HUT55189A - Herbicidal composition with improved effect and comprising wetting agent and silicone surface active material - Google Patents

Abstract

A herbicidal composition comprising a herbicidally effective amount of an agriculturally acceptable herbicide, humectant, and silicone surfactant optionally with inert adjuvants and water. A herbicidal method of use for killing and controlling weeds is also disclosed.

Description

The present invention relates to an improved herbicidal composition. Preferably, the active ingredient of the present invention comprises acifluorophen, an agriculturally useful salt thereof, oxyfluorophene, lactofen, mazaquinic acid, an agricultural salt thereof, agonist, N-phosphonomethylglycine, an agriculturally useful salt thereof, or a mixture thereof.

Herbicidal active ingredients are generally used in the form of various formulations. These include preferably liquid and dry formulations. The type of dressing used and the efficiency obtained are highly dependent on the plant species treated, the environmental conditions, the geographical environment and the climatic conditions.

Many parts of the earth require herbicidal compositions that are highly rain-resistant. Such areas are the extremely rainy geographical areas and those where rainfall is generally expected after application. In other areas, herbicidal compositions are applied to plants with a thick cuticle, which inhibits absorption of the active ingredient.

The compositions of the present invention are advantageous for increasing herbicidal efficacy, in particular for the treatment of perennial narrow-leaved Sorghum halapense, perennial narrow-leaved Sorghum halapense, Echinocloa crus-galli and Bromus tectorum.

Glyphosate (N-phosphonomethylglycine) is a well-known herbicide. Glyphosate is poorly soluble in water in the form of the free acid and therefore the commercial formulation contains the water-soluble salt of glyphosate. For example, the herbicidal concentrate Roundup contains glyphosate isopropylamine salt.

U.S. Patent Nos. 3,797,758 and 4,405,531 disclose N-phosphoromethylglycine derivatives, salts thereof, and derivatives thereof as herbicidal agents. U.S. Patent No. 4,315,765 discloses the onium salt of N-phosphonone-methylglycine trimethyl-1-ylphenyl and trimethyl 1-yl-phenyl. The iminocarbamide and substituted iminocarbamide, such as guanidine and aminoguanidine salts of N-Phosphono-methylglycine are also well-known herbicides.

The use of moisturizers in herbicidal compositions is described in Additives in Herbicide Formulations, by Andress G. Kánál 1opoulos, Sandoz LTD. , Agrochemical Department, Switzerland, which describes, on page 352, that a wetting agent improves the absorption of the herbicidal active ingredient into the plant leaf by facilitating the drying of the spray and thus increasing the time of ε <-Absorption. It further discloses that glycerol is used as a wetting agent with 2,4-D and other herbicidal agents. Other glycols include ethylene and propylene glycol as well as a mixture of polyhydroxy alcohols and free fatty acids and dimethyl 1-yl-foxide. Polymers useful as wetting agents include Carbowax, sucrose, molasses, and polypropyldiol as the compound.

D.R. Leece et al., J. Amer. Soc. Hor. Sci.

104 (5), 644-64S, 1979 discloses the use of nonionic silicone surfactant, L-77 (organic silicone block copolymer, Union Carbide, New York), nonionic hydrocarbon surfactant (X-77), free fatty acid, isopropanol and glycerol as wetting agent can be used as a foliar fertilizer. The use of a mixture of glycerol and L-77 is also mentioned in this literature.

Roundup (Monsanto) is marketed as an N-phosphonomethyl 1 glycine n-z opr api 1 amine salt. containing a further excipient comprising ethoxylated amine surfactant, inert carrier and water.

Organic silicone surfactants, such as the Silwet L-77 tank mix, can be used in combination with the Roundup herbicide to increase rain resistance. However, if rain does not occur after application of the above mixture, Silwet L-77 will interfere with the action of the herbicide in more than one plant, particularly narrow-leaved plants.

The absorption of Roundup herbicide can be improved with Pulse (Monsanto), which reduces the rain-free period of the active ingredient from 4-6 hours to 2 hours when spraying dry foliage.

The herbicidal composition disclosed in Australian Patent Application Publication No. 64552 / S6 comprises (a) an herbicidal amount of an agriculturally useful salt of N-phosphonomethylglycine, (b) at least one wetting agent having the same wetting capacity as sDrbitol, (c) inert carrier. d) water, wherein the ratio of component a / b is 1: 3-5: 1.

It is stated in the document that, if a suitable wetting agent is used, the N-phosphonomethylglycic salt will moisturize the plant surface for an extended period of time and thus be absorbed in greater amounts than without the use of a wetting agent.

L. L. Jansen (Weed Science, 21, 2, 1973) has shown in eight different species experiments that for six types of herbicides, non-ionic sulfone glycolic surfactant is better, while cationic, which is a female ionic surfactant, has less effect.

British Patent No. 1,225,249 discloses a herbicidal composition comprising a silicone glycol copolymer. Excipients described include silicone glycols containing diorganosiloxane units and alkylglycol siloxane units. Despite the large number of herbicidal active ingredients listed, this literature does not clearly disclose to a person skilled in the art which particular silicone glycol structure should be chosen for the appropriate herbicidal active ingredient, as it provides only one triazole herbicide for which 1.8 soli -o;: uses an auxiliary containing glycol chain consisting of an id unit.

In addition to the use of adjuvants, it is an important requirement that a significant proportion of the herbicidal efficacy of the product be maintained when the treated plant is exposed shortly after application, a feature known as 'rainfall'. This is particularly important for water-soluble herbicides applied on leaves, such as -fliphosate salts.

In addition to the tank mix of Roundup and Eilwet L-77 without glycerine wetting agent or glycerol, formulations containing N-phosphoromethyl glycine or an agriculturally acceptable salt or mixture thereof and containing organic silicones such as Silwet L- 77 without adversely affecting the herbicidal activity of N-phosphonomethylglycine in rainy or rainless weather.

SUMMARY OF THE INVENTION It is an object of the present invention to enhance the herbicidal efficacy of a composition comprising a herbicidal active ingredient, an excipient, water, a wetting agent and a silicone surfactant.

It is a further object of the present invention to provide a glyphosate herbicidal composition having improved efficacy in both rainy and rainless conditions, without the use of silicone surfactant reducing the herbicidal activity of the active ingredient.

It is a further object of the present invention to improve the efficacy of herbicidal compositions by increasing the contact time between the active ingredient and the treated plant surface.

It is a further object of the present invention to provide a herbicidal composition comprising an appropriate amount of a wetting agent and a silicone surfactant.

The present invention therefore relates to a herbicidal composition comprising a herbicidal active ingredient, an inert excipient, water, a wetting agent and a silicone surfactant.

The herbicidal active ingredient of the present invention is preferably acryl-1-fluorophen (5- (2-chloro-α, α, α-trifluoro- p-tolyl-oxy) -2-trobenoic acid), its agricultural salt (3). U.S. Patent No. 979,437), oxyfluorophene (2-chloro-1- (3-ethoxy-4-trinophenoxy) -4- (trifluoromethyl) benzene), lactofen (1'-ethoxycarbonyl). —Ethyl S- [2-chloro-4- (trifluoromethyl) phenoxy-2-nitrobenzoate), imazaquin (2-,5 4,5,5-dihydro-4-methyl-4- (1-methyl-1- diethyl 1) -5-oxo-1H-imidazol-2-yl] -3-quinolinecarboxylic acid, an agriculturally useful salt thereof, N-phosphonomethylglycine, an agriculturally useful salt thereof, or a mixture thereof.

The composition of the invention may be used in the form of a finished mixture or a tank mix.

Triazines, ureas, carbamates, acetamides, uracils, acetic acid or phenol derivatives, triazoles, benzoic acids, nitriles, diphenyl ethers and the like may be used as herbicidal active ingredients in the compositions of the invention.

- 8 Heterocyclic nitrogen / sulfur derivatives such as 2-chloro-4-ethyl-1-amino-6-isopropoxy-1-amino-triazine, 2-hour-4,6-bi (isopropyl-amino) -s-tri-azine, 2-h-4,6-bi (ethyl 1 -amine) -s-tri-azine, 3-isopropyl-1H-2,1,3-benzothi adi azin-4- (3H) -one-2,2-dioxide, 3-amino-1,2,4-triazole, 5-bromo-3-isopropyl-6-methyl-1-uracil , 2- (4-Isopropyl-4-methyl-5-oxo-2-imylazole-η-2-yl) -3-quinoline-n-carboxylic acid, 2- <4-methyl 1 -5-oxo-2-imidazole-2-yl) -nicotinic acid isopropylamine, methyl-6- (4-isopropyl-4-methyl-5-oxo-2-imidazole)-2- 11) -m-toluate, methyl 1-2- (4-4-isopropyl-4-methyl-5-oxo-2-imidazol-2-yl) -p-toluate, and acids, esters and alcohols such as 2,2-dichloropropionic acid, 2-methyl-4-chlorophenoxyacetic acid, 2,4-dichlorophenoxyacetic acid, methyl 1 -2-E4- (2,4-di hour-phenoxy i) -phenoxy 1-propionate, 3-amino-2,5-dichlorobenzoic acid, 2-methoxy-3,6-diurobenzoic acid,

2.3.6-trichlorophenyl 1-acetic acid, N-i-naphthyl-1-phthalic acid, sodium 5-E2-chloro-4- (trifluoromethyl) phenoxy-2-nitrobenzoate,

4.6-dinitro-o-sec-butyl-phenol, butyl-1-2-EC (trifluoromethyl) -2-pyridine 1-oxy-3-phenoxy] -propionate, and cyclohexanedione derivatives such as setoxidium and garlone, and ether derivatives 2,4-Dichlorophenyl-4-nitrophenyl 1-ether, 2-chloro-trifluoro-p-tolyl-3-ethoxy-4-ni trofiphenyl ether, 5- (2-chloro-4) -trifluoromethyl 1-phenoxy i) -M-methyl 1-parent 1-2-trobenzamide d, 1 '- (ethoxycarbonyl) ethyl 1-5 ~ E2 ~ chloro-4- (trifluoride) -methyl) -phenoxy-2-nitrobenzoate and other diphenyl ether derivatives, and other herbicides such as 2,6-dichlorobenzonitrile, methane-

2- (2-Chloro-arsenate-sodium salt, methane-arsenate-disodium salt, - Ο _

- phenyl-1-methyl-4,4-dimethyl-3-ioxoxazolyl non.

