HUT68202A - 2-cyano-1,3-dione derivatives, herbicidal compositions containing them, processes for their preparation and their use - Google Patents

2-cyano-1,3-dione derivatives, herbicidal compositions containing them, processes for their preparation and their use

Info

Publication number
HUT68202A
HUT68202A HU9401519A HU9401519A HUT68202A HU T68202 A HUT68202 A HU T68202A HU 9401519 A HU9401519 A HU 9401519A HU 9401519 A HU9401519 A HU 9401519A HU T68202 A HUT68202 A HU T68202A
Authority
HU
Hungary
Prior art keywords
cyano
processes
preparation
compositions containing
herbicidal compositions
Prior art date
Application number
HU9401519A
Other languages
English (en)
Other versions
HU9401519D0 (en
Inventor
Paul Alfred Cain
Susan Mary Cramp
Claude Lambert
Gillian Mary Little
John Morris
Tibor Musil
Simon Neil Pettit
Philip Henry G Smith
Original Assignee
Rhone Poulenc Agriculture
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB939310222A external-priority patent/GB9310222D0/en
Application filed by Rhone Poulenc Agriculture filed Critical Rhone Poulenc Agriculture
Publication of HU9401519D0 publication Critical patent/HU9401519D0/hu
Publication of HUT68202A publication Critical patent/HUT68202A/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C07D295/192—Radicals derived from carboxylic acids from aromatic carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/40—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by doubly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C307/00—Amides of sulfuric acids, i.e. compounds having singly-bound oxygen atoms of sulfate groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C307/02—Monoamides of sulfuric acids or esters thereof, e.g. sulfamic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/17—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing carboxyl groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/08—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/15—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C311/16—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/60—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton with the carbon atom of at least one of the carboxyl groups bound to nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/62—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
    • C07D295/26—Sulfur atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Hydrogenated Pyridines (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Pyrrole Compounds (AREA)
HU9401519A 1993-05-18 1994-05-17 2-cyano-1,3-dione derivatives, herbicidal compositions containing them, processes for their preparation and their use HUT68202A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB939310222A GB9310222D0 (en) 1993-05-18 1993-05-18 New compositions of matter
US9488193A 1993-07-22 1993-07-22

Publications (2)

Publication Number Publication Date
HU9401519D0 HU9401519D0 (en) 1994-08-29
HUT68202A true HUT68202A (en) 1995-06-28

Family

ID=26302912

Family Applications (1)

Application Number Title Priority Date Filing Date
HU9401519A HUT68202A (en) 1993-05-18 1994-05-17 2-cyano-1,3-dione derivatives, herbicidal compositions containing them, processes for their preparation and their use

Country Status (17)

Country Link
EP (2) EP0811611B1 (hu)
JP (1) JPH0770039A (hu)
KR (1) KR100422924B1 (hu)
CN (1) CN1082790C (hu)
AT (2) ATE189212T1 (hu)
AU (1) AU680483B2 (hu)
BR (1) BR9401097A (hu)
CA (1) CA2123859A1 (hu)
CO (1) CO4130326A1 (hu)
DE (2) DE69422837T2 (hu)
DK (1) DK0625505T3 (hu)
ES (2) ES2141559T3 (hu)
FI (1) FI942291A (hu)
HU (1) HUT68202A (hu)
IL (1) IL109658A0 (hu)
RO (1) RO112858B1 (hu)
TR (1) TR28869A (hu)

