehyde composition | |
| US3420703A (en) | Process for treating a textile material with an aqueous antistatic and handle-improving composition and the aqueous treating composition | |
| US3963437A (en) | Flame retardant process for cellulosic material including cyanamide, phosphonic acid, antimony oxide and polymeric halogen-containing material | |
| US3871822A (en) | Treatment of cellulosic textile fabrics with methylolated alkoxyalkyl carbamates | |
| US3817779A (en) | Process for imparting flame retardancy to a textile |