Other herbicides which may be used are phosamine, haloxyfop, imazapir, mefluidide, bisulfuron, picloram, quizalofop and imidazolinone.

The above list is merely an exemplary illustration of the range of active ingredients that can be used in the composition of the invention. The N-β-phosphonomethylglycine can be used alone, in the form of an agriculturally useful salt, amide, ester or derivative thereof, in the form of one or more agricultural derivatives or of a salt thereof, and of the N-f -methyl lgl icin and its agriculturally useful salt-in the form of.

Examples of suitable agricultural salts are those listed in U.S. Patent Nos. 3,799,758, 4,405,531, and 4,315,755, preferably isopropyl amino salts, sodium salts, ammonium salts, trimethylsulfonyl salts and guanidine salts. Also useful as herbicides are 3,455,575, 3,799,758, 3,977,850, 3,858,407,

The active compounds listed in U.S. Patent Nos. 315,755 and 4,397,575.

According to the invention, compounds which absorb water similarly to glycerol can be used as a moisturizer. Examples of moisturizers from furs include, polyethylene glycol, polypropylene glycol, propylene glycol, triethylene glycol, glycerol, sodium stearate, micro-* ·

10 crystalline cellulose, linear homopimer of ethylene oxide, soluble collagen such as collasol (Croda Inc.), lactonic acid and its salts, cane molasses and sodium lactate.

Organic silicone surfactants and polyalkylene-1-ene-modified dimethyl-polysiloxane copolymers, such as ε <, may be used as silicone surfactants according to the invention. Silwet (Unión Carbide Corporation, USA). These surfactants have a distinct hydrophilic (water-loving) and hydrophobic (water-repellent) moiety. These compounds are represented by the formula (I) wherein a is 3--24, b is 0-15, x is 0-3, y is 1-5,

Z is hydrogen, (C 1 -C 3) -alkyl or (C 2 -C 4) -acyl.

Suitable silicone surfactants of the Silwet type are those disclosed in Union Carbide: Silicones for the Agricultural Industry 8UI-356, 6/84, ΞΜ, and surfactant copolymers in the Union Carbide SUI-394A, 7/85, 5M.

Other silicone surfactants which may be mentioned are SF-11S8 (Generic Electric Company, Silicone F'roducts Division, Department of Rubber and Fluid Products, Waterford).

-11-New York 12188, USA), Silwet L-7607, and silicone glycol 02-5309, 02-5152, 02-5852 and 02-5853 (Dow Górning Corporation, Midland, Michigan, USA) and mixtures of rain.

Vegyületek Compounds of formula I are known a

No. 299,112 US Patent bsli, preferably which can be used on ;; OCME Me ^ Si (C ^ Kuo) τ-C ^ H ^ Me ₃ Si MeOlSi silane of formula.

The silicone surfactant may also be a silicone glycol of formula II wherein Me is methyl,

R is a C 2 -C 6 divalent alkenyl group such as ethylene, trimethylene group, tetramethyl group or hex;

Preferred compounds are those compounds of formula II wherein R is trimethylene. In the formula, Z is hydrogen, (C 1 -C 3) -alkyl and (C 2 -C 4) acyl, especially aceto.

The above-mentioned silicone glycols are known and can be prepared by reacting a glycol containing an allyl group at the central silicone group with a bis-siloxane of formula III containing a hydrogen atom. The reaction is usually carried out in the presence of a platinum catalyst. During the reaction, a part of the glycol containing the al1i1 group of the chain does not react and remains as a contaminant in the λ · · * V V>> V. • · · · · * · · <

sicyclic glycol in the final product. This contaminant is included in the herbicidal composition of the present invention, and compositions containing such contamination are included. In addition, silicone glycol-silicon-alkane terpolymers, such as compounds of formula IV, may be used as silicone surfactants in accordance with the present invention.

R is independently -C 1-6 alkyl,

A is a straight or branched C 7 -C 30 alkyl group,

G = -R · (0CH _{CH a)} a glycol residue of formula _m áltztlános 0z where

R · is a divalent alkylene group of 1 to 6 carbon atoms,

Z is hydrogen, (C1-C3) -alkyl or (C2-C4) -acyl, m is 8-10,

G is an alkyl group as defined in A, a glycol group as defined in G or an alkyl group as defined in R

0-100, value 0.1-25, value 0.1-50 »

Among the silicone glycol silicone alkane terpolymers of formula (II), the silicone-surfactants of formula (V)

He is methyl.

The conglomerate terpolymers of the above-mentioned Congolese coli may be prepared in a manner known per se. For example, glycol containing an allyl group at the end of the chain is reacted with an alpha-alkene to give a silane of formula VI:

0 · represents a group R or hydrogen,

R, x, y and z are as defined above.

Most preferably, 0.77 moles of α-dodecene and 1.90 moles of

CH _a = CHCH _a d (OCHaCHala ^ OCIDJCH.glycol) containing glycol containing a siloxane derivative of general formula VII to give 1 mole of a terpolymer product. At a temperature of Έ, and preferably in the presence of a solvent such as toluene or isopropanol, liquid compounds are preferred as silicone surfactants according to the invention.

In addition to the above-mentioned components, the compositions of the invention may also contain other conventional herbicidal excipients. Examples of excipients are vegetable oil concentrate, ORTHO X-77 spreading agent, a bulking agent such as LO-DRIFT, antifoaming agent, ···· ···

9 9,999 D-FOAMER, Compatibility Enhancer, E-Z MIX, and other well-known excipients.

For example, from about 0.1 to about 10 parts by weight of a silicone glycol silicon-alkane terpolymer may be thoroughly mixed with each part by weight of a herbicide to produce the composition of the invention. Preferably 0.5 to 5 parts by weight of terpolymer is used per 1 part by weight of pesticide. The optimum ratio of the components to a given herbicidal active ingredient can be readily determined by those skilled in the art.

The composition of the invention is dispersible in water and a. can be sprayed on the plant. Alternatively, the silicone glycol silicone alkane terpolymer excipient may be mixed directly with an aqueous solution or dispersion of the herbicidal active ingredient.

For example, the preparation of the present invention is based on the herbicidal active ingredient and the various components of the composition are administered in any order. Alternatively, an aqueous solution of 480 g / l (41 wt.%) Of the salt of β-phosphonomethyl 1-glycine-isopropyl may be used as starting material.

Thereafter, an appropriate amount of (a) a wetting agent, (b) a silicone surfactant, and optionally an inert excipient and a sufficient amount of water are added in any order.

································································································ ················································································· Once this has been released, will not be able to complete the program

If desired, the composition of the present invention may be prepared from the herbicidal active ingredient or an agriculturally useful salt thereof or from an excipient or a wet detergent or a silicone surfactant. Sufficient water is added to the composition if desired.

Although the concentrations of the various components used in the present invention are given below, it will be apparent to those skilled in the art that minor changes may be necessary to adapt to; the properties of a given herbicide.

The concentration of active ingredient in a herbicidal concentrate according to the invention is generally about 2-70% by weight, preferably about 4-40% by weight.

The concentration of the active ingredient in a ready-to-use solution, such as a spray solution for spraying leaves, is generally about 0.05 to 20% by weight, preferably about 0.15 to 5% by weight.

The ratio of herbicidal active ingredient to silicone surfactant is the same in the concentrate and in the spray liquid. The weight ratio of active ingredient to silicone surfactant is 1: 30-50: 1, preferably 1: 15-10: 1. The wetting agent is used in the amount of the herbicidal composition to counteract any antagonistic effect of the silicone surfactant on the herbicidal agent and / or to improve the likelihood.

The ratio of silicone-like surfactant to wetting agent is the same in the concentrate and in the spray liquor. The weight ratio of silicone surfactant to wetting agent is generally from 1: 1 to 1:200, preferably from 1: 5 to 1:50.

Any wetting agent capable of counteracting the antagonistic effect of the silicone surfactant on the herbicidal agent may be used in the present invention.

The ratio of herbicidal active ingredient to excipient will greatly depend on the type and properties of the herbicidal active ingredient used in the composition. The weight ratio of the herbicidal active ingredient to the excipient is generally from 1: 5 to 10: 1, preferably from 1: 2 to 4: 1.

Water is used in the amount required to prepare the concentrate or ready-to-use formulation, such as a spray liquid. However, the concentrate and / or the ready-to-use preparation may also be a dry preparation.

It will be apparent to those skilled in the art that the limits given may be varied slightly without affecting the use of the composition of the invention.

The composition of the invention, in particular the liquid and soluble powder formulations, may optionally contain one or more surfactants which may be dispersed in water or in oil as additional excipients.

The use of surfactants of this type can greatly improve the efficacy of the composition of the invention. As used herein, surfactants include wetting agents, dispersing agents, suspending agents, or emulsifying agents, which may be anionic, cationic or nonionic.

Suitable humectants include alkylbenzene and alpha-naphthalene sulfonates, sulfated fatty alcohols, amines or acid amides, long-chain acid sodium isothionate esters, sodium sulfosuccinate esters, sulfated ester or sulfonate, eum-sul phonates, synthonated vegetable oils, di-teri-ethyl-1-glycols, al-1-phenols-poly (derivatives of i-ethyl-1-ene) (mainly derivatives of isooct1-phenol and nonylphenol) and he ;: Polyoxyethylene derivatives of fatty acid esters of toanhydrid dec (sorbitan). Preferably, the dispersant used is methyl-target 1ulose, polyvinylalcohol alcohol Limlgnium n-sulphonate, polymeric alkyl naphthalene sulphonate, sodium naphthalene n-sulphonate, bis (naphthalenyl) -phonate; and sodium N-methyl-N- (long-chain carboxylic acid) -1 aura.

Suitable surfactants among the excipients are preferably those of 3 79? 75S and U.S. Patent 4,405,531.

Particularly preferred is a composition according to the invention comprising the commercial Roundup herbicidal composition, Silwet L-77, glycerol and water as diluent. Preferably, the above composition is used as a post emergent herbicide to control root stalk or seed sorghum, cocksfoot or rye.

