IE42255B1 - Improvements in or relating to refining molten glass - Google Patents

Abstract

1531743 Refining molten glass PILKINGTON BROS Ltd 21 Jan 1976 [31 Jan 1975] 4361/75 Heading C1M Molten glass 25 is refined in refining zone 13, the upper regions of the melt being heated (e.g. from ports 26) and the lower regions of the melt (constituting a return flow) being cooled through a heat-conducting support material 19, and the length of zone 13, the depth of the glass in zone 13 and the temperature difference between the inlet and outlet of zone 13 being controlled so that the ratio of forward flow to return flow is 2-6:1. Preferably support material 19 is molten tin, the cooling being by air circulation through channels 21. Preferably the refining zone 13 is shallower than melting zone 12 but deeper than conditioning zone 14 (in which there is preferably no return flow). The temperature at the upper melt surface (e.g. 1460‹ C.) may be up to 200‹ C. more than that at the bottom of zone 13. The atmosphere above zones 12, 13, 14 may be divided by platinum barriers (not shown).

Description

The present invention relates to glass melting and more particularly to a method of refining molten glass. The invention also relates to improved apparatus for use in refining molten glass.

In a known method of manufacturing glass in a continuous process, rax/ materials are fed in at one end of a glass melting tank to form a blanket floating on an existing bath of molten glass. The rate of feeding is sufficient to maintain a constant glass depth in the tank whilst molten glass progres10 sively flows towards the opposite end of the tank known as the working end, from which molten glass is taken away for use in a forming process. The blanket of raw materials is converted to » molten glass as it passes through a melting zone at one;end of the tank by heat which may come for example from burning fuel supplied from burners situated at spaced intervals in the side walls above the glass level or from electrical heating devices. The molten glass passes from the melting zone into a refining zone where heat is also applied above the molten glass. In the refining zone bubbles of gas still remaining in the glass are encouraged to escape or s© go into solution in the glass. The glass passes from the refining zone into a conditioning zone adjacent the working end of the tank. In the conditioning zone the glass is homogenised and brought to a suitable thermal condition for use in the forming process. Normally a canal leads from !5 the working end of the tank to a forming process.

To obtain glass free from gas bubbles and refractory corrosion products and to extend the life of the glass melting tank it· is desirable to ensure that the glass in contact with - 2 42255 the refractory is sufficiently cold. This is in part achieved by the convection flows set up in the molten glass within the tank, the flows causing glass to return from the colder to hotter areas in the lower sections of the tank. This can involve four or more times as much glass returning in the return flow within the tank as is being supplied to the forming process in the upper forward moving layers of molten glass. In this way additional heat is required to bring the return flowing glass to the temperature required in the forward flow.

It is an object of the present invention to provide an improved method of refining glass in which the ratio of forward flow to return flow in the refining zone is much larger than • normal.

The present invention provides a method of refining molten glass in a refining zone of a tank containing molten glass, comprising supporting molten glass on a heat conducting support material forming the base of the refining zone, heating the upper regions of the molten glass so that the temperature of the upper region is sufficient to effect refining, removing heat from the lower region of the molten glass through said support material forming the base of the refining zone to minimise undesirable interaction with the support material, causing the upper regions of the glass to flow forwardly through the refining zone from an inlet to the zone towards an outlet from the zone With a return flew in the lower regions of the glass, and controlling the depth of glass in the refining zone, the length of the refining zone and the temperature difference between the glass at. the inlet and outlet of the refining zene so that the ratio of return flow rate - 3 42255 to forward flow rate is between 1:6 and 1:2, In the case of normal flat glass compositions the temperature of the upper region of the glass may be at at least 146O°C and by use of the present invention the quantity of glass melt refined per unit area at that temperature is increased owing to the large proportion of forward flow through the refining zone. Furthermore, the glass leaves the refining zone having spent a controlled time being refined and,as the quantity of glass circulating is less, the quality of the glass melt is improved as the quantity of glass coming into contact with refractory material in.the refining zone is considerably reduced. This also means that a reduction in the refining area may be made e.g.by a reduction in the width of the known refiner, or an Increase • in output could be accommodated using the same tank.

