HUP9902631A2 - Detergent composition - Google Patents

Detergent composition

Info

Publication number
HUP9902631A2
HUP9902631A2 HU9902631A HUP9902631A HUP9902631A2 HU P9902631 A2 HUP9902631 A2 HU P9902631A2 HU 9902631 A HU9902631 A HU 9902631A HU P9902631 A HUP9902631 A HU P9902631A HU P9902631 A2 HUP9902631 A2 HU P9902631A2
Authority
HU
Hungary
Prior art keywords
cationic
moiety
detergent composition
alkyl
hydroxyalkyl
Prior art date
Application number
HU9902631A
Other languages
Hungarian (hu)
Inventor
Stuart Clive Askew
Robin Gibson Hall
Graham Alexander Sorrie
Original Assignee
The Procter & Gamble Co.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB9619885A external-priority patent/GB2317390A/en
Application filed by The Procter & Gamble Co. filed Critical The Procter & Gamble Co.
Publication of HUP9902631A2 publication Critical patent/HUP9902631A2/en
Publication of HUP9902631A3 publication Critical patent/HUP9902631A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/645—Mixtures of compounds all of which are cationic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Textile Engineering (AREA)
  • Detergent Compositions (AREA)

Abstract

A detergent composition or component of a detergent composition comprises a cationic surfactant and a water-soluble cationic compound. The cationic surfactant comprises cationic ester surfactants, cationic mono-alkoxylated amine surfactants, cationic bis-alkoxylated amine surfactants and mixtures of such surfactants. The water-soluble cationic compound, having clay soil removal/anti-redeposition properties, is selected from: (1) ethoxylated cationic monoamine compounds of formula (I); (2) ethoxylated cationic diamine compounds of formulae (II), (III) or (IV); (3) ethoxylated cationic polyamine compounds of formula (V); and (4) mixtures of such compounds. In (II)-(IV), M1, M2 = N+ or N, where at least 1 M2 is N+ In (V), A1 = formulae (i)-(x); R = H, 1-4C alkyl or hydroxyalkyl; R1 = 2-12C alkylene, hydroxyalkylene, alkenylene, arylene or alkarylene, or a 2-3C oxyalkylene moiety having 2-20 oxyalkylene units provided that no O-N bonds are formed; R2 = 1-4C alkyl or hydroxyalkyl, -L-X, or two R2 together form the moiety -(CH2)r-A2-(CH2)s-; A2 = -O- or -CH2-; r = 1 or 2; s = 1 or 2; r+s = 3 or 4; R3 = 1-8C alkyl or hydroxyalkyl, benzyl, L-X, or two R3 or one R2 and one R3 together form the moiety -(CH2)r-A2-(CH2)s-; R4 = substituted 3-12C alkyl, hydroxyalkyl, alkenyl, aryl or alkaryl group having p substitution sites; R5 = 1-12C alkenyl, hydroxyalkylene, alkenylene, arylene or alkarylene, or a 2-3C oxyalkylene moiety having 2-20 oxyalkylene groups provided that no O-O or O-N bonds are formed; X = nonionic group of H, 1-4C alkyl or hydroxyalkyl ester or ether groups, and mixtures of these; L = hydrophilic chain containing the polyoxyalkylene moiety -((R6O)m(CH2CH2O)n)-; R6 = 3-4C alkylene or hydroxyalkylene; m and n = numbers such that the moiety -(CH2CH2O)n- comprises \- 50 wt.% of the polyoxyalkylene moiety; d = 1 when M2 = N+, and 0 when M2 = N; n = at least 16 for the cationic monoamines, at least 6 for the cationic diamines, and at least 3 for the cationic polyamines; p = 3-8; q = 1 or 0; and t = 1 or 0 provided that t = 1 when q = 1. The ratio of (a):(b) is 1:95-95:1, preferably 1:12-8:1; with the proviso that if the detergent composition is a liquid detergent composition the water-soluble cationic compound having clay soil removal/anti-redeposition properties is selected from the cationic diamine and/or polyamine compounds. Also claimed is a method of washing laundry in a domestic washing machine where an effective amount of the above is introduced into the drum of the washing machine, preferably before washing, using a dispensing device which progressively releases the granular detergent composition into the wash liquor during the wash.
HU9902631A 1996-05-17 1997-05-16 Detergent composition HUP9902631A3 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US1788496P 1996-05-17 1996-05-17
US1788696P 1996-05-17 1996-05-17
US1788396P 1996-05-17 1996-05-17
GB9619885A GB2317390A (en) 1996-05-17 1996-09-24 Detergent compositions