A water dispersible powder composition will generally contain one or more active ingredients, an inert solid carrier and one or more wetting and dispersing agents. The inert solid carrier is usually a mineral material, such as natural clay, diatomaceous earth or synthetic powder, such as sulfur dioxide. Other examples of carriers include kaolinite, attapulgite, and synthetic magnesium silicate. The water-dispersible powder composition of the present invention is generally 5 to 95% by weight of the active ingredient, 0.25 to 25% by weight. wet whey, 0.25-25% by weight, dispersant and 4.5-94.5% by weight? containing from about 0.1 to about 2.0 parts by weight of a solid inert carrier with a corrosion inhibitor or an antifoaming agent.

To form an aqueous suspension, the water-insoluble active ingredient is dispersed in the presence of a barrier. The aqueous suspension is mixed and ground to give a concentrated suspension of finely divided particles. This concentrated aqueous slurry is characterized by an extremely small particle size and therefore, after dilution and application, the spray coating will be uniform.

If desired, the composition of the invention may be mixed with other components, such as fertilizers, phytotoxic agents and plant growth regulators, herbicides and the like, and applied together or sequentially.

Examples of active compounds which may be combined with the compositions of the present invention include triazines, ureas, carbamates, acetamides, uracins, acetic acid derivatives, phenol derivatives, thiocarbamates, triazoles, benzoic acid derivatives, nitriles and the like. similar materials.

For use, the composition of the invention, preferably a herbicidal composition such as N-phosphonomethylglycine, an agriculturally useful salt or derivative thereof, is applied in an appropriate amount to the plant to be treated, preferably to its foliage. The liquid or particulate solid herbicidal composition is applied by conventional means, for example, by hand or machine, through a sprayer or nozzle.

The amount of application of the herbicidal active ingredient depends on the effect desired, the plant species treated and its state of development, the applied herbicidal active ingredient and the weather conditions, such as the amount of rainfall. The amount of use can be readily determined by one skilled in the art from the description and examples.

In the examples which illustrate the invention, the following plant species were tested:

Sorghum halapense Seedwort (Sorghum halapense) Roach (Bromus tectorum) Cocksfoot (Echinochloa crus-galli) Silkworm (Abutilon theophrasti) Amberweed (Cyperus esculentus) Fescue (Cyperus esculentus) Fescue (Cyperus esculentus) retro-f 1 e;: us).

The narrow1 and windward test plants are 10 cm in diameter and have separate drainage holes.

7.5 cm deep plastic pots. Planting was done using Dupo mycelium soil (St. Charles Research Farm, Monsanto Company, St. Charles, Missouri, USA), which was previously sterilized by steam at 83 ° C. The soil is either mixed with slow fertilizer 14-14-14, or the planted plant is irrigated with 3-5 days of 5% Rapid-Gro fertilizer solution prior to treatment.

Seeds of sorghum grass, cockroach algae, rye, silk powder, thistle, wormwood and red-root dyed seeds, the root of the ors sesame grass is sown from the root of the orz s piece and the log is made of tuber. In each case, so much propagation material is used that there are more plants in one pot. About 7 to 10 days after planting, the silkworm, the serpentine and the red-rooted pork chop are removed and 2-3 pots of healthy plants are left in each pot.

After planting, the pots are placed in a greenhouse and arranged so that there are 40-60 pots on each shelf. Absorbent layers are applied to the shelves due to over-watering. The greenhouse temperature is maintained at 30 ° C during the day and 21 ° C at night. The illumination period is set to 14-16 hours a day with additional lighting. Water the pots as needed.

Depending on the plant species tested, the chemical treatment is 14-21 days after planting. day. At the time of treatment, narrow-leaved plants reached a height of about 10-40 cm and broad-leaved plants reached 2.5-10 cm.

The chemical treatment is carried out in a post-emergent manner by spraying the leaves using an apparatus equipped with a spray nozzle type 8001E. The sprayer was set so that the sprayed volume was 190 liters / ha and the spray pressure was 207 kPa.

On the day of treatment, a tank mix of the test compound was prepared. The composition contained an N-phosphonomethylglycine-isopropylamine salt, an excipient, a wetting agent, an organic silicone surfactant copolymer, and water.

The application rate of the active ingredient is 0.14-3.4 kg / ha / glyphosate acid equivalent. The composition of the test composition is as follows: glyphosate / surfactant 1: 0.125-1: 1, surfactant / silicone surfactant 1: 0.45-1: 20, silicone surfactant / n'-moisturizer 1: 1-1: 200 . One hour after spraying the composition, the artificial rain was carried out with an evening tower of about 0.6 cm rain.

After rainfall, the treated plants were placed in wheelbarrows and returned to the greenhouse. After the plants had completely dried, the pots were placed back on the shelves of the greenhouse and arranged in random blocks. Each experiment was performed in triplicate, and control plants and appropriate standard treatment were used for each experiment. A group of plants, treated in the same way, was used for a rain-free comparative study.

Early burn results are examined 7-10 days after treatment and the long-term effect 21-28 days. The effect on the plant was evaluated on a scale of 0-100 7, where 0 7 is no observable effect and 100 7 is the total death of the plant. When evaluating the effect, we also consider burns, yellowing, gouting, loss of growth and other observable effects.

The following examples illustrate the composition and use of the compositions of the invention without limiting the scope thereof to the examples. In one of the examples, comparative data is provided using a mixture of Roundup herbicide and Silwet L-77, Roundup herbicide alone, and a mixture of Roundup herbicide and glycerol as a tank mix. The amount of active ingredient is expressed in acid equivalents relative to N-phosphonomethylglycine.

Example 1

Treatment of rootstock sorghum-grass

Preparation Essence Effect (7.)

Application rate (kq / ha)

Ο, .zG Ci, δ 4 average

14 day the treatment after Roundup no 10 92 51 there is s ~ ^l 15 9 light fog 7 ~ j 87 47 Roundup + + Here7. L- -77 n i no 5 2 2? 5 12 there is 10 38 24 light fog 8 77 42 28 day the treatment after Roundup no 33 91 82 there is 10 38 24 light fog 18 97 58 Roundup + + lt7. L- -77 no 10 28 22 there is 22 48 light fog 28 88 53

Example 2

Treatment of rootstock sorghum without germination

Finished

Effect (7.) 28 days after treatment

Application rate (kq / ha)

0.28 0.56

0.84 over 1 g

Roundup 60 97 88 82 Roundup + lt7. L- / / 20 35 63 39 Roundup + 11X L-- 77+ + ltX glycerol 43 58 71 58 Roundup + lty. L-- 77+ + 3tX glycerol O5 78 77 63 Roundup + lt7. L- 77+ + 5t7. glycerol 72 88 92 84 Roundup + gli cer i n 60 100 100 87 Roundup + preparation of 3.7. gl i hope 62 100 100 87 Roundup + 5t7. gl i cer i n 55 100 100 85

• ·

Example 3

Treatment of seed sorghum-Fii with application rate of 0.56 kq / ha

Finished i tménv Esbz feeding Effect (X) 7 days 21 days Roundup no 75 100 there is 17 53 Roundup + ltX L.-77 no 45 there is 28 63 Roundup + ltX L-77 + + ltX gl icerin no 18 45 there is 60 93 Roundup + ltX L-77 + + 2tX glycerol no 33 66 there is 58 99 Roundup + ltX L-77 + + 5tX glycerol no 82 96 there is 52 92 Roundup + ltX L-77 + + 10tX glycerol no 93 100 there is 82 99

Example 3

Treatment of seed sorghum with application rate of 0.56 kq / ha

Ready to drink Eat bet » Effect (X) 7 days 21 days Roundup no 75 100 there is 17 53 Roundup + 1tZ L-77 no " 45 there is 28 63 Roundup + 1tZ L-77 + + 1tZ glyceri n no 18 45 there is pc bow 93 Roundup + 11Z L-77 + - + 2tZ glycerol no 33 66 there is 58 99 Roundup + 1tZ L-77 + + 5tZ glycerol no 82 96 there is 52 92 Roundup + ltZ L-77 + + 10tZ glycerol no 93 100 there is 82 99

Example 5

Treatment of seed sorghum

Ready to go

Rainfall Effect C /. 'After 23 days

Application rate (kg / ha)

0.14 0.42 over 1 year Roundup no 45 72 there is 5 72 38 Roundup + 0,25t7. L-77 no 3 ~ ncr 14 there is ³ 72 38 Roundup + 0.25t7, L-77 + + 10t7. glycerol no 98 100 99 there is 88 98 93 Roundup + 1tX L-77 no 5 30 18 there is 18 78 48

Roundup + ltZ L-77 +

+ 10tX glycerol no 80 99 90 there is 37 97 67 Roundup + 0,25t7. SF-1188 no 7 96 52 there is 5 72 3B

(Continue the table in Example 5) preparation Slurry Decision Utilize s (7th) after 23 days SUPPLY (Kq / ha) how much 0.14 0.42 over .1 g Roundup + 0,25t7. SF-1188 + + 10t7. glycerol no 94 100 97 there is 96 74 Roundup + 117th SF-1188 no 20 night 58 there is 10 43 26 Roundup + 117. SF-1188 + + 10t7. glycerol no 97 100 98 there is 85 100 92 Round up +1 Ot 7. g 1 i cer i n no 57 100 78

Ο 40 20 van ··· «»>

- 2? -

Example 6

Treatment of seed sorghum

Preparation Ingestion Effect (7.) After 21 days

Application rate (kg / ha)

0.14 0.42 over 1 year Roundup no 17 100 58 there is 0 88 44 Roundup + 0,25t7. L-77 no 3 22 13 there is 0 83 42 Roundup + 0,25t7. L-77 + + 5t7. PEG-200 n i ne s 43 99 71 there is 77 98 88 Roundup + 0.25tZ L-77 + · +1 Ot /. PEG 200 * no 95 100 97 there is 68 100 84 Roundup + 0.5t 7. L-77 no 8 20 14 there is 18 68 43 Roundup + 0.5t 7. L-77 + + 5t7. PEG-200 no 12 82 47 there is 42 96 69

♦ · · «« 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 )

Finished Rainfall Hatá F * c? 1 hr z s (X) after 21 days quantity (Ka / ha) 0.14 0.42 over 1 year Round up + 0, 5t X L - // + + 10f /. F'EG-200 no 80 100 90 - v a π 80 99 90 Roundup + ltX L- -77 ni ncs X ¹ ·? 50 36 there is 42 77 59 Roundup + ltX L- -77+ + 5tX PEG-200 n i n c s 17 50 33 there is 80 100 90

