IE810570L - Imidazolines - Google Patents
ImidazolinesInfo
- Publication number
- IE810570L IE810570L IE810570A IE57081A IE810570L IE 810570 L IE810570 L IE 810570L IE 810570 A IE810570 A IE 810570A IE 57081 A IE57081 A IE 57081A IE 810570 L IE810570 L IE 810570L
- Authority
- IE
- Ireland
- Prior art keywords
- alkyl
- titanium
- aluminium
- component
- carbon atoms
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
1. A process for the preparation of homopolymers and copolymers of C2 -C6 -alpha-monoolefins at from 20 to 160 degrees C, and under a pressure of from 1 to 100 bar, by means of a Ziegler-Natta catalyst system comprising (1) a titanium-III component which is obtained by reacting (1.1) 1 mole, calculated as titanium-III chloride, of a titanium-III chloride conventionally used for Ziegler-Natta catalyst systems, which has been modified with a compound possessing an aluminium chloride group and may or may not have been modified with an organic complexing agent, with (1.2) from 0.05 to 5 moles of an ether of the formula R**1-O-R**2 where R**1 and R**2 are identical or different and each is alkyl of 2 to 15 carbon atoms, phenyl or alkylphenyl, where alkyl is of 1 to 8 carbon atoms, the ether being in the form of an 0.1 - 10 molar solution in an inert hydrocarbon, at from 0 to 120 degrees C for a period of from 10 to 120 minutes, and with (1.3) from 0.1 to 20 moles of titanium tetrachloride, in the form of an 0.1 - 4 molar solution in an inert hydrocarbon, at from 0 to 120 degrees C for a period of from 10 to 220 minutes, and isolating the reaction product, and (2) an aluminium-alkyl component of the formula see diagramm : EP0036549,P8,F1 where R**3 and R**4 are identical or different and each is alkyl of 1 to 8 carbon atoms, with the proviso that the atomic ratio of titanium from the titanium-III component (1) to aluminium from the aluminium-alkyl component (2) is from 1:1 to 1:20, in which process the catalyst system employed contains, as a further component, (3) a phenolic compound of the formula see diagramm : EP0036549,P8,F2 where R**5 is C1 -C6 -alkyl, R**6 is hydrogen or C1 -C6 -alkyl, R**7 is hydrogen or a saturated hydrocarbon radical of not more than 30 carbon atoms, which may or may not contain up to a total of 6 ether groups and/or ester groups, R**8 is C2 -C24 -alkyl, and o is an integer from 1 to 6, with the proviso that the molar ratio of aluminium-alkyl component (2) to phenolic compound (3) is from 1:1 to 40:1.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19803011273 DE3011273A1 (en) | 1980-03-24 | 1980-03-24 | METHOD FOR PRODUCING HOMO AND COPOLYMERISATS FROM (ALPHA) MONOOLEFINS |
Publications (2)
Publication Number | Publication Date |
---|---|
IE810570L true IE810570L (en) | 1981-09-24 |
IE51021B1 IE51021B1 (en) | 1986-09-03 |
Family
ID=6098133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE570/81A IE51021B1 (en) | 1980-03-24 | 1981-03-16 | 1-aroyl-2-phenylamino-2-imidazolines,their preparation and drugs containing these compounds |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0036549B1 (en) |
AT (1) | ATE3868T1 (en) |
AU (1) | AU541722B2 (en) |
DE (2) | DE3011273A1 (en) |
ES (1) | ES500619A0 (en) |
IE (1) | IE51021B1 (en) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH543546A (en) * | 1971-03-23 | 1973-10-31 | Solvay | Alpha-olefin polymerization catalytic system |
DE2226167C3 (en) * | 1972-05-30 | 1979-04-26 | Basf Ag, 6700 Ludwigshafen | Process for the polymerization of α-olefins |
DE2658936A1 (en) * | 1976-12-24 | 1978-07-06 | Basf Ag | PROCESS FOR PRODUCING A TITANIUM CONTAINING COMPONENT FOR CATALYSTS OF THE ZIEGLER NATTA TYPE |
DE2658937A1 (en) * | 1976-12-24 | 1978-07-06 | Basf Ag | PROCESS FOR PRODUCING A TITANIUM CONTAINING COMPONENT FOR CATALYSTS OF THE ZIEGLER NATTA TYPE |
DE2739382A1 (en) * | 1977-09-01 | 1979-03-15 | Basf Ag | PROCESS FOR PRODUCING A TITANIUM CONTAINING COMPONENT FOR CATALYSTS OF THE ZIEGLER NATTA TYPE |
-
1980
- 1980-03-24 DE DE19803011273 patent/DE3011273A1/en not_active Withdrawn
-
1981
- 1981-03-10 EP EP81101737A patent/EP0036549B1/en not_active Expired
- 1981-03-10 DE DE8181101737T patent/DE3160457D1/en not_active Expired
- 1981-03-10 AT AT81101737T patent/ATE3868T1/en active
- 1981-03-16 IE IE570/81A patent/IE51021B1/en unknown
- 1981-03-23 AU AU68642/81A patent/AU541722B2/en not_active Ceased
- 1981-03-23 ES ES500619A patent/ES500619A0/en active Granted
Also Published As
Publication number | Publication date |
---|---|
DE3160457D1 (en) | 1983-07-28 |
ES8202033A1 (en) | 1982-01-01 |
ATE3868T1 (en) | 1983-07-15 |
AU6864281A (en) | 1981-10-01 |
IE51021B1 (en) | 1986-09-03 |
EP0036549A3 (en) | 1981-10-14 |
EP0036549A2 (en) | 1981-09-30 |
ES500619A0 (en) | 1982-01-01 |
EP0036549B1 (en) | 1983-06-22 |
AU541722B2 (en) | 1985-01-17 |
DE3011273A1 (en) | 1981-10-01 |
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