IE810570L - Imidazolines - Google Patents

Imidazolines

Info

Publication number
IE810570L
IE810570L IE810570A IE57081A IE810570L IE 810570 L IE810570 L IE 810570L IE 810570 A IE810570 A IE 810570A IE 57081 A IE57081 A IE 57081A IE 810570 L IE810570 L IE 810570L
Authority
IE
Ireland
Prior art keywords
alkyl
titanium
aluminium
component
carbon atoms
Prior art date
Application number
IE810570A
Other versions
IE51021B1 (en
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6098133&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=IE810570(L) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basf Ag filed Critical Basf Ag
Publication of IE810570L publication Critical patent/IE810570L/en
Publication of IE51021B1 publication Critical patent/IE51021B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

1. A process for the preparation of homopolymers and copolymers of C2 -C6 -alpha-monoolefins at from 20 to 160 degrees C, and under a pressure of from 1 to 100 bar, by means of a Ziegler-Natta catalyst system comprising (1) a titanium-III component which is obtained by reacting (1.1) 1 mole, calculated as titanium-III chloride, of a titanium-III chloride conventionally used for Ziegler-Natta catalyst systems, which has been modified with a compound possessing an aluminium chloride group and may or may not have been modified with an organic complexing agent, with (1.2) from 0.05 to 5 moles of an ether of the formula R**1-O-R**2 where R**1 and R**2 are identical or different and each is alkyl of 2 to 15 carbon atoms, phenyl or alkylphenyl, where alkyl is of 1 to 8 carbon atoms, the ether being in the form of an 0.1 - 10 molar solution in an inert hydrocarbon, at from 0 to 120 degrees C for a period of from 10 to 120 minutes, and with (1.3) from 0.1 to 20 moles of titanium tetrachloride, in the form of an 0.1 - 4 molar solution in an inert hydrocarbon, at from 0 to 120 degrees C for a period of from 10 to 220 minutes, and isolating the reaction product, and (2) an aluminium-alkyl component of the formula see diagramm : EP0036549,P8,F1 where R**3 and R**4 are identical or different and each is alkyl of 1 to 8 carbon atoms, with the proviso that the atomic ratio of titanium from the titanium-III component (1) to aluminium from the aluminium-alkyl component (2) is from 1:1 to 1:20, in which process the catalyst system employed contains, as a further component, (3) a phenolic compound of the formula see diagramm : EP0036549,P8,F2 where R**5 is C1 -C6 -alkyl, R**6 is hydrogen or C1 -C6 -alkyl, R**7 is hydrogen or a saturated hydrocarbon radical of not more than 30 carbon atoms, which may or may not contain up to a total of 6 ether groups and/or ester groups, R**8 is C2 -C24 -alkyl, and o is an integer from 1 to 6, with the proviso that the molar ratio of aluminium-alkyl component (2) to phenolic compound (3) is from 1:1 to 40:1.
IE570/81A 1980-03-24 1981-03-16 1-aroyl-2-phenylamino-2-imidazolines,their preparation and drugs containing these compounds IE51021B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19803011273 DE3011273A1 (en) 1980-03-24 1980-03-24 METHOD FOR PRODUCING HOMO AND COPOLYMERISATS FROM (ALPHA) MONOOLEFINS

Publications (2)

Publication Number Publication Date
IE810570L true IE810570L (en) 1981-09-24
IE51021B1 IE51021B1 (en) 1986-09-03

Family

ID=6098133

Family Applications (1)

Application Number Title Priority Date Filing Date
IE570/81A IE51021B1 (en) 1980-03-24 1981-03-16 1-aroyl-2-phenylamino-2-imidazolines,their preparation and drugs containing these compounds

Country Status (6)

Country Link
EP (1) EP0036549B1 (en)
AT (1) ATE3868T1 (en)
AU (1) AU541722B2 (en)
DE (2) DE3011273A1 (en)
ES (1) ES500619A0 (en)
IE (1) IE51021B1 (en)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH543546A (en) * 1971-03-23 1973-10-31 Solvay Alpha-olefin polymerization catalytic system
DE2226167C3 (en) * 1972-05-30 1979-04-26 Basf Ag, 6700 Ludwigshafen Process for the polymerization of α-olefins
DE2658936A1 (en) * 1976-12-24 1978-07-06 Basf Ag PROCESS FOR PRODUCING A TITANIUM CONTAINING COMPONENT FOR CATALYSTS OF THE ZIEGLER NATTA TYPE
DE2658937A1 (en) * 1976-12-24 1978-07-06 Basf Ag PROCESS FOR PRODUCING A TITANIUM CONTAINING COMPONENT FOR CATALYSTS OF THE ZIEGLER NATTA TYPE
DE2739382A1 (en) * 1977-09-01 1979-03-15 Basf Ag PROCESS FOR PRODUCING A TITANIUM CONTAINING COMPONENT FOR CATALYSTS OF THE ZIEGLER NATTA TYPE

Also Published As

Publication number Publication date
DE3160457D1 (en) 1983-07-28
ES8202033A1 (en) 1982-01-01
ATE3868T1 (en) 1983-07-15
AU6864281A (en) 1981-10-01
IE51021B1 (en) 1986-09-03
EP0036549A3 (en) 1981-10-14
EP0036549A2 (en) 1981-09-30
ES500619A0 (en) 1982-01-01
EP0036549B1 (en) 1983-06-22
AU541722B2 (en) 1985-01-17
DE3011273A1 (en) 1981-10-01

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