IE32484L - Detergent compositions - Google Patents
Detergent compositionsInfo
- Publication number
- IE32484L IE32484L IE134068A IE134068A IE32484L IE 32484 L IE32484 L IE 32484L IE 134068 A IE134068 A IE 134068A IE 134068 A IE134068 A IE 134068A IE 32484 L IE32484 L IE 32484L
- Authority
- IE
- Ireland
- Prior art keywords
- detergent
- sulphonate
- alkyl
- sulphate
- sulphonates
- Prior art date
Links
- 239000003599 detergent Substances 0.000 title abstract 12
- 239000000203 mixture Substances 0.000 title abstract 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 5
- -1 alkylbenzene sulphonate Chemical class 0.000 abstract 5
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 5
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 abstract 3
- 239000000344 soap Substances 0.000 abstract 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 abstract 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 abstract 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 abstract 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 1
- 239000004150 EU approved colour Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 abstract 1
- 150000003973 alkyl amines Chemical class 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 229910021538 borax Inorganic materials 0.000 abstract 1
- 238000005282 brightening Methods 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000008119 colloidal silica Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 239000007850 fluorescent dye Substances 0.000 abstract 1
- 230000002070 germicidal effect Effects 0.000 abstract 1
- 230000003165 hydrotropic effect Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 235000019353 potassium silicate Nutrition 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 150000003138 primary alcohols Chemical class 0.000 abstract 1
- YBBJKCMMCRQZMA-UHFFFAOYSA-N pyrithione Chemical compound ON1C=CC=CC1=S YBBJKCMMCRQZMA-UHFFFAOYSA-N 0.000 abstract 1
- WKEDVNSFRWHDNR-UHFFFAOYSA-N salicylanilide Chemical class OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000019351 sodium silicates Nutrition 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 239000004328 sodium tetraborate Substances 0.000 abstract 1
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 abstract 1
- 229940035044 sorbitan monolaurate Drugs 0.000 abstract 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 239000000375 suspending agent Substances 0.000 abstract 1
- 239000003784 tall oil Substances 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 150000003751 zinc Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Detergent Compositions (AREA)
Abstract
1,241,028. Detergent composition. COLGATE-PALMOLIVE CO. 5 Nov., 1968 [7 Nov., 1967], No. 52324/68. Heading C5D. A spray-dried detergent composition essentially free of water-soluble phosphate comprises an alkylbenzene sulphonate detergent with or without other synthetic anionic sulphonate and/or sulphate detergent, soap, nonionic detergent and water-soluble nitrilotriacetate, in a weight ratio of soap to total sulphonate and sulphate detergent in the range 1: 10 to 1: 2, a weight ratio of nonionic detergent to total sulphonate and sulphate detergent in the range 1: 10 to 1: 3 and a weight ratio of nitrilotriacetate to total sulphonate and sulphate detergent in the range 5: 1 to 1: 1. Preferably the alkylbenzene sulphonate is linear and has a high content in which the benzene ring is attached at the 3 position or higher on the alkyl chain. The optional sulphonate and sulphate detergents include alkene sulphonates, hydroxyalkane sulphonates, alkyl sulphates, alkyl sulphonates, salts of α-sulphofatty esters e.g. methyl α-sulphotallowate, sulphated oils e.g. turkey red oil, sulphates of mono- and di-glycerides of fatty acids, alkyl poly (ethenoxy) ether sulphates, higher alkyl glyceryl ether sulphonates. The soap material includes those derived from rosin or tall oil acids. The non-ionic detergent may be a condensate of ethylene oxide with straight chain primary alcohols, alkyl phenols, alkyl thiophenols, propylene glycol and a mixture of monoesters of hexahydric alcohols and inner ethers thereof e.g. sorbitan monolaurate. The preferred nitrilotriacetates are of sodium, potassium and ammonium. Optional ingredients include sodium and potassium silicates (corrosion inhibitors), sodium sulphate, higher fatty acid amides, tertiary higher alkyl amine oxides, fatty alcohols, hydrotropic material such as sodium toluene sulphonate, optical brightening agents or fluorescent dyes, germicides such as halogenated salicylanilide, halogenated bisphenols and the zinc salt of 1-hydroxy-2- pyridinethione, soil-suspending agents such as carboxymethyl cellulose, polyvinyl alcohol or methyl cellulose, colouring agents, anti-oxidants such as 2,6-di-tert-butylphenol, borax and colloidal silica. The composition may be spray-dried into the form of a free flowing powder comprising hollow spheres.
