IE42880L - Anionic polymerisation of conjugated dienes - Google Patents
Anionic polymerisation of conjugated dienesInfo
- Publication number
- IE42880L IE42880L IE760395A IE39576A IE42880L IE 42880 L IE42880 L IE 42880L IE 760395 A IE760395 A IE 760395A IE 39576 A IE39576 A IE 39576A IE 42880 L IE42880 L IE 42880L
- Authority
- IE
- Ireland
- Prior art keywords
- alet
- aralkyl
- alkyl
- lithium
- feb
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Abstract
1531085 Catalyst system in anionic diene polymerization MICHELIN & CIE (COMPAGNIE GENERALE DES ETABS MICHELIN) 26 Feb 1976 [27 Feb 1975] 07677/76 Heading C3P Conjugated dienes are homopolymerized or copolymerized with one another and/or with a vinyl aromatic compound at 50 to 120 C. in the presence of a catalyst formed from (A) an organometallic compound of a Group IIIB element (boron, aluminium group) having the formula where Me<SP>1</SP> is an alkali metal atom, Me<SP>2</SP> is an alkaline earth metal atom, M is a metal of Group IIIB, R<SP>1</SP> to R<SP>3</SP> are alkyl or aralkyl, R<SP>4</SP> is alkyl, aralkyl, or XB where X is O, S, NB, where B is alkyl, aralkyl, or M(R<SP>5</SP>R<SP>6</SP>) in which R<SP>5</SP> and R<SP>6</SP> are alkyl or aralkyl, and (B) an electron-donor compound. The monomers are typically butadiene or butadiene/styrene, while exemplified catalyst components include (A) Ba[AlEt 4 ] 2 , Ba[AlEt 3 OR] 2 , where R is nonyl phenyl, Li(AlEt 4 ], Li[AlEt 3 OiPr], LiOAlEt 2 , Li[AlEt 3 OAlEt 2 ], AlEt 3 , and Li[BEt 3 Bu], and (B) tetrahydrofuran, methanol, water, lithium isopropylate, tetramethylethylene diamine, picoline, acetonitrile, acetone, diisobutyl sulphide, hexamethylphosphoramide, lithium isopropylate/barium nonylphenate mixture, potassium t-amylate, the lithium salt of diethylene glycol monoethyl ether and the lithium salt of diethylaminoethanol.
[GB1531085A]
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7506239A FR2302311A1 (en) | 1975-02-27 | 1975-02-27 | PROCESS FOR PREPARING DIENE POLYMERS |
Publications (2)
Publication Number | Publication Date |
---|---|
IE42880L true IE42880L (en) | 1976-08-27 |
IE42880B1 IE42880B1 (en) | 1980-11-05 |
Family
ID=9151865
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE395/76A IE42880B1 (en) | 1975-02-27 | 1976-02-27 | Anionic polymerization of conjugated dienes |
Country Status (20)
Country | Link |
---|---|
JP (1) | JPS602323B2 (en) |
AR (1) | AR218220A1 (en) |
AT (1) | AT346580B (en) |
BE (1) | BE838825A (en) |
BR (1) | BR7601266A (en) |
CA (1) | CA1052948A (en) |
CH (1) | CH610339A5 (en) |
DE (1) | DE2607721A1 (en) |
EG (1) | EG12520A (en) |
FI (1) | FI62107C (en) |
FR (1) | FR2302311A1 (en) |
GB (1) | GB1531085A (en) |
IE (1) | IE42880B1 (en) |
IT (1) | IT1062199B (en) |
LU (1) | LU74429A1 (en) |
NL (1) | NL164870C (en) |
NO (1) | NO149847C (en) |
RO (1) | RO69312A (en) |
SE (2) | SE7602502L (en) |
ZA (1) | ZA761198B (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6026406B2 (en) * | 1978-09-13 | 1985-06-24 | 旭化成株式会社 | Method for producing conjugated diene polymer |
US4297240A (en) | 1980-02-25 | 1981-10-27 | The General Tire & Rubber Company | Solution polymerization |
US4302568A (en) | 1980-02-25 | 1981-11-24 | The General Tire & Rubber Co. | Solution polymerization |
FR2480290A1 (en) * | 1980-04-09 | 1981-10-16 | Michelin & Cie | PROCESS FOR THE PREPARATION OF POLYMERS OF CONJUGATED DIENES OR COPOLYMERS OF CONJUGATED DIENES EITHER THEREWITH OR WITH A VINYLAROMATIC COMPOUND |
FR2480289A1 (en) * | 1980-04-09 | 1981-10-16 | Michelin & Cie | PROCESS FOR THE PREPARATION OF POLYMERS OF CONJUGATED DIENES OR COPOLYMERS OF CONJUGATED DIENES EITHER THEREWITH OR WITH A COMPOUND |
FR2567135B1 (en) * | 1984-07-03 | 1989-01-13 | Asahi Chemical Ind | POLYMER OR COPOLYMER OF BUTADIENE AND PROCESS FOR PREPARATION |
