IE43576L - Process for isolating propylene glycol diesters in the¹preparation of propylene oxide. - Google Patents
Process for isolating propylene glycol diesters in the¹preparation of propylene oxide.Info
- Publication number
- IE43576L IE43576L IE760900A IE90076A IE43576L IE 43576 L IE43576 L IE 43576L IE 760900 A IE760900 A IE 760900A IE 90076 A IE90076 A IE 90076A IE 43576 L IE43576 L IE 43576L
- Authority
- IE
- Ireland
- Prior art keywords
- propylene
- propylene glycol
- organic solvent
- carboxylic acid
- propylene oxide
- Prior art date
Links
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 title abstract 22
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- -1 propylene glycol diesters Chemical class 0.000 title abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 4
- 239000003960 organic solvent Substances 0.000 abstract 4
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 abstract 3
- 239000000047 product Substances 0.000 abstract 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 3
- 239000006227 byproduct Substances 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1491661 Isolation of propylene glycol diesters BAYER AG and DEUTSCHE GOLDUND SILBER-SCHEIDEANSTALT 28 April 1976 [30 April 1975] 17180/76 Heading C2C The invention comprises a process for isolating a propylene glycol dicarboxylate from the reaction mixture produced in the preparation of propylene oxide by reaction of propylene with a solution of a percarboxylic acid in an organic solvent, the boiling point of which is lower than that of the carboxylic acid which corresponds to the percarboxylic acid, and higher than that of propylene oxide, and which mixture comprises propylene oxide, the carboxylic acid corresponding to the percarboxylic acid, one or more of the by-products propylene glycol, propylene glycol monocarboxylate and propylene glycol dicarboxylate, any unreacted propylene and organic solvent, the said process comprising separating the reaction mixture by distillation into a first fraction containing propylene oxide and propylene and a second fraction containing the carboxylic acid, one or more of the by-products and organic solvent, distilling the second fraction in a column at a pressure of from 1À5 to 6 bars with an average residence time in the sump sufficient to produce a sump product which comprises the carboxylic acid and the corresponding propylene glycol dicarboxylate, the organic solvent being removed as the top product, and separating the propylene glycol dicarboxylate from the sump product.
[GB1491661A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2519291A DE2519291C3 (en) | 1975-04-30 | 1975-04-30 | Process for the recovery of propylene glycol dicarboxylates in the manufacture of propylene oxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE43576L true IE43576L (en) | 1976-10-30 |
| IE43576B1 IE43576B1 (en) | 1981-04-08 |
Family
ID=5945444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE900/76A IE43576B1 (en) | 1975-04-30 | 1976-04-28 | Process for isolating propylene glycol diesters in the preparation of propylene oxide |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5946230B2 (en) |
| BE (1) | BE841201A (en) |
| CA (1) | CA1069458A (en) |
| DE (1) | DE2519291C3 (en) |
| ES (1) | ES447409A1 (en) |
| FR (1) | FR2309549A1 (en) |
| GB (1) | GB1491661A (en) |
| IE (1) | IE43576B1 (en) |
| NL (1) | NL175909C (en) |
| NO (1) | NO761472L (en) |
| RO (1) | RO69788A (en) |
| SU (1) | SU621313A3 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0540410U (en) * | 1991-10-24 | 1993-06-01 | 清水建設株式会社 | PC version joint |
| DE102009038398A1 (en) | 2009-08-24 | 2011-03-03 | Uhde Gmbh | Process and apparatus for the preparation of alkylene oxides and of alkylene glycols |
-
1975
- 1975-04-30 DE DE2519291A patent/DE2519291C3/en not_active Expired
-
1976
- 1976-04-28 NL NLAANVRAGE7604535,A patent/NL175909C/en not_active IP Right Cessation
- 1976-04-28 ES ES447409A patent/ES447409A1/en not_active Expired
- 1976-04-28 IE IE900/76A patent/IE43576B1/en unknown
- 1976-04-28 GB GB17180/76A patent/GB1491661A/en not_active Expired
- 1976-04-28 CA CA251,271A patent/CA1069458A/en not_active Expired
- 1976-04-28 RO RO7685933A patent/RO69788A/en unknown
- 1976-04-28 NO NO761472A patent/NO761472L/no unknown
- 1976-04-28 JP JP51047899A patent/JPS5946230B2/en not_active Expired
- 1976-04-28 BE BE2054984A patent/BE841201A/en not_active IP Right Cessation
- 1976-04-28 FR FR7612605A patent/FR2309549A1/en active Granted
-
1977
- 1977-04-28 SU SU772353465A patent/SU621313A3/en active
Also Published As
| Publication number | Publication date |
|---|---|
| NL175909C (en) | 1985-01-16 |
| FR2309549B1 (en) | 1979-09-07 |
| FR2309549A1 (en) | 1976-11-26 |
| DE2519291C3 (en) | 1980-07-03 |
| CA1069458A (en) | 1980-01-08 |
| IE43576B1 (en) | 1981-04-08 |
| ES447409A1 (en) | 1978-10-16 |
| GB1491661A (en) | 1977-11-09 |
| NL175909B (en) | 1984-08-16 |
| NO761472L (en) | 1976-11-02 |
| SU621313A3 (en) | 1978-08-25 |
| BE841201A (en) | 1976-10-28 |
| NL7604535A (en) | 1976-11-02 |
| JPS51133220A (en) | 1976-11-18 |
| RO69788A (en) | 1980-12-30 |
| DE2519291B2 (en) | 1979-10-11 |
| DE2519291A1 (en) | 1976-11-11 |
| JPS5946230B2 (en) | 1984-11-10 |
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