[GB1241028A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68110667A | 1967-11-07 | 1967-11-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE32484L true IE32484L (en) | 1969-05-07 |
| IE32484B1 IE32484B1 (en) | 1973-08-22 |
Family
ID=24733851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE134068A IE32484B1 (en) | 1967-11-07 | 1968-11-06 | Detergent compositions |
Country Status (16)
| Country | Link |
|---|---|
| AT (1) | AT325750B (en) |
| BE (1) | BE723389A (en) |
| BR (1) | BR6803741D0 (en) |
| CH (1) | CH507361A (en) |
| DE (1) | DE1804872A1 (en) |
| DK (1) | DK135324B (en) |
| DO (1) | DOP1968001518A (en) |
| ES (1) | ES359618A1 (en) |
| FI (1) | FI51598C (en) |
| FR (1) | FR1590487A (en) |
| GB (1) | GB1241028A (en) |
| IE (1) | IE32484B1 (en) |
| MY (1) | MY7400143A (en) |
| NL (1) | NL6815821A (en) |
| SE (1) | SE365241B (en) |
| ZM (1) | ZM14868A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA715956B (en) * | 1970-10-28 | 1973-04-25 | Colgate Palmolive Co | Heavy duty liquid detergent |
| PH10800A (en) * | 1972-10-31 | 1977-09-07 | Procter & Gamble | Detergent composition |
| ZA739579B (en) * | 1973-01-15 | 1975-07-30 | Colgate Palmolive Co | Laundry composition |
| CA2577907C (en) * | 2004-09-24 | 2009-11-03 | The Procter & Gamble Company | Process for forming a low density detergent granule |
| CN113562857B (en) * | 2021-07-29 | 2023-05-30 | 上海丰信环保科技有限公司 | Salt inhibitor for salt-containing wastewater back-spraying quenching tower process and use method thereof |
| WO2024138657A1 (en) * | 2022-12-30 | 2024-07-04 | The Procter & Gamble Company | Spray-dried particulate composition |
-
1968
- 1968-10-26 ES ES359618A patent/ES359618A1/en not_active Expired
- 1968-10-28 AT AT1048068A patent/AT325750B/en not_active IP Right Cessation
- 1968-10-28 DE DE19681804872 patent/DE1804872A1/en active Pending
- 1968-10-29 DK DK522968A patent/DK135324B/en unknown
- 1968-10-30 ZM ZM148/68A patent/ZM14868A1/en unknown
- 1968-10-31 CH CH1622568A patent/CH507361A/en not_active IP Right Cessation
- 1968-11-04 FR FR1590487D patent/FR1590487A/fr not_active Expired
- 1968-11-04 SE SE1493968A patent/SE365241B/xx unknown
- 1968-11-05 GB GB5232468A patent/GB1241028A/en not_active Expired
- 1968-11-05 BE BE723389D patent/BE723389A/xx unknown
- 1968-11-05 BR BR20374168A patent/BR6803741D0/en unknown
- 1968-11-06 IE IE134068A patent/IE32484B1/en unknown
- 1968-11-06 FI FI316468A patent/FI51598C/en active
- 1968-11-06 NL NL6815821A patent/NL6815821A/xx unknown
- 1968-11-06 DO DO1968001518A patent/DOP1968001518A/en unknown
-
1974
- 1974-12-30 MY MY7400143A patent/MY7400143A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR6803741D0 (en) | 1973-01-11 |
| ZM14868A1 (en) | 1970-06-18 |
| ES359618A1 (en) | 1970-06-16 |
| DOP1968001518A (en) | 1976-02-20 |
| CH507361A (en) | 1971-05-15 |
| FR1590487A (en) | 1970-04-13 |
| SE365241B (en) | 1974-03-18 |
| BE723389A (en) | 1969-04-16 |
| NL6815821A (en) | 1969-05-09 |
| MY7400143A (en) | 1974-12-31 |
| IE32484B1 (en) | 1973-08-22 |
| DE1804872A1 (en) | 1969-06-26 |
| FI51598B (en) | 1976-11-01 |
| DK135324C (en) | 1977-08-22 |
| GB1241028A (en) | 1971-07-28 |
| DK135324B (en) | 1977-04-04 |
| FI51598C (en) | 1977-02-10 |
| AT325750B (en) | 1975-11-10 |
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