Roundup + 1tX L-7 / +

+ 1OLX PEG - 200 ΙΊ i ne5 50 97 74 there is 65 98 82

Comment:

* - H0 (CH ^ CUsjO) _r , H

- 4.5 ··························································································•

Example 7

Treatment of rootstock sorghum grass

Finished Slurry Effect Abdomen (k (X) After 21 days digging: q / ha) how much 0.28 0.84 over 1 year Roundup no 15 98 56 there is 2 12 Roundup + LT7. SF-1188 no 8 85 47 there is 2 7 4 Roundup + ltZ SF-118S + +1, 25t 7. glycerin n i n c s 28 82 tZJ o there is 0 ET / 7 »She. 26 Roundup + ltX SF-1188 + + 2.5t 7. g 1 i c er i n no 82 97 89 there is 80 51 Roundup + 117. SF-118S + + 5% glycerol no 97 99 98 there is 83 98 91 Roundup + 1T7. SF-118s + + 10t7. glycerol no 97 100 98

There are 94

· * · «·· • 4 ·· ·· • · · • • # • · · · · · • • · · · • • · · * ·· · · · ··

Example 8

Treatment of kernel circkfü

preparation rainfall Effect Abdomen (S. (7.) After 21 days z digging q / ha) how much ski 0.14 0.42 over 1 a.g Roundup no 0 98 49 there is 7 83 45 Roundup + lt7. L-7607 no 12 48 31 there is 27 87 57 Roundup + lt'Á L-7607 + + lt7. glycerol no 37 32 ' 4 Zj. there is 27 67 47 Roundup + l t7. L-7607 + + 3t'Á glycerol no 43 97 70 there is 3S 88 63 Roundup + l t7. + L-7607 + 5t7. glycerol no 63 100 82 there is 90 95 93 Roundup + l 17. L-7607 + +1 Ot7. g 1 i c er i n n i n c s Ο · ζ .100 97 there is 83 98 91

ex da

Seedling of sorghum grass

Prepared product

Slurry

Effect </.) After 21 days

Application rate (kq / ha)

0.14 0.42 average

Roundup no 0 98 49 there is 7 83 45 Roundup + ltX SF-1188 no 0 33 17 there is 13 76 45 Roundup + ltX SF-11B8 + + lt.X glycerin no 3 59 31 there is 55 87 71 Roundup + ltX SF-1188 + + 3tX glycerol no 95 96 96 there is 58 99 79 Roundup + ltX SF-11S8 + + 5tX glycerol no 100 95 97 there is 93 100 97 Roundup + ltX SF-1188 + + 10tX glycerol no 93 100 97th there is 99 100 100

Example 10

Wall ka management

Ready made k.support Effect (7.) 28 Sun after Abdomen Zηάΐásí how much (Ka / ha) 1.12 2.25 3 ¹ 5 · ~ '(Σί' average Roundup no 50 77 71 there is 23 47 73 47 Roundup + 0,25t7. L-77 no 45 67 96 69 there is 45 82 57 61 Roundup + 0.25t * Z L - 77 + + 2.5% glycerol no 70 SS 90 82 there is 58 73 61 Roundup + 0.25t 7. L-77 + + 5t7. glycerol no 57 85 O Cj 80 there is 57 67 72 65 Roundup + 0.25tX L-77 + + 10tZ glycerol no 65 74 76 72 there is 47 95 65 6? Roundup + en% L - 77 no 65 75 87 76 there is 6u 73 73 69

<10th continued example table)

Finished Rainfall Effect Abdomen (K (X) After 28 days ználási /if) how much 1.12 J .., x. U 3.38 over 1 year Roundup + ltX L-77 + + 2.5t * Z glycerol n i n c s O7 84 80 77 there is 53 70 79 69 Roundup + 1T7. L-77 + -1-517. glycerol no 70 88 90 83 there is 53 O3 90 6? Roun d up +117, L.-77 + + 10% glycerol no 89 93 99 94 there is 77 63 92 77

11 »example

Seedling of sorghum

Finished

Slurry

Effect (?) After 2-3 days

Application rate (kg / h a)

O, 14 o, 4 2 á 11 a g

Roundup no 12 97 54 there is b 63 34 R o u n d u p + 0.2 S t? L-77 n i n c s 7 ~ 5 there is 3 17 10 Round up + 0.25t? L-77 + + 5t? sorbitol no 'pT 93 58 there is .13 85 49 Roundup-i-0.25t? L-77 + + 10t? sorbitol no 27 100 63 there is 23 94 59 Roundup + IOT? s orb i tcl no 32 98 65 there is 7 20 13

12 »example

Seed sorghum treatment

Finished Slurry Effect ('Z) 24 Above h ci S Π ά 1 ώi after a day how much ski (k q / ha) 0.14 0.42 over 1 year Roundup n i ncs 15 98 56 there is 10 87 48 Roundup + 0,05t7. L-77 no 12 38 .25 there is 17 2 o'clock Roundup + O, 05t7. L-77 + + 2,5t7. glycerol no 87 99 93 there is 72 100 86 Roundup + 0,05t7. L .-- 77+ + 5t Z glycerol η i n c s 98 98 98 there is 85 100 92 Roundup + 0.05; 7th L-77 + + 10t7. glycerol no 94 99 97 there is 9 Λ 95 94 Roundup + 0, iOtX L-77 no 8 8 8 there is 13 84 49

(continuation of example table 12)

Prepared product

Slurry

Effect (7th) after 24 days

Application rate (I; q / h a) over 1 hp

R o u n d u p + 0.1017. L- -77+ +2.517. glycerol n i n c s 79 100 S9 there is 7 plenty of • 45 R o u n d u ρ + 0, 1017. L- -77+ + 5tZ glycerol no 98 CjCj j f 99 there is 63 81 Roun d up +0, 1 5 7. l ._- -77+ + 10t7, glycerol no 90 C / C; 95 there is WZ. 93 90 Roundup + 0, 30t7. L- -77 no 7 18 13 there is 17 87 52 Roun d up + 0.30t 7. L_- -77+ + 2,5t7. glycerol no 20 SS 54 there is 18 65 42 Roundup + 0,30t7. L- -77+ + 5tX glycerol no 86 99 93 there is 52 99 75

Seedy

Example 13 Treatment of sorghum

Preparation Wetting Effect (7) After 21 days

Application rate (kq / ha)

0.14 0.42 over 1 year Roundup no 98 60 there is She 5 3 Roundup + 0.25t 7. L ~ 77 no 0 5 ₃ there is 0 0 0 Roun dup + 0.25t 7, L-77 + + 10tZ glycerol no 98 100 99 there is 93 97 95 Roundup + lt7. L-77 no 3 55 29 there is 15 28 five* Roundup + 117. L-77 + +1 Ot 7. g 1 i c er i n no 78 100 89 there is 67 100 83 Roundup + 0.25ta L-7607 no 0 12 6 there is She 1 Roundup + 0.25t 7. L-7607 + + 10t7. glycerol no 98 100 '99 there is 77 98 88

• * · «

- 40 (continued table in Example 13)

Prepared product

Rainfall Effect (X) after 21 days

Application rate (kg / h a)

0.14 0.42 over 1 year Roundup +117. L- / 607 no 0 7+) 16 there is 0 8 4 Roundup + 1t7 L-7607 + + i0t7. glycerol no 97 100 OCI there is 73 95 87 Roundup + 0,25t7. SF-1188 n i n c 5 0 13 7 ' there is 0 0 0 Roundup + 0,25t7. SF-1188 + + 10t7. glycerol ni ncs 92 100 96 there is 10 65 Roundup + ltX SF-1188 n i ncs 0 15 8 there is 0 0 0 Roundup + ltX SF-118B + + 10t7. glycerol nincs- 95 99 9'7 there is 33 97 65 Roundup + lOtX glycerin no 45 100 72 there is 0 8 4

I4. example

T h e r a t i o n

Ready made

Evening Effect (X) After 28 days

Application rate (kq / ha>

0.42 0.84

1.69 average

Roundup no 15 75 100 63 there is 0 5 13 6 Roundup + 0.25tX L-77 no 13 94 92 66 there is 3 7 8 6 Roundup + 0.25tX L.-77 + + 2.5tX glycerol n i ne s 9c » 99 100 98 there is VJ 18 72 32 Roundup + 0.25tX L - 77+ + 5tX glycerol no 97 99 99 98 there is 17 38 56 37 Roundup + 0.25t7, L-77 + + 10tX glycerol no 97 88 99 95 there is 58 42 70 57 Roundup + ltX L-77 no 23 72 39 there is 0 2 1

(continue the table in Example 14)

Finished

I- Training bet and Effect (X) after 28 days

Application rate (kg / h a)

Roundup + ltX L-77 + + 2,517. □ 1 i c er i π van

Roundup + ltX L.-7 / + + 5tX glycerin

Roundup + ltX L .-- There is 77+ + 10tX of glycerin

100

p. ~ ·

100 100

• · • ·

Example 15 but ?.

