IE22729B1 - Improvements in or relating to the thermal decomposition of certain chlorides and sulphates - Google Patents
Improvements in or relating to the thermal decomposition of certain chlorides and sulphatesInfo
- Publication number
- IE22729B1 IE22729B1 IE49056A IE49056A IE22729B1 IE 22729 B1 IE22729 B1 IE 22729B1 IE 49056 A IE49056 A IE 49056A IE 49056 A IE49056 A IE 49056A IE 22729 B1 IE22729 B1 IE 22729B1
- Authority
- IE
- Ireland
- Prior art keywords
- chloride
- produced
- gas
- magnesium
- hot gas
- Prior art date
Links
- 150000001805 chlorine compounds Chemical class 0.000 title 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 title 1
- 238000005979 thermal decomposition reaction Methods 0.000 title 1
- 239000007789 gas Substances 0.000 abstract 9
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 5
- 239000007788 liquid Substances 0.000 abstract 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 3
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 3
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 abstract 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 2
- 239000001110 calcium chloride Substances 0.000 abstract 2
- 229910001628 calcium chloride Inorganic materials 0.000 abstract 2
- 238000002485 combustion reaction Methods 0.000 abstract 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 abstract 2
- 238000005406 washing Methods 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 230000002745 absorbent Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 239000012452 mother liquor Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 1
- 239000004291 sulphur dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/745—Preparation from sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/02—Oxides or hydroxides
- C01F11/04—Oxides or hydroxides by thermal decomposition
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/02—Magnesia
- C01F5/06—Magnesia by thermal decomposition of magnesium compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/02—Magnesia
- C01F5/06—Magnesia by thermal decomposition of magnesium compounds
- C01F5/10—Magnesia by thermal decomposition of magnesium compounds by thermal decomposition of magnesium chloride with water vapour
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/06—Ferric oxide [Fe2O3]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
<PICT:0793700/III/1> A melt or solution of magnesium, ferrous or ferric chloride or sulphate or calcium chloride is sprayed into a hot gas, preferably in counter-current, water vapour being present in the case of a chloride, sc as to produce the corresponding metal oxide, and hydrogen chloride or sulphur dioxide and trioxide. The hot gas may be at a temperature of 750-1100 DEG C. The height of the chamber may be 3-10 m. The time of contact may be 5-20 sec. The size of the particles of sprayed liquid is preferably 50-200 m . The hot gas may be producer gas or gas produced by the combustion of gaseous or liquid fuel. Magnesium chloride may be decomposed by gas at 900 DEG C. produced by the combustion of solar oil. Magnesium chloride containing one or more of the compounds calcium, sodium and potassium chloride, e.g. as obtained from the mother liquor remaining after the crystallization of carmallite, may be used. The reaction may be conducted such that these chloride impurities are not decomposed, so that the resulting magnesium oxide may be purified by washing with water. The hydrogen chloride also produced may be recovered by washing with water or hydrochloric acid. The lower limit for the concentration of hydrogen chloride in the gas produced, for efficient operation is considered to be 7 per cent. In the case of magnesium chloride this concentration is produced at a temperature of 500 DEG C. As shown, sprayed liquid from nozzle 4 is decomposed in a reactor 1 by hot gas introduced through pipe 7. The oxide produced is withdrawn at 3, while the resulting gas passes through a cyclone separator 9 and then through a scrubber 12 in counter-current to an absorbent liquid.
[GB793700A]
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3554054A GB793700A (en) | 1954-12-08 | 1954-12-08 | Improvements in or relating to the thermal decomposition of certain chlorides and sulphates |
Publications (1)
Publication Number | Publication Date |
---|---|
IE22729B1 true IE22729B1 (en) | 1960-11-16 |
Family
ID=10378869
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE49056A IE22729B1 (en) | 1954-12-08 | 1956-08-29 | Improvements in or relating to the thermal decomposition of certain chlorides and sulphates |
Country Status (9)
Country | Link |
---|---|
BE (1) | BE548967A (en) |
CH (1) | CH357059A (en) |
FR (1) | FR1153218A (en) |
GB (1) | GB793700A (en) |
IE (1) | IE22729B1 (en) |
IL (1) | IL8722A (en) |
IT (1) | IT559538A (en) |
NL (1) | NL208410A (en) |
NZ (1) | NZ117394A (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1154444B (en) * | 1958-12-19 | 1963-09-19 | Fullers Earth Union Ltd | Process for acid activation of clays |