US4933401A (en) * | 1988-02-26 | 1990-06-12 | Japan Synthetic Rubber Co., Ltd. | Catalyst composition for polymerization of conjugated diene and process for producing conjugated diene polymer |
FR2722503A1 (en) | 1994-07-15 | 1996-01-19 | Michelin & Cie | FUNCTIONAL DIENE POLYMERS, PROCESS FOR THEIR PREPARATION AND THEIR USE IN ELASTOMERIC SILICA-FILLED COMPOSITIONS FOR USE IN TIRE ENVELOPES |
FR2722505B1 (en) | 1994-07-15 | 1996-09-27 | Michelin & Cie | SILICA-FILLED ELASTOMERIC COMPOSITIONS FOR USE IN TIRE TIRES |
FR2744127A1 (en) | 1996-01-26 | 1997-08-01 | Michelin & Cie | RUBBER COMPOSITION BASED ON A DIENE POLYMER HAVING A SILANOL FUNCTION AND COMPRISING AN ORGANOSILANE DERIVATIVE |
US6018007A (en) * | 1997-09-22 | 2000-01-25 | Bridgestone Corporation | Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst |
FR2951186B1 (en) | 2009-10-12 | 2012-01-06 | Michelin Soc Tech | RUBBER COMPOSITION BASED ON GLYCEROL AND A FUNCTIONALIZED ELASTOMER AND TIRE TREAD FOR PNEUMATIC |
FR2992649B1 (en) | 2012-07-02 | 2015-06-19 | Michelin & Cie | PROCESS FOR CONTINUOUS SYNTHESIS OF DIENE ELASTOMER |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3716495A (en) * | 1970-09-02 | 1973-02-13 | Phillips Petroleum Co | Polymerization initiator composition and use thereof |
-
1975
- 1975-02-27 FR FR7506239A patent/FR2302311A1/en active Granted
-
1976
- 1976-02-20 NL NL7601763.A patent/NL164870C/en not_active IP Right Cessation
- 1976-02-23 BE BE164535A patent/BE838825A/en not_active IP Right Cessation
- 1976-02-25 LU LU74429A patent/LU74429A1/xx unknown
- 1976-02-25 DE DE19762607721 patent/DE2607721A1/en not_active Ceased
- 1976-02-26 SE SE7602502D patent/SE7602502L/en not_active Application Discontinuation
- 1976-02-26 SE SE7602502A patent/SE417521B/en not_active IP Right Cessation
- 1976-02-26 RO RO7684923A patent/RO69312A/en unknown
- 1976-02-26 CA CA246,639A patent/CA1052948A/en not_active Expired
- 1976-02-26 IT IT67445/76A patent/IT1062199B/en active
- 1976-02-26 GB GB7677/76A patent/GB1531085A/en not_active Expired
- 1976-02-27 JP JP51020214A patent/JPS602323B2/en not_active Expired
- 1976-02-27 NO NO760671A patent/NO149847C/en unknown
- 1976-02-27 CH CH247076A patent/CH610339A5/en unknown
- 1976-02-27 IE IE395/76A patent/IE42880B1/en unknown
- 1976-02-27 AT AT146576A patent/AT346580B/en not_active IP Right Cessation
- 1976-02-27 BR BR7601266A patent/BR7601266A/en unknown
- 1976-02-27 FI FI760518A patent/FI62107C/en not_active IP Right Cessation
- 1976-02-27 ZA ZA761198A patent/ZA761198B/en unknown
- 1976-02-27 AR AR262411A patent/AR218220A1/en active
- 1976-02-28 EG EG117/76A patent/EG12520A/en active
Also Published As
Publication number | Publication date |
---|---|
AR218220A1 (en) | 1980-05-30 |
SE417521B (en) | 1981-03-23 |
JPS602323B2 (en) | 1985-01-21 |
NL164870C (en) | 1981-02-16 |
CA1052948A (en) | 1979-04-17 |
IE42880B1 (en) | 1980-11-05 |
AT346580B (en) | 1978-11-10 |
FR2302311B1 (en) | 1979-08-17 |
NL7601763A (en) | 1976-08-31 |
NO149847C (en) | 1984-07-04 |
NO149847B (en) | 1984-03-26 |
FI62107C (en) | 1982-11-10 |
FR2302311A1 (en) | 1976-09-24 |
NO760671L (en) | 1976-08-30 |
ATA146576A (en) | 1978-03-15 |
BR7601266A (en) | 1976-09-14 |
RO69312A (en) | 1980-05-15 |
JPS51115590A (en) | 1976-10-12 |
GB1531085A (en) | 1978-11-01 |
EG12520A (en) | 1979-09-30 |
SE7602502L (en) | 1976-08-30 |
ZA761198B (en) | 1977-02-23 |
DE2607721A1 (en) | 1976-09-09 |
FI62107B (en) | 1982-07-30 |
BE838825A (en) | 1976-08-23 |
FI760518A (en) | 1976-08-28 |
LU74429A1 (en) | 1977-01-07 |
IT1062199B (en) | 1983-07-28 |
NL164870B (en) | 1980-09-15 |
CH610339A5 (en) | 1979-04-12 |
AU1143976A (en) | 1977-09-01 |
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