HUP9801131A2 - Titanium dioxide-catalysed cyclisation in the liquid phase of 6-amino caproic acid nitrile to caprolactam - Google Patents
Titanium dioxide-catalysed cyclisation in the liquid phase of 6-amino caproic acid nitrile to caprolactamInfo
- Publication number
- HUP9801131A2 HUP9801131A2 HU9801131A HUP9801131A HUP9801131A2 HU P9801131 A2 HUP9801131 A2 HU P9801131A2 HU 9801131 A HU9801131 A HU 9801131A HU P9801131 A HUP9801131 A HU P9801131A HU P9801131 A2 HUP9801131 A2 HU P9801131A2
- Authority
- HU
- Hungary
- Prior art keywords
- titanium dioxide
- liquid phase
- caprolactam
- caproic acid
- acid nitrile
- Prior art date
Links
- -1 6-amino caproic acid nitrile Chemical class 0.000 title abstract 3
- 239000007791 liquid phase Substances 0.000 title abstract 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 title 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title 1
- 229960002684 aminocaproic acid Drugs 0.000 title 1
- 229910052719 titanium Inorganic materials 0.000 title 1
- 239000010936 titanium Substances 0.000 title 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 5
- 239000004408 titanium dioxide Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Polyamides (AREA)
- Hydrogenated Pyridines (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A találmány tárgya eljárás ciklikűs laktámők előállítására aminő-karbőnsav-nitrilek vízzel végzett reagáltatása útján, ahőlfőlyadékfázisban, titán-diőxid alapú heterőgén katalizátőrőkjelenlétében dőlgőznak, és a katalizátőr az összes titán-diőxid-tartalőmra számítőtt 0,1-95 tömeg% rűtilt és 99,5-5 tömeg% anatázttartalmaz. ŕThe subject of the invention is a process for the production of cyclic lactam supports by reacting amino carboxylic acid nitriles with water, from which they are precipitated in the liquid phase, in the presence of titanium dioxide-based heterogeneous catalyst supports, and the catalyst support is 0.1-95% by weight of the total titanium dioxide content and 99.5 Contains 5% anatase by weight. ŕ
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19517821A DE19517821A1 (en) | 1995-05-18 | 1995-05-18 | Process for the production of caprolactam |
| PCT/EP1996/001891 WO1996036600A1 (en) | 1995-05-18 | 1996-05-07 | Titanium dioxide-catalysed cyclisation in the liquid phase of 6-amino caproic acid nitrile to caprolactam |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| HUP9801131A2 true HUP9801131A2 (en) | 1998-08-28 |
| HUP9801131A3 HUP9801131A3 (en) | 1999-05-28 |
| HU220356B HU220356B (en) | 2001-12-28 |
Family
ID=7761968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU9801131A HU220356B (en) | 1995-05-18 | 1996-05-07 | Titanium dioxide-catalysed cyclisation in the liquid phase of 6-amino-caproic acid nitrile to caprolactam |
Country Status (20)
| Country | Link |
|---|---|
| EP (1) | EP0815077A1 (en) |
| JP (1) | JPH11505230A (en) |
| KR (1) | KR19990014859A (en) |
| CN (1) | CN1075810C (en) |
| AU (1) | AU700098B2 (en) |
| BG (1) | BG102027A (en) |
| BR (1) | BR9608470A (en) |
| CA (1) | CA2218132A1 (en) |
| CZ (1) | CZ289460B6 (en) |
| DE (1) | DE19517821A1 (en) |
| EA (1) | EA199700402A1 (en) |
| HU (1) | HU220356B (en) |
| MX (1) | MX9708676A (en) |
| NO (1) | NO307964B1 (en) |
| NZ (1) | NZ308485A (en) |
| PL (1) | PL323389A1 (en) |
| SK (1) | SK154897A3 (en) |
| TR (1) | TR199701385T1 (en) |
| TW (1) | TW340840B (en) |
| WO (1) | WO1996036600A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19738463C2 (en) * | 1997-09-03 | 1999-09-23 | Basf Ag | Process for the production of caprolactam |
| DE19738464A1 (en) * | 1997-09-03 | 1999-03-04 | Basf Ag | Use of moldings as a catalyst for the production of caprolactam |
| CN101890370B (en) * | 2010-08-05 | 2012-05-30 | 上海交通大学 | Nano-titanium dioxide and polyphosphazene based composite optical catalyst and preparation method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2029540A (en) * | 1935-10-01 | 1936-02-04 | Porteous William | Trailer |
| US2301964A (en) * | 1941-09-12 | 1942-11-17 | Du Pont | Method of preparing lactams |
| JPS4821958B1 (en) * | 1969-01-28 | 1973-07-02 | ||
| US4628085A (en) * | 1985-09-03 | 1986-12-09 | Allied Corporation | Use of silica catalyst for selective production of lactams |
| US4625023A (en) * | 1985-09-03 | 1986-11-25 | Allied Corporation | Selective conversion of aliphatic and aromatic aminonitriles and/or dinitriles into lactams |
| JP2969779B2 (en) * | 1990-05-01 | 1999-11-02 | 株式会社明電舎 | Shading image processing device |
| DE4339648A1 (en) * | 1993-11-20 | 1995-05-24 | Basf Ag | Process for the production of caprolactam |
-
1995
- 1995-05-18 DE DE19517821A patent/DE19517821A1/en not_active Withdrawn
-
1996
- 1996-05-02 TW TW085105277A patent/TW340840B/en active
- 1996-05-07 PL PL96323389A patent/PL323389A1/en unknown
- 1996-05-07 TR TR97/01385T patent/TR199701385T1/en unknown
- 1996-05-07 EP EP96919687A patent/EP0815077A1/en not_active Withdrawn
- 1996-05-07 CA CA002218132A patent/CA2218132A1/en not_active Abandoned
- 1996-05-07 JP JP8534516A patent/JPH11505230A/en active Pending
- 1996-05-07 HU HU9801131A patent/HU220356B/en not_active IP Right Cessation
- 1996-05-07 NZ NZ308485A patent/NZ308485A/en unknown
- 1996-05-07 AU AU58147/96A patent/AU700098B2/en not_active Ceased
- 1996-05-07 CZ CZ19973578A patent/CZ289460B6/en not_active IP Right Cessation
- 1996-05-07 EA EA199700402A patent/EA199700402A1/en unknown
- 1996-05-07 WO PCT/EP1996/001891 patent/WO1996036600A1/en not_active Application Discontinuation
- 1996-05-07 KR KR1019970708204A patent/KR19990014859A/en not_active Application Discontinuation
- 1996-05-07 CN CN96194001A patent/CN1075810C/en not_active Expired - Fee Related
- 1996-05-07 SK SK1548-97A patent/SK154897A3/en unknown
- 1996-05-07 MX MX9708676A patent/MX9708676A/en unknown
- 1996-05-07 BR BR9608470A patent/BR9608470A/en unknown
-
1997
- 1997-11-06 BG BG102027A patent/BG102027A/en unknown
- 1997-11-17 NO NO975268A patent/NO307964B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU5814796A (en) | 1996-11-29 |
| CN1075810C (en) | 2001-12-05 |
| CZ357897A3 (en) | 1998-04-15 |
| KR19990014859A (en) | 1999-02-25 |
| DE19517821A1 (en) | 1996-11-21 |
| MX9708676A (en) | 1998-02-28 |
| BR9608470A (en) | 1998-12-29 |
| EP0815077A1 (en) | 1998-01-07 |
| WO1996036600A1 (en) | 1996-11-21 |
| PL323389A1 (en) | 1998-03-30 |
| NZ308485A (en) | 2000-01-28 |
| CA2218132A1 (en) | 1996-11-21 |
| CN1184467A (en) | 1998-06-10 |
| TW340840B (en) | 1998-09-21 |
| TR199701385T1 (en) | 1998-04-21 |
| AU700098B2 (en) | 1998-12-24 |
| JPH11505230A (en) | 1999-05-18 |
| CZ289460B6 (en) | 2002-01-16 |
| NO975268D0 (en) | 1997-11-17 |
| BG102027A (en) | 1998-08-31 |
| HUP9801131A3 (en) | 1999-05-28 |
| HU220356B (en) | 2001-12-28 |
| NO307964B1 (en) | 2000-06-26 |
| NO975268L (en) | 1997-11-17 |
| EA199700402A1 (en) | 1999-06-24 |
| SK154897A3 (en) | 1998-07-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HMM4 | Cancellation of final prot. due to non-payment of fee |