It is preferable to maintain the return flow in the refining zone out of contact with refractory material at the base of the refining zone and preferably the molten glass is supported on a layer of molten metal at the base of the refining zone. Preferably the molten metal comprises tin. Other metals and alloys including alloys of tin can be used.

Although the ratio of return cf flow to forward flew may be varied, the preferred ratio is i;4.

Preferably heat is extracted from the base of the refining, zone by circulating cooling air below the refining zone so 25 as to maintain the molten metal where necessary at a temperature where it will not react with the glass.

The invention also provides a glass melting tank for carrying out a method as aforesaid having a melting zone at one end of the tank into which glass forming materials are fed, a conditioning zone in which molten glass is brought to a desired thermal condition,prior to discharge from the tank, a refining zone between the melting and conditioning sones, means for applying heat to the upper surface of the - 4 4825 5 glass In the melting and refining zones, the refining zone being provided with a layer of molten netal at the base of the tank, on which layer the molten glass is supported, and cooling means located below the base of the refining zone for removing heat from the lower region of molten glass in the refining zone.

Preferably refractory barriers are located at opposite ends of the refining zone, the barriers upstanding from the base of the refining zone so as to contain the molten metal solely within the refining zone. Preferably the molten netal is molten tin.

Conveniently the cooling means comprises means for circulating cooling air below the refining zone.

The time necessary for satisfactory refining is to some extent dependent on the temperature at which refining is carried out. In the case of soda-lime-silica glass it is desirable to use a refining temperature of at least 1460°C. When using a refining temperature of 146O°C or above for the flow of glass leaving the refining zone, i.e. the load flow for the conditioning zone, one may need to maintain a minimum temperature differential between the surface of the glass melt and the interface between the glass melt and the molten metal of substantially 200°C, It is only the load flow of glass which will eventually enter the forming process which needs to reach the refining temperature, in this case l46O°C. This offers the facility to control the molten glass/molten tin interface temperature at a value, dependent upon the chemical properties of the glass, at which the risk of significant interaction between the glass and metal is minimised. This temperature - 5 4 3 255 differential is achieved hy providing cooling means below the refining zone to remove heat at rates of the order of 30 Kws/sq.m.

The glass return flow within the refining zone recircula5 tes at a relatively high temperature compared with previous proposals and this reduces the amount of reheating required when the glass again moves forward with the forward flow.

The amount of heat required in the refining operation in accordance with the present invention is reduced due to the reduction of quantity of glass in the return flow. The overall thermal efficiency is improved when the temperature differential between the surface and the support material is minimised. The - heat which is extracted from the base of the refining zone can be reused, for example by use in the regenerator chambers or for preheating batch material fed to the tank.

Preferably the melting zone of the tank is arranged to hold molten glass at a greater depth than the refining zone. In this way greater recirculation of molten glass may occur within the melting zone. It is also preferred that the melting zone is provided with a filling pocket into which batch material is fed.

The raw materials may be fed in pellet form and may be preheated by hot gas. The pellets may be heated to about 700°C and fed onto, the surface of the existing batch of molten glass 25 by conventional means.

Preferably the conditioning zone is shallower than the refining zone and is preferably arranged so that the molten glass flow through the conditioning zone is entirely in the forward - 6 42255 direction.

The present invention is also applicable to refining molten glass in an independent refining unit separate from the glass melting tank. In this case molten glass should be fed to the refiner in a substantially stone-free condition. The use of a refining unit independent of the melting unit means that it is possible to arrange the supply of molten glass from more than one source, thus enabling problems of operation and life arising in the melting unit to be solved without necessar10 ily affecting the entire production. In the case of a conventional tank where melting zone, refining zone and conditioning zone are inter-related, a problem in one zone cannot be * separated from the overall operation of the tank.