Publications (2)

Publication Number Publication Date
HUP9902631A2 true HUP9902631A2 (en) 1999-12-28
HUP9902631A3 HUP9902631A3 (en) 2001-11-28

Family

ID=27451527

Family Applications (1)

Application Number Title Priority Date Filing Date
HU9902631A HUP9902631A3 (en) 1996-05-17 1997-05-16 Detergent composition

Country Status (8)

Country Link
EP (1) EP0906382A4 (en)
CN (1) CN1225668A (en)
BR (1) BR9710679A (en)
CA (1) CA2255011A1 (en)
CZ (1) CZ371798A3 (en)
HU (1) HUP9902631A3 (en)
MX (1) MX9809685A (en)
WO (1) WO1997044417A1 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1238801A (en) * 1996-09-24 1999-12-15 普罗格特-甘布尔公司 Detergent composition or component
GB2317392A (en) * 1996-09-24 1998-03-25 Procter & Gamble Detergent compositions
BR9711535A (en) * 1996-09-24 1999-08-24 Procter & Gamble Detergent compositions
GB2317395A (en) * 1996-09-24 1998-03-25 Procter & Gamble Detergent compositions
GB2317393A (en) * 1996-09-24 1998-03-25 Procter & Gamble Detergent compositions
BR9714343A (en) * 1996-09-24 2000-04-11 Procter & Gamble Particularly detergent
GB2317391A (en) * 1996-09-24 1998-03-25 Procter & Gamble Detergent compositions
US6696401B1 (en) 1999-11-09 2004-02-24 The Procter & Gamble Company Laundry detergent compositions comprising zwitterionic polyamines
CZ20021612A3 (en) * 1999-11-09 2002-11-13 The Procter & Gamble Company Detergent composition containing zwitterion polyamines
DE10044472A1 (en) * 2000-09-08 2002-03-21 Cognis Deutschland Gmbh laundry detergent
DE10044471A1 (en) * 2000-09-08 2002-03-21 Cognis Deutschland Gmbh Fabric-conditioning detergent composition comprising an anionic surfactant, a nonionic and amphoteric surfactant, a cationic polymer and a phosphate
EP1417290A1 (en) * 2001-08-16 2004-05-12 The Procter & Gamble Company Clear fabric conditioner with alkyleneoxide substituted cationic charge booster
FR2855973B1 (en) * 2003-06-12 2007-12-21 Bernard Mariotti DETERGENT / PREDESINFECTANT LIQUID COMPOSITION, CONCENTRATED AND DILUABLE, AGAINST BACTERIAL BIOFILMS.
US20080234165A1 (en) * 2007-03-20 2008-09-25 Rajan Keshav Panandiker Liquid laundry detergent compositions comprising performance boosters
CN105164241A (en) 2013-05-02 2015-12-16 艺康美国股份有限公司 Concentrated detergent composition for the improved removal of starch in warewashing applications
EP4073216B1 (en) * 2019-12-11 2023-08-09 Unilever IP Holdings B.V. Detergent composition

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1104451A (en) * 1978-02-28 1981-07-07 Manuel Juan De Luque Detergent bleach composition and process
EP0028432B1 (en) * 1979-11-03 1984-01-18 THE PROCTER & GAMBLE COMPANY Granular laundry compositions
US4664848A (en) * 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
US4597898A (en) * 1982-12-23 1986-07-01 The Proctor & Gamble Company Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties
GB9513990D0 (en) * 1995-07-08 1995-09-06 Procter & Gamble Detergent compositions

Also Published As

Publication number Publication date
CA2255011A1 (en) 1997-11-27
WO1997044417A1 (en) 1997-11-27
EP0906382A4 (en) 1999-11-24
CN1225668A (en) 1999-08-11
BR9710679A (en) 1999-08-17
CZ371798A3 (en) 1999-04-14
EP0906382A1 (en) 1999-04-07
MX9809685A (en) 1999-03-01
HUP9902631A3 (en) 2001-11-28

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