HUP0004619A2 - Eljárás formilfoszfonsav előállítására - Google Patents

Eljárás formilfoszfonsav előállítására

Info

Publication number
HUP0004619A2
HUP0004619A2 HU0004619A HUP0004619A HUP0004619A2 HU P0004619 A2 HUP0004619 A2 HU P0004619A2 HU 0004619 A HU0004619 A HU 0004619A HU P0004619 A HUP0004619 A HU P0004619A HU P0004619 A2 HUP0004619 A2 HU P0004619A2
Authority
HU
Hungary
Prior art keywords
acid
formylphosphonic acid
consumed
formylphosphonic
reaction
Prior art date
Application number
HU0004619A
Other languages
English (en)
Inventor
Thaddeus S. Franczyk
Original Assignee
Monsanto Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Company filed Critical Monsanto Company
Publication of HUP0004619A2 publication Critical patent/HUP0004619A2/hu
Publication of HUP0004619A3 publication Critical patent/HUP0004619A3/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3886—Acids containing the structure -C(=X)-P(=X)(XH)2 or NC-P(=X)(XH)2, (X = O, S, Se)
    • C07F9/3891—Acids containing the structure -C(=X)-P(=X)(XH)2, (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3817—Acids containing the structure (RX)2P(=X)-alk-N...P (X = O, S, Se)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A találmány tárgya eljárás formilfoszfonsav vagy annak származékaielőállítására, oly módon, hogy egy aminometilfoszfonsav szubsztrátot,egy víz, alkohol, fenolvegyület és ezek elegyei közül választottreagenst és egy oxidáló gázt katalizátor jelenlétében érintkeztetveformilfoszfonsavat vagy annak származékát tartalmazó reakcióelegyetállítanak elő, és az érintkeztetést olyan körülmények között hajtjákvégre, hogy a reakciótermékben keletkezett formilfoszfonsav vagy annakszármazéka legfeljebb 50%-a fogy el a reagenssel történő reakcióban,ahol az aminometilfoszfonsav szubsztrátnak legalább körülbelül 25%-aelfogy. Ó
HU0004619A 1997-05-05 1998-05-04 Method for preparing formylphosphonic acid HUP0004619A3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4582597P 1997-05-05 1997-05-05
US09/071,265 US6054608A (en) 1997-05-05 1998-05-01 Method for preparing formylphosphonic acid
PCT/US1998/008814 WO1998050391A1 (en) 1997-05-05 1998-05-04 Method for preparing formylphosphonic acid

Publications (2)

Publication Number Publication Date
HUP0004619A2 true HUP0004619A2 (hu) 2001-06-28
HUP0004619A3 HUP0004619A3 (en) 2003-02-28

Family

ID=26723245

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0004619A HUP0004619A3 (en) 1997-05-05 1998-05-04 Method for preparing formylphosphonic acid

Country Status (13)

Country Link
US (6) US6054608A (hu)
EP (1) EP0986566A1 (hu)
KR (1) KR20010012122A (hu)
CN (1) CN1255137A (hu)
AU (1) AU747331B2 (hu)
BR (1) BR9809222A (hu)
CA (1) CA2287248A1 (hu)
HU (1) HUP0004619A3 (hu)
ID (1) ID22832A (hu)
IL (1) IL132729A0 (hu)
NO (1) NO995388D0 (hu)
NZ (1) NZ500178A (hu)
WO (1) WO1998050391A1 (hu)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6054608A (en) * 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
WO2000009519A1 (en) * 1998-08-12 2000-02-24 Monsanto Company Preparation of formylphosphonic acid from (phosphonomethyl)amine n-oxides
US6274760B1 (en) * 2000-03-14 2001-08-14 Monsanto Co. Preparation of formylphosphonic acid from tertiary aminomethylphosphonic acid N-oxides
US6441223B1 (en) 2000-11-30 2002-08-27 Monsanto Technology Llc Method of making phosphorus-containing compounds and products thereof
AU2004220645C1 (en) * 2003-03-10 2010-11-18 Mudalla Technology, Inc. Dynamic configuration of a gaming system
CN103930135A (zh) 2011-08-31 2014-07-16 马林克罗特有限公司 使用h-膦酸酯的纳米颗粒peg修饰
CN102786547B (zh) * 2012-08-29 2015-05-20 常州储能材料与器件研究院 一种合成增甘膦的方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3784590A (en) * 1969-01-02 1974-01-08 Merck & Co Inc Hydroxy and imino containing phosphonic acid diesters
US3738937A (en) * 1970-05-08 1973-06-12 Textilana Corp Polyalkylene polyamino polykis methylene phosphonic acids and salts thereof and methods for producing same
US3969398A (en) * 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine
US3907652A (en) * 1974-10-30 1975-09-23 Monsanto Co Electrooxidation of phosphonomethyl amines
US4072706A (en) * 1976-01-02 1978-02-07 Monsanto Company Oxidation of phosphonomethylamines
US4264776A (en) * 1976-01-02 1981-04-28 Monsanto Company Production of secondary amines
DE3039998A1 (de) * 1980-10-23 1982-06-03 Bayer Ag, 5090 Leverkusen Phosphonoformaldehyd, ein verfahren zu seiner herstellung und seine verwendung als zwischenprodukt fuer die herstellung von arzneimittel
US4439474A (en) * 1981-10-30 1984-03-27 The Procter & Gamble Company Disposable floor mat with improved wet soil absorptivity
US4439373A (en) * 1982-12-27 1984-03-27 Stauffer Chemical Company Process for preparing phosphonomethylated amino acids
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US4568432A (en) * 1984-12-28 1986-02-04 Monsanto Company Process for preparing glyphosate and glyphosate derivatives
US4650613A (en) * 1984-12-28 1987-03-17 Monsanto Company Process for preparing N-phosphonomethylglycine and derivatives
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
IE883838L (en) * 1988-12-22 1990-06-22 Barclay Intellectual Propertie N-phosphonomethylglycine
EP0402887B2 (en) * 1989-06-15 2000-10-04 FINCHIMICA S.p.A. A method for the preparation of N-phosphonomethyl glycine
US5312972A (en) * 1992-10-29 1994-05-17 Hampshire Chemical Corp. Conversion of hydroxymethyl-iminodiacetic acid to phosphonomethyl-iminodiacetic acid
US6054608A (en) * 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine

Also Published As

Publication number Publication date
NO995388L (no) 1999-11-04
CA2287248A1 (en) 1998-11-12
ID22832A (id) 1999-12-09
WO1998050391A1 (en) 1998-11-12
US20010031889A1 (en) 2001-10-18
CN1255137A (zh) 2000-05-31
US20040225147A1 (en) 2004-11-11
IL132729A0 (en) 2001-03-19
AU747331B2 (en) 2002-05-16
KR20010012122A (ko) 2001-02-15
AU7273498A (en) 1998-11-27
EP0986566A1 (en) 2000-03-22
BR9809222A (pt) 2000-07-04
US7091376B2 (en) 2006-08-15
HUP0004619A3 (en) 2003-02-28
US6218570B1 (en) 2001-04-17
NO995388D0 (no) 1999-11-04
US20060211881A1 (en) 2006-09-21
US7294733B2 (en) 2007-11-13
US6762317B2 (en) 2004-07-13
NZ500178A (en) 2001-10-26
US6054608A (en) 2000-04-25
US20030114706A1 (en) 2003-06-19

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