One embodiment of the invention will now be described by way of example and with reference to the accompanying drawing which shows a longitudinal section through a glass melting tank in accordance with the present invention. In this example a tank 11 has a melting zone 12, a refining zone 13 and a conditioning zone 14. The melting zone 12 has a filling pocket 15 at the melting end of the tank. The conditioning zone 14 leads to the working end of the tank from which conditioned glass is discharged to a canal 9 leading to a forming process. The tank is formed of refractory material and, as is shown in the drawing, the base of the tank is stepped so that the melting zone provi25 des the greatest depth of glass. The base of the tank has an upward step 16 at the downstream end of the melting zone so that the refining zone 13 is shallower than the melting zone. Similarly the downstream end of the refining zone has an upward - 7 42255 step 17 so that the conditioning zone 14 is shallower than the refining zone. The base of the refining zone 13 is formed of a high heat conducting refractory 18 supporting a layer of molten tin 19 between the step 17 and an upstanding barrier 20 5 adjacent the inlet to the refining zone, Belov; the base 18 of the refining zone 13 is an air circulating system for circulating cooling air. This comprises a series of elongated apertures 21 between refractory supports 22. The supports 22 are mounted on a further refractory base 23.

In operation, glass forming material is fed into the pocket in a conventional manner to form a blanket 24 lying on top of the molten glass 25· Heat is applied to the melting zone by ’ gas burners mounted above the surface of the molten glass within the melting zone and operating through ports 26, The glass circulates, as shown by the arrows, in the melting zone so that there is a substantial return flow as well as forward flow.

The molten glass progressively moves along the tank to the refining zone 13 and the conditions of operation in the refining zone are arranged such that the forward flow through the refin20 ing zone is substantially greater than the return flow, as j.s indicated by the arrows in the refining zone. The conditioning zone is shallow and operated so that all the glass in the conditioning zone 14 moves in the forward direction towards the working end of the tank, with no return flow.

The temperature of the upper region of the glass in the refining zone is at about 146O°C in order to carry out satisfactory refining. To prevent interaction between the molten glass and the tin in the refining zone, heat is extracted from - 8 42255 the bottom of the refining zone in order to lower the temperature of the glass in contact with the molten tin. The temperature of the glass adjacent the tin can be of the order of 200°C below the temperature of the upper surface of the glass in the r, refining zone.

The cooling air which is circulated through the passages 21 below the refining zone extracts heat through the high conductivity refractory 18 and molten tin 19 and the extracted heat may be re-used by passing the cooling air to heat regenerators (not shown).

For a particular load, the ratio of fen/ard to return flow rate within the refining zone 13 is dependent on the temperature differential between the glass entering the refining zone at its inlet and the glass leaving the refining zone at its junction with the 15 conditioning zone as well as the depth of glass within the refining zone and the length of the refining zone (that is the distance between the barrier 20 and the step 17). In this particular example the temperature difference between the inlet and outlet of the refining zone, the depth of the refining zone and the length of the refining zone is adjusted such that the ratio of return flav rate to forward flow rate is between 1 : 6 and 1 : 2. Preferably the ratio is 1-4 as this provides maximum thermal efficiency. The choice of these conditions to attain a particular return flow is dependent on the original design of the tank.

Such a design is best determined by a practical model work or by use of a theoretical computer model of the variables in the type of tank envisaged. In the practical operation of the tank,the final adjustment to control the return flow can be achieved by - 9 255 varying the temperature difference, and less desirably the glass depth by varying the tin depth in the refining zone. All the other variables are fixed by the design of the tank. The glass depth is normally of the order of two thirds of a metre and the length isfas indicated above, a function of the residence time needed for refining vzith a particular glass and the rate of flow of glass through the system. These factors are all determinable by the man practised in the art on the basis of his knowledge of the proposed operating load and the operating conditions of the tank.

Although in the above example the base of the refining zone is provided by molten tin, it may be possible in some cases to use other molten metals, including alloys, or even other refractory material provided it is capable of avoiding excessive interaction vzith the molten glass at the return flow temperature used in the refining zone.