Seedling of sorghum grass

Ready to work

Effect (7th) after 22 days

Application rate (k q / h a)

0.14 0.42 average

Roundup ri i n c s 8 9? 54 there is 3 32 18 Roundup + 0.2517. L-77 no 13 3 8 there is 0 18 9 Roundup + 0,25t7. + L-77 + 5t7. glycerol ni ncs 9'3 99 96 there is 58 97 78 Roundup + 0,25t7. L-77 + + 5t7. dextrose no 5h 99 76 v a n 15 85 50 Roundup + 0,25t7. L-77 + + 5tX sodium lactate no 97 100 98 there is 3 47 2'0 Roundup + 0,15t7. L-77 + + 5t% lactic acid no 52 97 74 there is 7 nn 14

Λ

- 44 · -

(see Table 15 ρέ-lda Preparation 1 Continued) Cooling H cl ti cl Abdomen (7th) 22 plays (1i q / ha) after a day how many shes 0.14 0.42 over 1 year R o u n d u p + 0.2 517. L - 7 7 + + 5t 7. tr i et i 1 en 1 i kο 1 ni ncs 91 99 95 - there is 91 98 95 Roundup + 0,25t7. L-77 + + 5t7. PEG-200 r i i ne 5 91 OQ 96 there is 57 99 78 Roundup + 0.25tZ L-77 + +517. Μ ο 1 a s s e s no 12 5 there is 15 30 23 Roundup + 5t7. dsxtróz n i π c s 13 97 there is 5 10 8 Roundup & 517th sodium to um1 file t n i n c s 75 100 88 there is 27 14 Roundu.p + 5tX tej weeks no 40 82 61 there is Ü 33 17 Roundup + 5t7. triethylene glycol is absent 67 99 83 there is 0 10 5 R o u n d u ρ + o 17. P E G - 2 0 0 no 62 oc 80

there is

(continued table in example 15)

Finished Eats bet Effect (“Z”) after 22 days Application (Kq / ha) how much 0.14 0.42 over 1 year Roundup + 5t7. reeds asz no 5 2 3 there is 5 2 3

Example 16

Treating Seeds of Sorghum Without Irrigation

preparation

Effect after 7 days

Application rate (kq / ha)

0.14 over 1 g

Roundup 62 98 80 Roundup + 0.0117. L-77 i 3 97 05 Roundup + 0.01 t'ZL-77 + 0.25t7. glycerol 5 77 41 Roundup + 0.01 t ° Z L-77 + 0.5t7. glycerol Shoot 90 oo Roundup + 0.01 tZ L - 77 + l, 0t7. glycerol 25 97 61 Roundup + 0.011% L - 77 + 0.15tX TEG * | She 83 47 Roundup + 0, Olt λ L-77 + 0.5t * Z TEG 12 93 5z Roundup + 0,01t7. L-77 + 1.00t7. TEG 42 88 65

· £ £ <<<<(((((((((((((((((((((((((((((((((((((((((((((((((atása (atása folyt

Formulation Effect (%) after 21 days

Application rate (kg / ha)

0.14 0.42 average

R o u n d u p + 0.0251% L - 7 7 68 36 Roun d u ρ + C>, C> 2 51 X L · -77 + 0.0251 /the cil iceri n • 45 23 Roundup + 0,025t7. L-77 + 0,50t'Á gli ceri n 2 57 2? R oun d u ρ +0,02517. L - 77 + 1, 001 7. gli cerin 15 78 46 R o u n d u p + 0.0251% L - 7 7 + 0.2 51 7. TEG / • «J 43 23 Rounduρ +0, 02517. L-77 + 0.5017. 1 hr G BOW 55 28 Roundup + 0,025t7. L-77 + 1.00t7. TEG 13 77 45 Roun dup + 0.05t 7 L-77 n ~ 15 Roundup + 0,05t7. L-77 + 0,50t7. gli cer i n 0 8 4 · Roundup + 0,05t.7. L-77 + 1, OOt7. glycerol 7 35 18 Roundup + 0.05t 7. L-77 + 2.50t7. gli ceri n 58 73 66 Roundup + 0.05t7 L-77 + 0.50tX TEG 0 13 7 Roundup + 0,05t7. L-77 + 1,00t7. TEG 0 -ζτ p · s. '· -J » 17

···· ·" ···· *· • · · · " * " · · ··· · • " · · · the* .. ··· ·"

4'7 (continuation of table in Example 16)

Preparation Effect (* /.) After 21 days

Application rate (kg / h a)

0.14 0.42 avg Roundup + Ü, 05t 7. L-77 + 2.50t? TEG 25 75 50 Roun dup +0.1 Ci17. L-77 3 13 8 Roundup + 0, lOt'z L-77 + 0.50t? gli cerin 8 5 Roundup + 0, Here? L-77 + 1, OOt '/ l gli ceri n 2 15 8 Roundup + 0,10t7. L-77 + 2,50t7. gli ceri n 02 92 ~ 7 ^ / .c. Roundup + 0, lüt '/. L-77 + 0.50t.Z TEG 7 2 4 Roundup + 0, lOt'Z L-77 + 1, ÜOt ° /. TEG - She * 2? Roundup + 0, lOt? L-77 + 2.50t 7. TEG 27 78 53

Comment:

tri eti 1éngli col.

• · • · · · ··· · · · λ · • V

Example 17

Treatment of Serbian

Finished yoke «· · · · · · · · · · · · · ·

Rainfall Effect <'<) After 22 days

Usage rate (k □ / 'ti a)

O, 07 0.21

Roundup

R o u n d u p + 0, 2 51 λ L - 7 7

R o u n d u ρ + 0.2 517 L - 7 7 + 5t '·: glycerol

η i n c s 60 100 100 there is 0 57 η i n c s 43 EA ~> Cz vein . '' 1 (Ϊ EO Yeah no 8Ό 95 100

7.0 van .t 00 • · ·

- 49 Example 18

IJ j j asmuhar and pig stew! without torrential rain preparation User. Impact (7) After 20 days how much crabgrass pigweed (k q / h a> Roundup 0.07 20 0 0.21 96 100 0.35 98 100 0.49 100 100 average 76 7 o Roundup + 0,25tZL -77 0.07 0 / Zi 0.21 33 100 0.35 72 100 0.49 78 100 over 1 aq 94 + 0,25tZ Roundup L-77 + 5tZ glycerol in 0.07 67 100 0.21 97 95 0.35 100 100 0.49 100 100 average 91 99

Example 19

Roz snok and sel ' vemperje hands neither preparation Plant E söztetés Effect( X) 23 after a day Abdomen digging i how much (k q / h a ) 0.35 0.49 over 1 year Roundup roz snok no 83 Ο 38 there is 68 63 sel yernper je n i n c s 50 77 63 there is BOW 2 1 Roun dup + 0.25t 7. L - 77 brome n i nos 63 equ 72 there is / 77 62 'S 1 y €? fϊ j p G j 3 n i ne s 80 80 80 there is EA 9 bows vij R o u n d u p -I- 0.2 51X L - 7 7 + · 517. g 1 i c e r i n brome n i η c s 00 100 100 there is 99 100 100 velvetleaf ni nos 47 í “7 > / 72 there is 98 98 98

• ♦

Example 20

Treatment of seed sorghum without anesthesia

Ready to drink

Effect (7th) after 21 days

Application rate (k q / h a) over 1 a g

Roundup 85 99 0 '' .; Roundup + 0,25t7. L - 77 20 63 42 Roundup + O, 25tZ, L-77 + 5t'Z glycerol 97 100 98 MON-O139 / MON-0818 (2: 1) 78 O Q 89 MON-O139 / MON - 0818 + 0.25t 7. L-77 15 etc. 51 MON-0139/0818 + M0N-0,25t7. L-77 + 5t7. glycerol 93 98 96 MON-0139 / M0N-0818 (4: 1) 73 99 86 MON-0139/0818-MON + 0,25t7. L-77 18 47 "·? ·? M0M-0139 / M0N-0818 + 0.25t'Z L-77 + 5L7. glycerol 94 100 97 MON-O 139 / MON - 0S18 (8: 1) • -2 '/ 100 68 MON-O 139 / MON-0818 + 0.25t7. L-77 10 38 24 MON-0139 / HON-0S18 + 0,25t7. L-77 + 5t7. glycerol 99 100 1OO MON-O139 / Arquad T50 (2: 1) 87 100 93 ΜΟΝ-0139 / Arquad T50 + O, 25t7. L-77 17 76 46

(continued table in example 20)

Ready made Effect Up ha (X) After 21 days, you will b & si meηnyi s ι (Ka / ha) 0.14 0.42 average M □ N-0139 / Arquad T 5 0 + 0.251.X L- / 7 + + ST7. glycerol oc 100 90 M0N-0139 / Arquad T50 (4; 1) 90 100 95 MuN-0139 / Arquad T50 + 0.23t7. L- 7 7 13 53 33 M □ N-0139 / Ar quad T50 + 0.251X L- 77+ + 31X glycerol 98 100 99 MDN-0139 / Arquad T50 (Ssl) -Yeah 100 72 HON-0139 / Arquad T50 + 0.25 tX L- 7 7 10 43 2 - N0N-0139 / Arquad T50 + 0.25t7. L .. ~ 77+ + 5t7. glycerol 98 100 CZ · '.33 MDN-0139 / Ethoquad 0--25 (2: 1) 7 2 99 O A MDN-0139 / Ethoquad 0-23 + 0.2 V.J l / 3 L-77 18 84 51 MDN-0139 / Ethoquad 0--23 + 0.2 stx; L - + 77 + 5t7. glycerol Cd ji. 100 81 MDN-0139 / Ethoquad (4: 1) 48 98 73 MDN - 0139 / Ethoquad 0-25 + 0.2 5t% L-77 18 33 2 o'clock MDN-0139 / Ethoquad 0-25 + 0.2 L-77 + + 5% glycerol 95 100 98 MDN-0139 / Ethoquad 0-25 (8: 1) 20 99 k = io V_> f

(continued table in example 20)

Preparation Effect (7) After 21 days

Application rate (kg / ha)

0.14 0.4 2 over 1 year NDN-0139 / Ethoquad 0-25 + 0.25tX L-77 7 33 20 M0N-0139 / Ethoquad 0-25 + 0.25tX L-77 + + 5tX glycerol 99 100 99 M0N-0139 / Arquad B-100 C2: i) 74 100 87 ' MON-O139 / Arquad B-100 + 0.25tX L-77 27 85 58 MON-O139 / Arquad B-100 + 0.25tX L-77 '' + + 5tX glycerol 9 cp ψ 96 0-0139 / Arquad B-100 (4: 1) 77 100 88 M0N-0139 / Arquad B-100 + 0.25tX L-77 25 73 49 MON-O139 / Arquad B-100 + 0.25tX L-77 + + 5tX glycerol 99 100 100 MON-O139 / Arquad B-100 (8: 1) 33 100 67 M0N-0139 / Arquad B-100 + 0.15tX L-77 23 73 42 M0N-0139 / Arquad B-100 + 0.25tX L-77 + + 5tX glycerol 99 100 100 Notes: Arquad T50 ~ compound of formula (A), where rn and n

total of 15

Ethoquad 0-25 = Compound of Formula (B) wherein R is tallow

M0M-0818 = Compound of Formula (C) wherein R is tallow, in, n and p total 20

Arquad B-100 = Compound of Formula (D) wherein R is z i s s a v.

