IL25409A - Separation process of N, N 'dialkyl bipyridilium salts and N-alkyl pyridinium salts - Google Patents
Separation process of N, N 'dialkyl bipyridilium salts and N-alkyl pyridinium saltsInfo
- Publication number
- IL25409A IL25409A IL25409A IL2540966A IL25409A IL 25409 A IL25409 A IL 25409A IL 25409 A IL25409 A IL 25409A IL 2540966 A IL2540966 A IL 2540966A IL 25409 A IL25409 A IL 25409A
- Authority
- IL
- Israel
- Prior art keywords
- salts
- bipyridylium
- dialkyl
- salt
- halide
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 title claims description 29
- 238000000926 separation method Methods 0.000 title claims description 10
- 238000000034 method Methods 0.000 claims description 21
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 7
- -1 halide salts Chemical class 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 2
- 150000001805 chlorine compounds Chemical class 0.000 claims description 2
- 230000003993 interaction Effects 0.000 claims 2
- 150000004820 halides Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- QAIGYXWRIHZZAA-UHFFFAOYSA-M 1-methylpyridin-1-ium;chloride Chemical compound [Cl-].C[N+]1=CC=CC=C1 QAIGYXWRIHZZAA-UHFFFAOYSA-M 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- PQBAWAQIRZIWIV-UHFFFAOYSA-N N-methylpyridinium Chemical class C[N+]1=CC=CC=C1 PQBAWAQIRZIWIV-UHFFFAOYSA-N 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000002026 chloroform extract Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/16—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
- C07D213/20—Quaternary compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/22—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing two or more pyridine rings directly linked together, e.g. bipyridyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB11771/65A GB1084868A (en) | 1965-03-19 | 1965-03-19 | Separation of bipyridylium and pyridinium salts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL25409A true IL25409A (en) | 1969-11-12 |
Family
ID=9992411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL25409A IL25409A (en) | 1965-03-19 | 1966-03-17 | Separation process of N, N 'dialkyl bipyridilium salts and N-alkyl pyridinium salts |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3506677A (enExample) |
| AT (1) | AT261614B (enExample) |
| BE (1) | BE678108A (enExample) |
| BR (1) | BR6677959D0 (enExample) |
| CH (1) | CH476728A (enExample) |
| DE (1) | DE1695232A1 (enExample) |
| DK (1) | DK112522B (enExample) |
| ES (1) | ES324369A1 (enExample) |
| GB (1) | GB1084868A (enExample) |
| IL (1) | IL25409A (enExample) |
| NL (1) | NL6603346A (enExample) |
| SE (1) | SE317973B (enExample) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1960334A (en) * | 1934-05-29 | Process of preparing n-methyl com | ||
| US3159641A (en) * | 1964-12-01 | Process for separating |
-
1965
- 1965-03-19 GB GB11771/65A patent/GB1084868A/en not_active Expired
-
1966
- 1966-03-15 NL NL6603346A patent/NL6603346A/xx unknown
- 1966-03-17 DE DE19661695232 patent/DE1695232A1/de active Pending
- 1966-03-17 DK DK140266AA patent/DK112522B/da unknown
- 1966-03-17 IL IL25409A patent/IL25409A/en unknown
- 1966-03-17 SE SE3558/66A patent/SE317973B/xx unknown
- 1966-03-18 CH CH392766A patent/CH476728A/de not_active IP Right Cessation
- 1966-03-18 AT AT262466A patent/AT261614B/de active
- 1966-03-18 ES ES0324369A patent/ES324369A1/es not_active Expired
- 1966-03-18 BR BR177959/66A patent/BR6677959D0/pt unknown
- 1966-03-18 BE BE678108D patent/BE678108A/xx unknown
-
1969
- 1969-05-26 US US828812A patent/US3506677A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| BR6677959D0 (pt) | 1973-09-04 |
| DK112522B (da) | 1968-12-23 |
| US3506677A (en) | 1970-04-14 |
| CH476728A (de) | 1969-08-15 |
| NL6603346A (enExample) | 1966-09-20 |
| GB1084868A (en) | 1967-09-27 |
| ES324369A1 (es) | 1967-02-01 |
| SE317973B (enExample) | 1969-12-01 |
| BE678108A (enExample) | 1966-09-19 |
| DE1695232A1 (de) | 1972-04-20 |
| AT261614B (de) | 1968-05-10 |
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