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US5627131A (en) * 1995-01-09 1997-05-06 Zeneca Limited Herbicidal compositions of 4-benzoylisoxazole and antidotes therefor
DE59605056D1 (de) * 1995-02-24 2000-05-31 Basf Ag Phenyldiketon-derivate als herbizide
WO1997013765A1 (fr) * 1995-10-09 1997-04-17 Idemitsu Kosan Co., Ltd. Derives de 2-cyano-1,3-dione et herbicides dont ils constituent le principe actif
DE19543641A1 (de) * 1995-11-23 1997-05-28 Basf Ag Phenyldiketonderivate
GB9526436D0 (en) * 1995-12-22 1996-02-21 Rhone Poulenc Agriculture New herbicidal compositions
AU1593497A (en) * 1996-01-26 1997-08-20 Rhone-Poulenc Agriculture Limited Isoxazole and 2-cyano-1,3-diones derivatives and their use as herbicides
AU1594997A (en) * 1996-01-30 1997-08-22 Rhone-Poulenc Agriculture Limited Benzoylisoxazoles and 2-cyano-1,3-dione derivatives and their use as herbicides
GB9606015D0 (en) * 1996-03-22 1996-05-22 Rhone Poulenc Agriculture New herbicides
US6297198B1 (en) * 1996-05-14 2001-10-02 Syngenta Participations Ag Isoxazole derivatives and their use as herbicides
DE69802190T2 (de) 1997-06-10 2002-03-14 Aventis Cropscience S.A., Lyon Neue herbizide mischungen
AU8863798A (en) * 1997-07-18 1999-02-10 Rhone-Poulenc Agriculture Limited 4-benzoyl-isoxazole- and -pyrazole derivatives and 2-cyano 1,3-dione derivativesas herbicides
EP1173449A1 (de) 1999-04-27 2002-01-23 Basf Aktiengesellschaft Phosphorhaltige benzoyl-derivate und ihre verwendung als herbizide
FR2803592A1 (fr) 2000-01-06 2001-07-13 Aventis Cropscience Sa Nouveaux derives de l'acide 3-hydroxypicolinique, leur procede de preparation et compositions fongicides les contenant.
FR2815969B1 (fr) 2000-10-30 2004-12-10 Aventis Cropscience Sa Plantes tolerantes aux herbicides par contournement de voie metabolique
DE10125432A1 (de) * 2001-05-25 2002-11-28 Bayer Ag Substituierte Benzoylketone
FR2844142B1 (fr) 2002-09-11 2007-08-17 Bayer Cropscience Sa Plantes transformees a biosynthese de prenylquinones amelioree
AR074941A1 (es) 2009-01-07 2011-02-23 Bayer Cropscience Sa Plantas transplastomicas exentas de marcador de seleccion
WO2011012248A2 (de) 2009-07-29 2011-02-03 Bayer Cropscience Ag 2-(3-aminobenzoyl)-3-cyclopropyl-3-oxopropannitrile und ihre verwendung als herbizide
US8153132B2 (en) 2009-10-30 2012-04-10 Ms Technologies, Inc. Antibodies immunoreactive with mutant hydroxypenylpyruvate dioxygenase
CN102741415A (zh) 2010-02-02 2012-10-17 拜尔农科股份公司 使用hppd抑制剂作为选择剂的大豆转化
DE112011101566T5 (de) 2010-05-04 2013-05-08 Basf Se Pflanzen mit erhöhter herbizidtoleranz
CA2820706C (en) 2010-12-03 2018-05-22 Ms Technologies, Llc Optimized expression of glyphosate resistance encoding nucleic acid molecules in plant cells
US8648230B2 (en) 2011-03-18 2014-02-11 Ms Technologies, Llc Regulatory regions preferentially expressing in non-pollen plant tissue
US9084425B2 (en) 2011-07-15 2015-07-21 Bayer Intellectual Property Gmbh 2,3-diphenyl-valeronitrile derivatives, method for the production thereof and use thereof as herbicides and plant growth regulators
MX344968B (es) 2012-02-01 2017-01-12 Dow Agrosciences Llc Peptido de transito al cloroplasto.
NZ746567A (en) 2013-11-04 2019-09-27 Dow Agrosciences Llc Optimal soybean loci
CA2928855A1 (en) 2013-11-04 2015-05-07 Dow Agrosciences Llc Optimal maize loci
KR102269769B1 (ko) 2013-11-04 2021-06-28 코르테바 애그리사이언스 엘엘씨 최적 메이즈 유전자좌
TW201527312A (zh) 2013-12-31 2015-07-16 Dow Agrosciences Llc 新穎玉米泛素啓動子（一）
TW201527313A (zh) 2013-12-31 2015-07-16 Dow Agrosciences Llc 新穎玉米泛素啓動子（二）
TW201527316A (zh) 2013-12-31 2015-07-16 Dow Agrosciences Llc 新穎玉米泛素啓動子（五）
TW201527314A (zh) 2013-12-31 2015-07-16 Dow Agrosciences Llc 新穎玉米泛素啓動子（三）
TW201538518A (zh) 2014-02-28 2015-10-16 Dow Agrosciences Llc 藉由嵌合基因調控元件所賦予之根部特異性表現
CN104774186A (zh) * 2015-04-28 2015-07-15 江苏中旗作物保护股份有限公司 农药除草剂异恶唑草酮的合成方法
CN106565621B (zh) * 2016-11-08 2018-12-11 上虞颖泰精细化工有限公司 一种异噁唑草酮的合成方法
CN107652217B (zh) * 2017-10-24 2019-09-03 青岛清原化合物有限公司 取代的苯甲酰基二酮腈类化合物或其互变异构体、盐、制备方法、除草组合物及应用
CN113004179B (zh) * 2019-12-20 2022-06-24 江苏中旗科技股份有限公司 一种异噁唑草酮关键中间体的制备方法

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IE41200B1 (en) * 1973-08-24 1979-11-07 Henkel Corp Aromatic diketones and their use in the extraction of metal values from aqueous solutions
JPS58201851A (ja) * 1982-05-18 1983-11-24 Akishima Kagaku Kogyo Kk 安定化された塩素含有樹脂組成物
GB8520968D0 (en) * 1985-08-21 1985-09-25 Blower D H Protective headgear
US4781750A (en) * 1985-08-27 1988-11-01 Rohm And Haas Company Herbicidally active enols
GB9101659D0 (en) * 1991-01-25 1991-03-06 Rhone Poulenc Agriculture Compositions of matter
GB9101660D0 (en) * 1991-01-25 1991-03-06 Rhone Poulenc Agriculture New compositions of matter

Also Published As

Publication number Publication date
ATE189212T1 (de) 2000-02-15
IL109658A0 (en) 1994-08-26
EP0811611B1 (en) 2000-01-26
HU9401519D0 (en) 1994-08-29
CN1082790C (zh) 2002-04-17
ES2123682T3 (es) 1999-01-16
ES2141559T3 (es) 2000-03-16
EP0811611A1 (en) 1997-12-10
KR100422924B1 (ko) 2004-07-30
DE69414170T2 (de) 1999-04-15
TR28869A (tr) 1997-08-06
BR9401097A (pt) 1995-05-02
DK0625505T3 (da) 1999-07-05
CO4130326A1 (es) 1995-02-13
FI942291A (fi) 1994-11-19
DE69422837D1 (de) 2000-03-02
JPH0770039A (ja) 1995-03-14
EP0625505A2 (en) 1994-11-23
FI942291A0 (fi) 1994-05-17
CN1100261A (zh) 1995-03-22
RO112858B1 (ro) 1998-01-30
DE69422837T2 (de) 2000-08-17
EP0625505B1 (en) 1998-10-28
ATE172718T1 (de) 1998-11-15
AU680483B2 (en) 1997-07-31
CA2123859A1 (en) 1994-11-19
AU6315694A (en) 1994-11-24
DE69414170D1 (de) 1998-12-03
EP0625505A3 (en) 1995-02-15

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