Example 21 Selvemperj 5 treatment without irrigation

Ready made H 0 1- cλ s Abdomen above (7.) After 21 days ználási (ka / h a) how many s> 0.35 0 .. 5 6 average Roundup 3'7 77 52 R 0 u π d u p + 0.2 517. L - 7 7 72 87 79 Roundup + 0.25tX L-77 + 5t7, glycerin 68 94 81 MON-O139 / M0N-0818 (2: 1) 38 7 b 57 MON-O139 / M0N-0818 + 0,25t7. L-77 68 o ~? Ox. 75 MON-O139 / H0N-0818 + 0,25t7. L-77 + 5t7. glycerol 83 91 87 MON-O139 / M0N-0S18 (4: 1) 23 70 47 Milne-0139 / M0N - 0818 + 0,25t7. L-77 68 87 78

(Continue the table in Example 21)

Finished Effect (7th) after 21 days Use amount (k q / h a)

0.35 0.56 average

MON-0139/0313 + Μ0Ν-0,25t7. L- ~ / 7 + 5t7. glycerol / 7 87 82 MON-O139 / MDN-0818 (8: 1) 20 68 44 M0N - 0139/0818 + M0N-0,25t7. L- -77 73 87 80 M0N-0139/0818 + M0N-0,25t7. L- -77 + 5t.7. gli seri n 73 87 80 M0N ~ 0139 / Arquad T50 (2: 1) 25 78 52 MON-O139 / Arquad T50 + 0.25tX L-77 25 58 42 MON-0139 / Arquad T50 + 0.25t7. L. - / / + + 5tX glycerol 73 93 83 MDN - 0139 / Arquad T50 (4: 1) 3 72 • 70 FI 0 N - 013 9 / A r q u a d T50 + 0.2317. L-77 55 75 65 ΙΊ0Ν-0139 / Arquad T50 + 0.25t7. + L-77 + 5t'Z glycerol 65 88 77 M0N-0139 / Arquad T50 (8: 1) 5 60 32 M0N-0139 / Arquad T50 + 0.25t'Z L-77 60 77 68 M0N-0139 / Arquad T50 + 0.25t7. L-77 + + 5t'Á glycerol 75 83 79 ΜΟΝ-0139 / Ethoquad 0-25 (2: 1> 15 80 48

(continued table in example 21)

Prepared product Effect Abdomen (7.) After 21 days, you will see the Merinyi ski (Kq / ha) 0.35 0.56 over 1 year M0N-0139 / EthDquad 0-25 + 0.25t 7. L-77 73 62 M 0N-0139 / Ethoquad 0-25 + 0.25% L-77 + 45t7. glycerol 77 88 82 MON-O139 / Ethoquad (4: 1) 12 68 40 M 0 N-0139 / Et hoq u a d 0-25 + 0.25t 7. L-77 62 77 69 MON-O139 / Et hoquad 0-25 + 0.25 ° L-77 + + 5t7. glycerol 77 85 82 M 0 N -0139 / Ethoquad 0-25 (Front) 7 47 27 Μ 0 N - 013 9 / E t h o q u a d 0-25 + 0,25tZ L-77 73 90 82 MON-O139 / Ethoquad 0-25 + 0.25t 7. L-77 + + 5tX glycerol 75 86 81 ΜΟΝ-0139 / Arquad B- -100 (2: 1) 1E 62 40 MON-O139 / Arquad B- -100 + 0,25t7. 1 ..- 77 63 68 66

MON-O139 / Arquad B-100 + 0.2bt7. L-77 +

+ 5t7. glycerol 77 87 82 MON-O139 / Arquad B-100 (4: 1) 2 28 MDN-0139 / Arquad B-100 + 0.25t7. L-77 82 78 80

(continued table in example 21)

Preparation Effect (7) After 21 days

Application rate (kq / ha),

0.35 0.56 average

ΜΟΝ-O139 / Arquad B- -100 + 0,25t7. L- -77 + + 5tX glycerol 62 83 72 MDN 0139 / Arquad B- -100 (8: 1) 3 63 .í'ó MON-O139 / Arquad B- -100 + 0,15t7. Κ- -77 60 90 75 NON-O139 / Arquad B- Ι 00 + 0.25h 7. L- -77+ + 5fZ glycerol 67 ' 78 72

Example 22

Treatment of seed sorghum and cocksfoot grass with a use rate of 0.42 kq / ha

Finished Slurry Impact (7) seedy c i r o k t ü After 27 days kakasl ab-f ü Roundup no 100 73 - there is 30 Roundup + 0,25t7. L -77 no 84 65 there is 0 17 Roundup + 0.25t 7. L -77 + 5t71 glycerol n i ncs 99 90 there is b'5 S9 MON-0139-1-0,09t7. M0N-081S no 100 94 there is 40 0'7 MON-0139 + 0.09t 7. MDN-081B + 0,25t7. I_-77 no 68 50 there is 3 13 MON-0139 + 0.09t 7. MDN-0818 + + 0,25t7. L-77 + 5Í7. gli ceri n no 100 97 there is 97 97 MON-0139 + 0.09t 7. Witconate X-7163 ni ncs 85 69 there is 13 23

(continued table in example 22)

Ready to drink

Rainfall Effect (X) After 27 days, Seedweed Sorghum

MuN-0139 + 0.09tX Witconate

X-7163 + 0,25t7. L - 77 no 15 12 there is 17 20 HüN-0139 + 0.09t.X Wi tconate X-7163 + 0.25tX L - 77 + 5t7. gl i ceri n no 100 95 there is 90 80 MON-0139 + 0.09tZ Ethoquad C / 12 ni ncs 100 100 there is 80 50 M0N-0139 + 0.09tX Ethoquad C / 12 + + 0.15tX 1.-77 ni ncs 40 65 there is 27 MDN-0139 + 0.09tZ Ethoquad C / 12 + + 0,25t7. L-77 + 5% glycerol no 100 9v there is 100 85 MON-0139 + 0.09tX Sorpol S227 no 100 87 there is 17 12 MDN-0139 + 0.09tX Sorpol 8227+ + 0.25tZ L-77 no 42 30 there is 8 3

(continued table in example 22)

Preparation Irrigation Effect (7.) After 27 days, coccyx foot seeds

M0N-0139 + 0.0917. Sorpol 8227+

+ 0,25t7. L-77 + 5t7. glycerol n i ncs 9 / Ί 98 there is 91 74 M □ N-0139 + 0.0917. Ethomeen C / 12 n i n c s 98 t ^: there is 27 17 HD N-0139 + 0.0917 »Ethomeen C / 12+ + 0.25tX L - 77 no 38 70 there is 13 cr VJ MDN-0139 + 0.09% Ethomeen C / 12 + 4-0.25t7 »L — 77 + 517. g 1 icer i n no 100 100 there is 97 M 0 N -0139 + 0.0917. I g e p a 1 C A - 7 2 0 no 98 88 there is 68 60 MON-0139 + 0.09t% Igepal CA - 720 + + 0,25t7. L-77 no 12 5 there is 13 10 MON-O139 + 0.09 tX Igepal CA-720 + + 0.25tX L-77 + 5t7. glycerol no 100 95 there is 97 91

(continued table in example 22)

- 61 Preparations

Slurry

Effect ('Z) After 27 days, coccyx foot seeds

ΙΊ0Ν-0139 + 0.09t% increase 1 phenol

mix no 100 94 there is 30 ··? " MDN-0139 + 0,09t7. nonylphenol + 0,25t7 mixture. L-77 no 3 12 there is 18 13 M0N ~ 0139 + 0.09 tn + nylphenol + O mixture, 23t7. L-77 + 5fZ glycerol no 100 98 there is 87 70 M0N-0139 + 0,09t7. Sterox NJ no 100 91 there is She 0 MDN-0139 + 0.09t 7. St er οχ N J + + 0,23t7. L-77 no 28 10 there is 0 0 M0N - 0139 + 0,09t7. Sterox NJ + + 0,25t7. L-77 + 5t7. glycerol no 100 90 there is 90 86 N0N-0139 + 0,09t7. Miranol CM-SFK no 100 99 there is 0 13

(continue the table in Example 22)

Finished

Rainfall Effect <7.) After 27 days, seed-necked ab-grass sorghum-grass

M0N-0139 + 0,09t7. Miranol CM-SFK +

+ 0,25t7. L-7 / no there is 62 0 32 0 M0N-0139 + 0,09t7. Miranol CM-SFK + + 0.25t'Z L - 77 + 5t7. glycerol ni ncs 98 76 there is 95 62 MON-O139 + 0.09 Aerosol MA SALT no 5 c · 27 there is 0 0 MON-O139 + 0,09t7. Aerosol MA-80 + + 0,25t7. L-77 ni ncs 20 28 there is 0 0 MON-O139 + 0,09t7. Aerosol MA-80 + + 0.25t'Á L-77 + 5'7. glycerol no 100 88 there is 100 78 MDN-0139 + 0,09t7. Frigate n i ncs 100 95 there is 45 43 MON-O139 + 0,09t7. Fri gate + 0.25t7. L-77 no 73 78 there is 10 8

(continue the table in Example 22)

Finished

Slurry

Effect (7th) After 27 days, seed-necked alphabet

MON-O139 + 0.09t 7. Fr i gate + 0.25t7.