The invention is not limited to the details of the foregoing example. For instance, the refining zone could be provided in a separate refining unit.

Although the example shown has one conditioning zone supplied by the refining and melting regions 13 and 12, it may be desirable in some cases to provide two or more conditioning canals which operate in parallel and are fed from a single melting or refining unit. It may in some cases be desirable when all three zones form a common unit to provide between each zone in the space above the glass a shadow wall or a barrier made of a platinum sheet to reduce or prevent free flow of the atmosphere from one space to the next.

Claims (16)

1. CLAIMS:1. A method of refining molten glass in a refining zone of a tank containing molten glass, which method comprises supporting molten glass on a heat conducting support material 5 forming tlie base of the refining zone, heating the upper regions of the molten glass so that the temperature of the Upper region is sufficient to effect refining, removing heat from the lower region of the molten glass through said support material forming the base of the refining zone to minimise 10 undesirable interaction with the support material, causing the upper regions of the glass to flow forwardly through the refining zone from an inlet to the zone towards an outlet from the ’ zone with a return flew in the lower regions of the glass, and ccntrolling the depth of glass in the refining zone, the length of the refining 15 zone and the temperature difference between the glass at the inlet and outlet of the refining zone so that the ratio of return flow rate to forward flow rate is between 1:6 and 1:2.

2. A method according to Claim 1 in which the return flow of molten glass in the refining zone is maintained out of 2o contact with refractory material by the provision of a layer of molten metal at the base of the refining zone.

3. A method according to Claim 2 in which the molten metal comprises tin.

4. A method according to any one of the preceding claims 25 in which the ratio of return flow’ to forward flow in the refining zone is substantially ι·4. - 11 42255

5. A method, according to, any one of the preceding claims in v/hich heat is extracted from the baie of the'refining zone by circulating cooling air below the refining zone.

6. A glass melting tank far use in carrying out the method clairred in ary one of claims 1 to 5 , having a melting zone at cue end of the tank,into which glass forming materials are fed, a conditioning zone in which molten glass is brought to a desired thermal condition prior to discharge from the tank, a refining zone between the melting and conditioning zones,means for 10 applying heat to the upper surface of the glass in the melting and refining zones, the refining zone being provided with a layer of molten metal at the base of tank,on which layer the molten glass is supported, and cooling means located below the base of the refining zone for removing heat from IS the lower region of molten glass in the refining zone.

7. A glass melting tank according to Claim 6 in which refractory barriers are located at opposite ends of the refining zone, the barriers upstanding from the base of the refining zone so as to contain the molten metal solely within the refin2 0 ing zone.

8. A glass melting tank according to Claim 6 or Claim 7, wherein the molten metal is molten tin.

9. A glass melting tank according to any one of Claims 6 to 8 in which the cooling means comprises means for circulating 25 cooling air below the refining zone.

10. A glass melting tank according to any one of Claims 6 - 12 42355 to 9 in which the melting zone of the tank is arranged to hold molten glass at a greater depth than the refining zone.

11. A glass melting tank according to any one of Claims 6 to 10 in which the melting zone is provided with a filling poc5 ket together with means for feeding batch material into the filling pocket.

12. A glass melting tank according to any one of Claims 6 to 11 in which the conditioning zone is shallower than the refining zone and is arranged so that the molten glass flow through 10 the conditioning zone is entirely in the forward direction.

13. A glass melting tank according to any one of Claims 6 k to 12 in which the outlet end of the conditioning zone communicates with a canal leading to a glass forming process.

14. A method of manufacturing molten glass comprising 15 melting glass forming batch material in a melting zone of a glass melting tank, refining the molten glass by a method according to Claim 1 and delivering the molten glass through a canal to a glass forming process,

15. A method of refining molten glass substantially as 2o hereinbefore described with reference to the accompanying drawing.

16. A glass melting tank substantially as hereinbefore described with reference to the accompanying drawing.