IE34080L - Catalytic epoxidation of olefins. - Google Patents

Catalytic epoxidation of olefins.

Info

Publication number
IE34080L
IE34080L IE40370A IE40370A IE34080L IE 34080 L IE34080 L IE 34080L IE 40370 A IE40370 A IE 40370A IE 40370 A IE40370 A IE 40370A IE 34080 L IE34080 L IE 34080L
Authority
IE
Ireland
Prior art keywords
olefinic
epoxides
april
carbon atoms
octene
Prior art date
Application number
IE40370A
Other versions
IE34080B1 (en
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of IE34080L publication Critical patent/IE34080L/en
Publication of IE34080B1 publication Critical patent/IE34080B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)

Abstract

1,248,709. Epoxides. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 1 April, 1970 [2 April,-1969], No. 15375/70. Heading C2C. Epoxides are produced by reacting one or more olefinic compounds with one or more organic hydroperoxides using a catalyst which is insoluble in the reaction mixture and comprising vanadium in chemical combination with a solid silica and/or inorganic silicate. The preferred olefinic starting materials are olefinic hydrocarbons having 2-10 carbon atoms, butadiene, and olefinic compounds substituted by hydroxy groups or halogens, e.g. allyl alcohol, crotyl alcohol and allyl chloride. Suitable organic hydroperoxides are those of formula ROOH in which R is a C 3 -C 20 hydrocarbon group, in particular a secondary or tertiary alkyl or an aralkyl group of 3-10 carbon atoms. Examples describe the preparation of 1-octene oxide from 1-octene and t-butylhydroperoxide. [GB1248709A]
IE40370A 1969-04-02 1970-04-01 A process for epoxidizing olefins with organic hydroperoxides IE34080B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81292469A 1969-04-02 1969-04-02

Publications (2)

Publication Number Publication Date
IE34080L true IE34080L (en) 1970-10-02
IE34080B1 IE34080B1 (en) 1975-01-22

Family

ID=25210980

Family Applications (1)

Application Number Title Priority Date Filing Date
IE40370A IE34080B1 (en) 1969-04-02 1970-04-01 A process for epoxidizing olefins with organic hydroperoxides

Country Status (14)

Country Link
JP (1) JPS5030051B1 (en)
AT (1) AT302987B (en)
BE (1) BE748317A (en)
BR (1) BR7017927D0 (en)
CH (1) CH529125A (en)
DE (1) DE2015542C3 (en)
DK (1) DK133749B (en)
ES (1) ES378132A1 (en)
FR (1) FR2042773A5 (en)
GB (1) GB1248709A (en)
IE (1) IE34080B1 (en)
NL (1) NL145234B (en)
NO (1) NO127503B (en)
SE (1) SE361171B (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3391213A (en) * 1967-06-12 1968-07-02 Shell Oil Co Isoprene production from isopentane via hydroperoxide and borate ester

Also Published As

Publication number Publication date
DE2015542B2 (en) 1979-11-29
GB1248709A (en) 1971-10-06
ES378132A1 (en) 1972-05-16
AT302987B (en) 1972-11-10
JPS5030051B1 (en) 1975-09-29
DK133749C (en) 1976-11-29
NL145234B (en) 1975-03-17
IE34080B1 (en) 1975-01-22
NO127503B (en) 1973-07-02
DK133749B (en) 1976-07-12
DE2015542C3 (en) 1980-08-07
CH529125A (en) 1972-10-15
FR2042773A5 (en) 1971-02-12
SE361171B (en) 1973-10-22
DE2015542A1 (en) 1970-10-08
BR7017927D0 (en) 1973-01-11
NL7004584A (en) 1970-10-06
BE748317A (en) 1970-10-01

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