L-77 + 5t7. glycerol no 100 93 there is 85 98

Notes i

Witconate X-7163 = Compound of Formula (E) wherein n is 8-10

Igepal CA-720 = Compound (F)

Sterox NJ = Compound (G)

Mixture of Sorpol 8227 - Compound of Formula (H) and Alkyl 1-Phenol-Ethoxy

Ethoquad C / 12 = Compound of Formula (J) wherein R is coconut acid

Ethomeen C / 12 = <K), wherein R is coconut fatty acid

Aerosol MA-80 = Compound of Formula (L)

Frigate = Excipient based on tallowamine ethoxy1

Miranol CM-SFK = a compound of formula (M) or (N) wherein R is coconut fatty acid

- 64 - Example 23 Seeds of sorghum and cocoa slábfu treats and 0.42 kq / ha utilization at dig qqel preparation Eísbztetés Impact (X) After 27 days seedy barnyardgrass ci rokf ü Roundup no 100 88 there is 17 25 Roundup + 0,25t7. L-77 no 50 there is 8 17 Roundup + 0,25t7. L-77 + 5TX gli cerin n i n c s 100 94 there is 97 87 no r i um-g1i f it pass. + 0,09t7. M0N-081S no 98 80 there is 45 27 n through.r ium-g 1 i phos + 0.09t 7. M0N-0818 + 0.25t 7. L-77 no 42 37 there is 10 3 sodium um-gl-i-phosphate + 0.09t7. M0N-0818 + 0,25t7. L-77 + + 5t7. glycerol no 100 92 there is 99 80

(continued table in example 23)

Preparation Wetting Effect (Z) After 27 days Seedling Cockroach Sorghum Potassium Glyphosate + 0.09tZ

Μ0Ν-081Θ no 99 83 there is 48 28 k á 1 i u m - g 1 i f o z á t + 0, 0 917. M0N-0818 + 0.25tZ L-77 ni ncs 62 55 there is 7 13 potassium um-gli phosate + 0.09tZ M0N-0818 + 0.25tZ L.-77 + + 5tZ glycerol no 100 73 there is 96 90 copper ~ gl i phosate + 0.09tZ M0N-0818 no 97 70 there is 3 10 copper-gl i phosphate + 0.09tZ M0N-0818 + 0.25tZ L - 77 n i n c s 12 there is 7 3 copper-glyli phosate + 0.09tZ MON-OS18 + 0.25tZ L-77 + + 5tZ glycerol no 100 72 there is 96 67

* «·· ························································································································································································· declining ·

- 66 (continued Table of Example 23)

Inventory / Irrigation Effect (?) After 27 days rn a g w a s k a s 1 a b τ ü ci rock

IP A-g 1 i f o z á t + 0, 091 7.

H0N-0S18

ΪΡΑ glyphosate + 0.09?

Μ0Ν-0818 · ι 0.25? L-77

IFA- g 1 i ΐ o z á t +0, 091?

M0N-0818 + 0,25t7. L-77 ++ 5t? glycerin a m m ó π i u m - c, · 1 i f o z á t + 0.0 91?

M0M-0S18 a m m ά n i u rn - g 1 i f o z á t + 0.0 91? MQN-OSIS + O, 2517th L-77 a m rn ó n i u m - g 1 i f o z á t + 0.0 91?

M0N-0S18 + 0, 25t? L-77 + i-51? glycerol

n i n c s 100 / 8 there is 3 3 43 π i n c s 58 - ~ the there is 15 "7" no 100 SS vari 8S 8U η i n l s 100 8 8 there is -η * '*> 3 Ej n i n c s 8y 81 there is 7 n i ne s 100 lake lake

van ······································································································································· *

Example 24

Treatment of seed sorghum grass and cocksfoot grass 0.42 kq / ha 1 π ^- , 'e η π yis é qqe 1

Preparation after day m a g w a s k a s 1 á b + ü c i r o k -F i.'t

Roundup n i n c s 100 90 there is 50 30 M 0 N - 013 9 + 0.0 917. H 0 N -0318 n i n c s 100 6h there is 37 27 MON-0139 + 0.09t 7. M0N-0313 + + 0,25t7. L-77 η i n c s 97 73 there is ~ r 17 M D M — ü 16> 9 + O, 0 91X Μ 0 N ~ 0 31S + · +0, 2 517. L - 7 7 + 517, g 1 i c e r i n no 100 89 there is 100 SKI M0N - 0139 + 0.09tZ M0N - 0313 + + 0,25t7. L-77 + 5t7. dipropylene 1engli col n i n c s 69 50 there is 27 30 MON-0139 + 0.0? T 7. M0N-03? 8+ + 0.25tX L - 77 + 5tZ ethylene- gl i k cüI n i n c s 57 ' 47 there is 17

· «·« • * ·······························································•

- 68 (continued Table of Example 24)

Preparation Eating Effect \ 7) After 26 days, coccyx foot seeds

MQN-0139 + 0.09t7 M0N-0818 +

+0.2 517 L · - 7 / + 517 b u t a η ο 1 no v a n J'Z. • 2 · Ό Μ □ N + 0139 0,09t7. M0N-0818 + + 0.25t7 L ~ 77 + 5t7 glucose no CG > 'C5 there is FIVE Cj ”5 M 0 N -0139 + 0.0917. M □ N - 0 818+ +0.2 517 L ~ 7 7 + 517 f r u k t ó z ni ncs 100 O A there is 'y' O 62 M 0 N ~ 0139 + 0.0917 M □ N ~ 0 818+ +0.2517 L. - 7 7 + 517. s z a h a r ó z n i ncs 100 S4 there is BTJ She /'

Notes:

M0N-0139 = 62 7 Aqueous concentrate of N-phosphotomethyl 1 glycine n-isopropyl amide salt

M0N-0818 = ethoxylated tallow surfactant.

«· · · · · · · · · · · · · · · · · · · · · · · · · · · · · ··· ·

Example 25 »

Μ a q ν a s c i r o k + 'ü, cocksfoot and handling your ski jumper 0.42kq / ha use i how much séqqel preparation Esőstétés Impact (X ) After 28 days seedy k & k ti ~~ Selva c i r o k -F ü foot through je Roundup π i π c s 00 100 there is 3- She 0 Roundup + 0.23tX L-77 no V J 42 100 there is 20 100 R o u n d u p + 0.2 5tX L - 7 7+ + ltX glycerol ni ncs 47 90 100 there is 60 73 07 Roundup + 0.25tX L.-77 + + 5tX g1i cer i rί This is because 100 100 there is 100 100 100 ammonium g1-iosate + O, 0917th M0N-0818 n i n c s 100 92 there is "7 '" » J ** · V j 0 ammonium glycate + 0, 09tX MGM-0818 + 0.25tX L-77 n i ne s 3o ZJ ZJ 100

10 ί 00 (continuation of Example 25 table)

Preparation Wetting Effect (X) After 28 days Ammonium glyphosate + O, 0 917 Seeds of Cockroach Silk c i r o k f i i f i n g.

MON-O818 + O, 25t7. L-77 +

+ lt7. glycerol π i n c s there is 'D / 9? 5'6 00 .1.00 a m m u n i u m - g 1 i f o z á t + 0.0 917, M0N-0818f 0.25+ 7. L.-77 + -f-5t'Z glycerol no 100 .100 100 there is 100 100 O ~ 7 'I mmonium glyphosate + O, 0 917 ,, Ethoquad C / 12 no 100 10U 72 v a n 17 17 0 ammonium glycate + 0.0917, E t h o q u a d C / i 2 + 0.2 51 7. L - 7 7 n i n c s 30 48 100 there is · 7 ζ3 88 arninőnium glyphosate + 0.0917. Ethoquad C / 12 + 0.25t7, L_ ~ 77 + LT7. glycerol ni ncs 65 95 100 there is 15 18 1OO

(continued table in example 25)

Preparation Wetting Effect (7.) After 28 days, g v c <s k a s - s e 1 y e rn sorghum fungus m m u n i u m - g 1 i sho w + 0.0 917.

EtOAc C / 12 + 0.25t7.

+ 5t7. glycerol n i n c s 100 100 100 there is 97 92 75

2a. example

Managing wind-eveiϋ weeds

Finished USES digging how much (Kg / ha) Effect (7) 21 after a day selyern- during this hemp í Salt - ni a) serpentine s h a j n a 1 ..... K B1 is er + 0.14 0 0 0 20 0.42 3 0 She 33 El Azer + 0.5tX Triton AG — 98 0.14 2 0 She 47 0.42 17 3 10 97 B1 azer + 0.5t Λ Triton AG-98 + + 0,5t7. L-77 0.14 2o 20 47 0.42 37 67 27 100

(a.

example table above)

Finished Utilize-- Effect (7) 21 after a day Γΐ á 1 cd 'Ξ> 1 hemp how much Serbian- dawn- silk- (hemp sesbania (Kq / ha) t ö v i s kai through j e? n i a)

B1 azer + ú, bt 7.

ir.it.on A'J-9ü + + 0.5t7 L-77 +

+1 ö 17 g 1 i c e r i n 0.14 17 47 27 72 0.42 37 100 88 97 B1 azer + 0, 5t < L-77 0.14 10 33 20 28 0.42 25 68 87 100 El Azer + 0.5tZ L-77 + 10t7. glycolic cer i n 0, 14 17 0 33 27 0.42 60 98 80 77 El Azer + 0.5t7i X-45 & 10L7. glycolic glycerol 0.14 20 23 20 57 0.42 20 43 48 100 B1 azer + 0.5t7i X-45 & 0,5t7. L-77 ^;, + + 10tX glycerol 0.14 7 20 17 48 0.42 18 78 63 97

(a 2'6.

continued example table)

Ready to work

USER

Effect ΟΧ) After 21 days, amount of hemp in Serbian - dawn silk - (Sesba ____ (kg / ha) ____ rootstock per a)

IBI azer + O, 5tX

Tri t οπ AG-9S + +0,517. Igepal

CA-210 + lOtX

gli cerín 0.14 0.42 17 1 2 0 53 B1 azer + 0.5t7. L-77 + 0,5tX Igepal CA-630 + + 10t7. glycerol 0.14 30 0.42 45 ' lake / 53 100

Notes:

* - active ingredient: acif1uorfen

Triton AG-98 - 80 tX Alkyl-1-Poly (oxyethylene) glycol; excipient

Triton X40 - Lig, H i'z L1 (GH ^ CH ^ O)? ^ H

Igepal CA-630 = C _e H ₇ ---------- 0 -------------- (CH ₌ CH _S O) ^ H

Igepal CA-210 = C _a H _iV -------- 0 -------------- (CH _a CH ₂ 0) x, _B H

Example 27

Seeds of sorghum and cocksfoot are treated with 0.42 kq / ha

Usage quantity

Prepared product Effect (X) after 21 days Seeds of sorghum cacti 1 ab-Fü · Scepter » 2/27 Seept er + L-77 47 50

Scepter + L-77 + glycerin 57 o3

Scepter + Triton Χ-45 + Glycerin 63 47

Comment:

* ~ active ingredient: imazaquin

Example 28

Treatment of coccyx foot with 0.42 kq / ha acacia, 0.25 t * Z.