US3258332A (en) * | 1962-10-16 | 1966-06-28 | Alberta Res Council | Hydrometallurgical method for selective metal removal |
NL295685A (en) * | 1963-03-04 | 1900-01-01 | ||
US3378335A (en) * | 1964-02-24 | 1968-04-16 | Government Of Israel As Repres | Preparation of mixed metal oxides by thermal decomposition of metal salts |
AT319188B (en) * | 1970-02-20 | 1974-12-10 | Veitscher Magnesitwerke Ag | Process for the industrial production of high-purity magnesium oxide |
US3852430A (en) * | 1970-05-18 | 1974-12-03 | Sued Chemie Ag | Method for the production of concentrated hydrohalogen acids and metal oxides |
US4777031A (en) * | 1986-07-14 | 1988-10-11 | Cadot Corporation | High temperature process for making fine magnetic particles |
US4765920A (en) * | 1986-07-14 | 1988-08-23 | Cabot Corporation | High temperature process for producing fine magnetic particles of M-phase structure |
AR240445A1 (en) * | 1986-12-17 | 1990-04-30 | Sudamericana Quimica Sa | PROCEDURE TO MANUFACTURE FERRIC OXIDE AND AMMONIUM SALTS |
CN101356291A (en) * | 2005-12-22 | 2009-01-28 | Bhp比利通Ssm开发有限公司 | Magnesium oxide recovery |
AU2012295626B2 (en) * | 2011-08-16 | 2016-05-12 | Purac Biochem Bv | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
CN109134239A (en) * | 2011-08-16 | 2019-01-04 | 普拉克生化公司 | It can be used for the method by recycling carboxylic acid from carboxylic acid magnesium salts with hydrochloric acid precipitation of fermentation liquor treatment |
EP3845486A1 (en) * | 2011-08-16 | 2021-07-07 | Purac Biochem B.V. | Recovery of carboxylic acid from their magnesium salts by precipitation using hydrochloric acid, useful for fermentation broth work-up |
BR112014003379A2 (en) | 2011-08-16 | 2017-03-01 | Purac Biochem Bv | recovery of carboxylic acid from its magnesium salts by precipitation using hydrochloric acid, useful for the development of a fermentation medium |
CN103288142A (en) * | 2013-06-04 | 2013-09-11 | 滨州坤宝化工有限责任公司 | Production process and production equipment for ferric trichloride |
-
0
- IL IL8722D patent/IL8722A/en unknown
- IT IT559538D patent/IT559538A/it unknown
- NL NL208410D patent/NL208410A/xx unknown
- BE BE548967D patent/BE548967A/xx unknown
- NZ NZ117394D patent/NZ117394A/xx unknown
-
1954
- 1954-12-08 GB GB3554054A patent/GB793700A/en not_active Expired
-
1956
- 1956-05-17 FR FR1153218D patent/FR1153218A/en not_active Expired
- 1956-08-29 IE IE49056A patent/IE22729B1/en unknown
- 1956-09-13 CH CH357059D patent/CH357059A/en unknown
Also Published As
Publication number | Publication date |
---|---|
NL208410A (en) | |
FR1153218A (en) | 1958-03-04 |
IT559538A (en) | |
CH357059A (en) | 1961-09-30 |
BE548967A (en) | 1956-07-14 |
GB793700A (en) | 1958-04-23 |
NZ117394A (en) | |
IL8722A (en) |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
IE22729B1 (en) | Improvements in or relating to the thermal decomposition of certain chlorides and sulphates | |
US3682592A (en) | Treatment of waste hci pickle liquor | |
US3226192A (en) | Process of treating waste gas containing sulfur oxide | |
US4186176A (en) | Method of simultaneously removing sulfur dioxide and nitrogen oxides from exhaust gases | |
US4313925A (en) | Thermochemical cyclic system for decomposing H2 O and/or CO2 by means of cerium-titanium-sodium-oxygen compounds | |
US2317443A (en) | Process for making chlorine dioxide and for separating the same from chlorine | |
GB1361519A (en) | Scrubbing of gases containing ticl4 | |
EP0016290B1 (en) | Continuous process for the removal of sulphur dioxide from waste gases, and hydrogen and sulphuric acid produced thereby | |
US4426364A (en) | Removal and recovery of nitrogen oxides and sulfur dioxide from gaseous mixtures containing them | |
US3687614A (en) | Conversion to formate in one stage of thiosulfate formed in removal of sulfur dioxide from gases with formate | |
US3607001A (en) | Removal of sulfur oxides from waste gases | |
US2240344A (en) | Preparation of hypochlorous acid | |
US3832444A (en) | Recovery of so{11 {11 and so{11 {11 from flue gases | |
US3987147A (en) | Process to desulfurize gas and recover sulfur | |
GB844115A (en) | Chlorine recovery | |
GB742195A (en) | Improvements in or relating to the pickling of ferrous metals | |
GB1421646A (en) | Purification of hydrogen fluoride | |
US3110563A (en) | Process for the production of high percentage nitric oxide | |
US3250591A (en) | Method of recovering values from the pyrolysis of spent sodium sulfite liquor | |
GB1089880A (en) | Recovery of ammonia from gaseous mixtures | |
US3098710A (en) | Alkali and sulfite recovery | |
US2793102A (en) | Production of pure chlorine | |
ITMI950357A1 (en) | PROCESS OF ABATEMENT OF SO2 FROM THE GASES CONTAINING IT WITH DIRECT PRODUCTION OF ELEMENTARY SULFUR | |
US3690824A (en) | Desulfurization of flue gas | |
US3069233A (en) | Process for converting nitrosyl chloride to nitrogen oxide and an aqueous solution of acids |