Fluid with silicone surfactant and 2.5 tZ of glycerol

Preparation Effect (X) After 25 n aps

Without Gutter With Glycerin With Glycerin With Glycerin With Glycerin Without Kin 1

Roundup 95 100 12 8 Roundup + Fluid 3 20 87 She 57 Roundup + F1u id 7 40 100 She / z Rounclup + F1 u i d 8 40 0 99 2 68 Roundup + Fluid 4 100 99 • w. · 73 Roun dup + F1u i d 6 100 100 30 / jd Roun dup + F1ui d 10 100 1OO 5 64

Example 29

Treatment of Cascade Foot Grass with 0.42 kq / ha, 0.25 tZ

Fluid colored with native surfactant and 5 µl of glycerol

Formulation Effect (Z) after 27 days

Without Grease With Glycerin With Glycerol Glycerin With Glycerol N

Roundup I00 99 2 of 27 Roundup + F1 ui d 1 100 100 UO 98 Roundup + Fluid 5 100 100 5 100

Example 30

Treatment of Cocksfoot Grass with 0.4z kq / ha application rate

Finished

Effect (Z) after 2 days

Rainfall

Without rain

Roundup 96 3 Roundup + 5tZ glycerin 94 3 Roundup + 0.5tZ Fluid 9 86 0 Roundup + 0.5tZ Fluid 9+

+ 5tZ glycerol

100 *

- / Example 31

Treatment of cervix alphabet with 0.56 kq / ha application rate

Preparation Effect (7.) After 24 days

Ö zt · · né né and 1 ku]. Esdztetéssel

Roundup 100 Roundup + ltX Fluid 6 00 oh 3 Roundup + en.7. Fluid 6 + 1t.X glycerin 100 53 Roundup + ltX Fluid 6 + 3tX Glycerin 100 86 Roundup + ltX Fluid 6 + 5tX Glycerin 100 95

Example 32

Treatment of cervix alphabet with 0.42 kq / ha application rate

Preparation Effect (X) after 26 days

This is not the case with rainfall

Roundup 98 3 Roundup + 0.251X F1 u i d 2 73 3 R o u n d u p + 0.2 517. F1 u i d 2 + 11X g 1 i c e r i n 98 40 R o u n two p + 0.2 51X Fluid 2 + 2.5tX glycerol 86 63 Roundup + 0.25tX Boys d 2 + 5tX glycerol 88 98 Roundup + 5tX q1i ceri n 85 3

Example 33

Treatment of rootstock sorghum with 0.42 kq / ha application rate

preparation

Effect (%)? after a day

Roundup

Roundup + 0.125tX Fluid 8+ + ltX glycerin

100

· 7

Roundup + 0.25tX Fluid 8+ + ltX glycerin

100

Roundup + 1tX Fluid 8+ ltX + gli cer i n

100

Roundup + ltX Fluid 6/8 • «

Example 34

Rootstock sorghum treatment with Roundup, application rate 0.56 kq / ha

Szili is horny

Glycerol

Effect ("Z) after 22 days up overactivated)

Without sprinkling Sprinkling material (0,5tZ)

- 95 fluid 11 0 52 0.5 80 1 48 76 5 100 FI ui d 7 0 13 0.5 65 1 98 98 fluid 8 She 18 0.5 45 1 72 2 99 FI ui d 6 0 90 0.5 99 1 99 2 100

/ '• · ·

- so (continuation of table in example 34)

Silicone Glycerol Effect ('Z) After 22 Days Surfactant (7) Without Inhibition By Injection (0.5t7)

Fluid 10 ü 0 5 U / '' / X. 96 60 80 1 99 93 2 99 97

Comments. · ::

A compound of formula (II) wherein Q and R are methyl, x and y are 0, G is

-CH ^ CHaCHaCOCHaCHa) - _z 0C = 0Me, z is 1 • ·

- SKI SILICONE - Surfactant

S " al cannon. Alkánegység EO unit College G1 Di meti month S3SSZ cA (Y) (M) (Z) unit First 16 0.90 12 4.60 8.5 12 1.32 12 weather J 2.0 T 12 0.50 4 5.00 8.5 4th 12 1.50 24 2.50 C. 3 0 ^z 5 » 12 0.64 7 1.36 0.0 6th 12 0.64 24 1.36 0 n 0 7th 12 0.50 4 3.50 2.0 8th 12 0.25 4 1.75 0.0 9 » 12 2.00 12 9.00 19.0 10th 12 1.00 24 4.50 8.5

Comment;

G ~ -CHaCHaCHaíOCHaCHa) _m OC = OMe * ·

Claims (28)

Claims Claims 1. An improved herbicidal composition comprising a herbicidal active ingredient, a wetting agent and a silicone surfactant. Composition according to claim 1, characterized in that the herbicidal active ingredient is 5- (2-chloro-α, α, α-trifluoro- p-tolyloxy) -2-trobenzoic acid or an agricultural salt thereof, -chloro-1- (3-ethoxy-4-trinophenoxy) -4- (trifluoromethyl) -benzene, 1 '- (ethoxycarbonyl) -ethyl 1-5-12-chloro-4 - (trifluoromethyl) phenoxy-1-2-trobenzoate, 2-14,5-dihydro-4-methyl-4- (1-methyl-1-yl) -5-oxo-1H-imidazole-2- 1111-3-quinolinecarboxylic acid or its agriculturally useful salt, N-phosphonomethylglycine or its agriculturally useful salt or mixture thereof are contained in glaze. Composition according to claim 2, characterized in that the herbicidal active ingredient is N-phosphonomethylglycine or an agriculturally acceptable salt thereof. ' 4. The composition of claim 3, wherein the herbicidal agent is N-phosphonomethylglycine-isopropylamine. Composition according to claim 3, characterized in that N-phosphonomethylglycine isopropylamine ···· - Contains 83 salt, hilwet L-77 additive and wetting agent. The composition of claim 1, wherein A silicon oxide copolymer of a polyalkylene oxide modified by a polyalkylene oxide of formula (I) as silicone surfactant, wherein a is from 3 to 24, b is from 0 to 15, x is from 0 to 3, y is from 1 to 5, Z. is hydrogen, (C 1 -C 3) alkyl or (C 2 -C 4) acyl. 7. A composition according to claim 6, wherein 1) comprising a compound of formula I wherein a is 4-7, b is 0-3, x is 0, y is 1, Z is as defined in claim 6. S. A composition according to claim 1 wherein the silicone surfactant is a compound of formula IV wherein R is independently C 1-6 alkyl, A is a linear or branched alkane 1 group having from 7 to 30 carbon atoms. - 84 -G is -R (DCH 2 CH 5) _m 0z, wherein R- is a divalent allyl group containing 1 to 6 carbon atoms, Z is hydrogen, C 1 -C 3 alkyl, or C 2 -C 4 acyl-treated, m 8-100, Q is independently selected from the group consisting of A, glycol G, or alkoxy selected from R, x is 0-100, y is 0.1-25, z is 0.1-50. The composition of claim 8, wherein 1. A composition comprising a compound of formula (V) as a silicone surfactant, wherein He means rosti 1 group. A composition according to claim 1, wherein 1. A herbicide comprising N-phosphonomethylglycine or an agriculturally useful salt thereof, and a silicone surfactant comprising a compound of formula (III) or a compound of formula (IV): Me represents a methyl group having a value of 4-7, · · * ·> 4 has a value of 0-3, denotes hydrogen atom, C 1-3 alkoxy is removed. • 4 ♦ ♦ 4 4 4 4 4 4 4 4 obsession C2-4 acilesöpört, each -függetlenül i-ώ alkyl groups Bargain, br s enathate omos individual or branched chain alkyl I No. 1 group represents -R> (0CH _{CH a)} a glycol residue of formula _m 0z where 1 represents -C 6 divalent alkyl 1 en, L. is hydrogen, C 1-3 alkyl, C2-C4 acryl, S-100 value -F t h i n g i n g va1 ams1y The group specified in your report, some of the b e e 1 e n g e d 11 The value of R in your report 0.1-50. 11. A composition according to claim 10, wherein said silicone surfactant is a compound of formula (III) wherein 4-7 'l is methyl-washed, - 88 b ranges from 0 to 3, Z is hydrogen, (C 1 -C 3) -alkyl or (C 2 -C 4) -acyl. 12, A IQ. A composition according to claim 1, wherein 1) N-Phosphonomethylglycine as an active ingredient in the form of a salt of an amine, trimethyl-1-parentmonium or iminocarbamide. 13. A composition according to claim 10, wherein It is claimed that it contains the amine salt of N-Phosphonomethylglycine isopropyl as an active ingredient. 14. The composition of claim 7, wherein the moisturizing agent is sorbitol, glycerol, polyethylene glycol, polypropylene glycol, propylene glycol, triethylene glycol, glycerol, sodium stearate, microcrystalline cellulose, a linear ethylene oxide homopolymer, or a soluble polymer thereof, contains cane molasses. A composition according to claim 7, characterized in that it contains from 2 to 70% by weight of the active ingredient. 16. A composition according to claim 12 wherein 1 to 4 to 40% by weight of active ingredient. 17. The composition of claim 13, wherein 1 e that the ready-to-use solution is 0.05-20 wt. contains the active ingredient. · · · · · · · · · · · · · · · · · · · ··· - S7 - 18. The composition of claim 14, wherein the ready-to-use solution contains from 0.15 to 5% by weight of the active ingredient. 19. The composition of claim 14, wherein the weight ratio of active ingredient to silicone surfactant is 1: 1. 20. The composition of claim 16, wherein It is noted that the weight ratio of active ingredient to silicone surfactant is 1: 30-50: 1. 21. A composition according to claim 17, wherein It is claimed that the weight ratio of active ingredient to silicone surfactant is 1: 15-10: 1. 22. The composition of claim 16, wherein: It is noted that the weight ratio of silicone surfactant to wetting agent is nearly the same. 23. The composition of claim 19, wherein the weight ratio of silicone surfactant to wetting agent is from 1: 1 to 1: 200. 24. The composition of claim 20, wherein the weight ratio of silicone surfactant to wetting agent is from 1: 5 to 1:50. 25. The composition of claim 19, wherein the weight ratio of active ingredient to excipient is ε < 1: 5-10: 1. 26. The composition of claim 22, wherein the weight ratio of active ingredient to excipient is from 1: 2 to 4: 1. 27. A composition according to claim 1, wherein It contains inert excipients and water. 28. The composition of claim 1, wherein It is claimed that it contains excipients suitable for use in dry formulations. The agent shall: