HUE031838T2 - Jódszulfuron-metil-nátriumsó kémiai stabilizálása hidroxisztearátok alkalmazásával - Google Patents
Jódszulfuron-metil-nátriumsó kémiai stabilizálása hidroxisztearátok alkalmazásával Download PDFInfo
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- HUE031838T2 HUE031838T2 HUE13724578A HUE13724578A HUE031838T2 HU E031838 T2 HUE031838 T2 HU E031838T2 HU E13724578 A HUE13724578 A HU E13724578A HU E13724578 A HUE13724578 A HU E13724578A HU E031838 T2 HUE031838 T2 HU E031838T2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
I Ικ· pjestíoí itvvemion relues ίο nevel o»! dispersion hunu'Utons 0d> tommîaltons'i of iodnsulfuron-methyl sodium salt '«hieb comprise hydroxyshwdbs. lit partie«iaî lithium fo ^Mstsuan O >s* f on «a sis, Oui * N » teth>. «.<»1 au m? > u<k'>‘ * es thr group of suHbnamfcl# fNMite
Active ingredients h» os op protection arc generally net used i» their pure hunt Depeudma ou the field of application «eul the type of application. mrd also on physical, chemical an$ Äl&i!^ in|pÉfetH ismmá ip a nbx?ere with customary anAlflaftelllti additives as active ingredkmt fbrnuthtlion, The ecnnbimUtorts with other active ingredients for extending the spectrum ofÄbp and/or'tor protecting crop plants fy# by-suffer va*« idoles) are also known.
Formulations of active ingredients for crop prntevii-.m should getwteih have high ciknsic-tl and tew steal suduftp. v - -u applvatsao .md u rs Fa. at au". and a broad Ovdogsoal etlem «oh high selectivity. i ic>Oa,.ida! setoe sncicdu'nî^ hens ttn. group O'suhstnueodes, at h ms sofOmi ktw»s. genetelK have a high degree öfehebMeal t&pd d^psdatkx veyjg.·m» result oiv hydrolysis.
One optton ot ionnuütmg chuukalh labile active mgtedienis is t|*c?pnteíi^t # sdld formulations. Thus, foruutiations of active ingredients front the gtoup of suHonylureas are knoun m the form of po« Jet A &-mules and tablets (¾¾. tifffi A 764404yW0 Λ 1908/44412, Wtt \ tool i <o>8) I ho processes fa ptotlnenrg solid tofoudations, eg tn the form Ο grannies and tablets, however, arc generally laborious, psrticuiatdy of low-melt irtg activé ingredients or auxiliaries and additives are incorporated. Moreover, solid formulations are generally momdtlUcutt to %ppl> ansi less irsor-lfiertdly, t N t .Ό0'1 sga'S" disci,"cs far example. hpuid ’VimoiaiS'us eompnsinu active hedueidsi OSSPd.ien.is horn îh® group of the ALh inhibitors {noetol&etaie synthetase luhihitors).
Inpttsd:husttU: * d o* s K n tuns v> ^ v\so 10 aop v. (,κ eset pck \ and tnureover genmafh evbthif Feder OOogtad dVkaos
Ltrptsd hmwnlauans.o» stt| vtnvfnrcas tsre >Κ*ι>Νμ eg 0991 ’ Atl * v . { u t s B 467)817, P.P A 24505«, WO A 2001/8769.0 f.P A 00107, PP Λ 0514768. FF A 163598 nsd P \0 V) l U ON» C 04> UAv< Has »lîv ohx « Ny Os hw WO \ 0 H sn or Ef-A 0 514 015. WO \ Joon O'UOC -\iOih'" ο*» '»UN|kONk".s soravUastes xosspHtss»»,» coe o» nnne vtsw herbicidai Ingredients feni Ihe grotsg nf íhe ssilphohanddes, ?»· suspended torm: s me or mosd OÏÎOOO! \ ÍÍMO or ü'OH organ ut solvents ttroJ »axe os snore sujphoes« emotes ;V< »top ptoteoStoîs conspusitsons.
The objet® ól providing « iaspeemb ere»p profeiipn sontfÄiksi: widi îte chemically very reactive ssjHhnyUweas which has high chemical ^stability as well as high biidogfca! c&ciivimcss a ad crop phust tolerability was dx-sendcd by the patent application WO Λ 2004/054364, hi adxhîsoss. She osx? ;»f snltosuex ro>ne.» ns ausihxsry ^ descîthed so Wo Λ OKR'OS4po4 Siiiidspspihafes are la :&-i««ta«:asKl inmost oil dispersion fonnuftxtions oS sulihaylurcss .•md effect the cbennvol shdnhvaOou oi she stdSonxkiKOs. finge Étlplfe used dinctyteulíliSüceistate sodium sah h«^- $$ p4i (risk of sefeus.damage lo r>esi atxmsWingdn FU (díidclis>e67/S4Sí®EC; oh:IP6WM/IP» Pi4hajyPmró xwer-dnx'ndi) .Ütemem x - tern. heen conclu lor she chemical stabdfetion of ssdfonyloreas.
Additionally, the od xOspsrfeov asv gessensity îh ich eased wish slice! ssüe-nes Os order So prevent phase separations und settling of solid particles. The components hitherto used an m frequently tor this are She Beta no erodes Os Hesse Uit end Beatmt fess Pont 1 k»' xntss x ' < » b »cd on montmorsltomtc However, these very frequently intve a tendency toward '««controlled, comudruh e 'hf 'Oronge, wtuch ».in make n xbfIVnh So eo.pSs she trade ρηΛ »
Mxmmtn 0>e use 4'hvihvmsix.ujfea ts du<AetSs»N is hromn m ax tiro hsbra mh ftsdnnsv \ usx I \fcuï ros ' agiosh h»*íiuia.Ufcun>»-*i»vvvvtót.x »»Mb t * \ wt> otvHfeedl. it has wiw tensTonttd hs wK' ssssx huhow s xo? six's m *h hern.» » f1 >Oks, qtnd bmnnbvu ϋ\ x'i sodi'pxshsioM xtxetf x 1 senjunn salt sax h\ as mx stearate ''«sjntssm tx xt!m imam ,àvnt. s;» XV di as sho thvkwrom. a einaniud siabsifeitors of she sufenvlurom :iin:p«rfKadssn."tti«lsihK«η h\ onx n< he feuinstd ou roui rs ngnt οirix sa'n t t\\s χχη dw s.Mntm sxsh ct'a'dossditsr"' /five _- Îotmîi i ίϊ >s ΐ.ΐ ; isseit s^sISsstmi^i'sïï- oil disperáiint comprising: * «s active iisgresiiefit kxksvssifvisoti-issethyl swihusn -sail. * »«« or ®w.' hp^rosvstccratesv selected frmi the group coniÉithg kt' socHim« liydrci^pîcamiCô calciun· hydroxystearate or ehts;· htdroxysaeofiite end * al le art one sinnisifier and * ik \ f < V phrd si \ ostt oiot t h ol » <** *<9 ' sOneiai aui * yjstjonally inrshes àuxifi&îfe &«iMíthbm
Psvivosbiy, ihe invention relaies So ibmstiiaiistna in ih« fórra of an oil dispersion comprising «· 0.0i (o sü% by weight, pretmibiy 0 1 so 5% in weighs, based on she weigh* of the fonnsikîïon,. cd'k>dr>aii!!\ifa>svitssthyl sodium sab., and * 0 0 to b . bs wesHd, weiiSSnb n d tu v'0 \ nr ad, banni > tin weight d dm Unamkibon, ad' one os ira sre hyds'oxyssvasíites. and » ÍU ίο Y in ne Jd f vts b'H Ό "η"« "s we phi, Ps sd say ke wtu i* <·. ihe jo o»uhn>on. of wm os äss>ee SLStiidssfüLi- ásni » 50 to 9*1®·« by weight, prderstbiy 55 to 955¾ by neighs, bares! 00 lise weighs of the a>; ntsi!»0' ta:, of one or snore plans or asme nb mis or evict s of one 0$ name phm? <>r misseral ods ansi * optionally festi ter auxiliaries attd additives.
Here., the b ar norm In weight ist ‘w by weight refer, its she evests of the psesemm of nvn os snore ibydrsasiyatOisrases, sísssssiaiflera str sdls s>r ecte Sbesttof to she iotmisiatio« aceostlbsg do thb; sumde stob^v t, ο V oss 0: * *t. hvtl't'Maît'.snnv^oosssK isvr-rros O'e-îsî · hemol
The idiom lasst >ns at. cooling fst she invent ism are fmhydpp*;l>& ##f k lests t%p r'··« by weighs, based on ire weighs of she ionsssslaihad, 1 he sown da n also mkte- to a intess fos ide p*e»vn«ït«oft ot she umnor dams .tew a Tog. its site tisventioo. in nhioh she sosisom sáli of iaifoadlhroti-sstéibyf is Älft Ägoihör "Wt8h iíhfr vdiubober iss tbc plant $1¾ U Ûn «st#, ifi fkW W miriinsl mf bpd .fteis hydroxvatáarase aíid optiosiaily further asigiliaries cndscádiiivoS: amsssMesl
The lövotiiioo álist rsiatcs ist iá proseas for she prepsiábbst of she fórmdbdíoris áccb;rÉb| bt::tÍCa 1*0 cotton. ids : wTkif: Ihe sodinm rais ipf: N fÎPk Ιβί Pgeiher with: the tin© itydrpxysfeisrtue mui optioitsdly forth»? aoxiUârié# séÉ:¾Äivi^:1i^M:pÄ^ minors 1 oil m «s ihn ester ci « pfosp or mînx-rai od. lise jsjyeïiîioîî ahn relaies to the use of the ilsrmidismms according to the invention for eeótollisíg weeds, !%ffe.itihfy, for ihlsif impose, the foonubuons according to tit« invention are diksted vx on OiitvW dent piv.mcmg a crop pr-nMtoo u'mpochi.u witsch can then ho tisxd tox controlting smdexired pinnt growth.
The fovesnixm ,fexo reotex to a o set mm to* wumodnig midexteed plant syxwxtb, sn oho ft the formnbiirm according to the inventmn ox the crop protection compoxibon according to the imenfeon is* applied to the harm ltd plant-, toecnish pian* parts, piattl seeds ot fite ásott on which the planta grove. iVfmafek, the ibitttnbtioaa according to tin* situation eomptixc hxfenmfeuienmxmhu xodann sail an the söffe active ingredient. However, It is likewise possible to use, in addition to Tdo^olfenen-methsl soft ants, salt, otx os more feni I ici agtoxheouoni asttso mgrethestxx amint x.dnnmx as the fee suti latiéit aceardntgte the at cents' <n.
Suitable feather agtoehemfeaf active fitf?odlo«ts are in particular iM-DTTetbylhexyl ester, aiiii.huniftnvns xodhnn -up. difeufestkun, flfoertaovt. femoxaprop fuibw, ibrannmlfenon sodium sah, tstda/ilhnn, bosnfhitoie, metrikusán, rnesostfe forms-methyl umdium -salt;.· propoxyvartwooe sodium salt, pyrasttlfestole, tentbolrione, d ? ï e n os rfesao ae-sstm h y L trinhanorn.·. x, sstHu vdestvsx m n pmtteuh, > >p *tnwoo, new tdm η suol mow "p\ sok foci
Prcfofapfe the formulations au: ordnt g to fete inventons cost an ine lithisaa hybroxyvehrats·. pom:nia.;':y preferably lithium ü>h>dro\>stearate. Preferably, the formulai imts tteoordmg is? täte xe s*on \,x mp» χχ> itihsnni non s' x > Ικ χ * wh u »fe a tx fonifertvd ; a s: iioitlc entaissfeers and dkpatt cams arc e.g. showy bind alcohols, alkoss latod fsttiy aoi-.k a tvs.wSated triglyrendox omets contain hydnoo tabs aeidx. poiyethx knooxsds·* pxds props kuscxs sale Ids'·, f> xonoo ox 5 '' and ,'.nvlphus»d afe-ow Tax IVeilmed ionic mmfeyiikrs/dbpersnnts are e.g. saht; of alkybrylsulhmK or phnsphnnic uciitfe Imd p <h\ ivt s p,\ ti « U1 \ S' 'r* sxtxao <'« \' »wk -xtsl o< nk a r msuu ! * wd<
Preferred pbol oils os- estera olpisrst sais tue vos hems oil. upexced oil. corn seed oil, tnndfower ail comm ccsxf oil, linseed otl, eocnitut oil, palm oil, xsilfoweroil, mMmUnl pettnnt oil, olive oil or undos oti, in parfeexihsr mpcsual oil.
The laity avid esters ane preferably esisrs ol rUK';I preferably CI2-C20 fatty acids. I'ho-t'td < 22 ynt\ nc»»l enc»N srs. £* *,sample cwix o* >inaata-mieduof'«auitsied CI0-C22 fatty «ί i-k äü rvots au o',!' î nmtUei o-tVmN'o utu η·, » μ e:nci íOî-L. burn' -uul pkenué pcid and *n particular Ci8 fatty ucisht such us smarte acid» oleic acid, findetc-seld er acid. lu ' -modo ! meboi Un V > ! pumádé h preteoed
Freierred materai oils ere suivis re s oI aromatic sad aliphatic hydrocarbons. such as solvents of the Solves«*#· series, c.g. Ssdvesso€dOO, SolvessrrfdSO otu^Äass^SÖÖ íkx.xonMohsi Chemicals), of the $olv*rex#/Soi\fary# series {TolalFmafilf) or of the Carom**# series, e g. < OiO«>axdh2.8 (Fetrochem Carless >.
Sialvesso®:®0 and; lelvesse® BP aîefstrtietdsrly pmferred:, I it, plan! oils or mtms.d otk os tmur thtteof can Nr ptx£t.m ou then own ο» to a nuxtnre. Use •sits used preferably have a low dissolving power for 1«: agrochemical active ingredient et ingbkilehis «setf suipatf ieoksrtits pitsayfsalldnamtdM:: besides t:N or, sterns m vh us y ntom <n d resets üst,, o Aeneis *\d tluv>tt>»,iu. agents, sycklshk hgcsttS; antixkh; agents!, adhesives, genet ration agents, preservatives and frost i pmtenisn agents, amtoxtdanK, solubility promoters, Odem, carrier? and dyes, anti foams«: ,,s «ätiotx er u< ,roots Λ h t, -, , s oCt ,tsragent*' I" .'!\u e ' n >\ tttd she xsm,\ m?\ us rsd,'f!ui auxdi,tries and eddiUvcx , , mt s s«, dm* o ,He 's, sN me ,v, kot >0 ' od*b vd xes ,n *>·,, t ‘ t su spevlrtnt: ol economkah} >ϊ*ηχΛΠ«·» mono· .and· dseotxkxh-nommanoiutl hatodul plante Dtsssctthdo-coturol perennial harmful plums χβΐ: emerge Iront rlliromefg rootstocks:and other permanent organs are a Iso easilv tackled by the loonulation.s. I t5e psescnl im codon ihosviotc aUt provides a method bn control.ing undeamm pi mo, os t'os fceniatmg dsemvswth of-plants. preferahh in crop ooiittKm m winch u fotmntetion ,,e< otdotg $0 täte sstvfhtiort i.(r & crop protection cosnposhion prepared therefrom (p«K*Stbly application^ mixtures such os e,u. spray îttMifçs) d-to-Hte.;pbfd* (e.g. harmW päastts such ss tstosto- >'f dxvkledostous rveeds >os undevnvd crop plasds), the sees! nsaterial se g graitts, seeds or vegetative replication s>rgtttts such as others or sposattstp parts svitb buds) or the area ott which the plants grow te.g/lho cnUrvaisiiarcay In tftis eotfttcétSôik the fortttttlnhons according to d , mwntso' o', tli' 0','jf ptouetmu usaposUioos psop.eod ttutohojn e,nt be applied x e prior sowing (optionally also by ineorporation into Sie Mii), ptxoesstergeitat or poxt-cmetsenue \ need und tv, -nme representative* ot the or«».' md do ot\h'd<mmm íVm which canhe controtted by: the fommieboos aseorttoi to Ihe Jo«otbo or & crop protection composhasrs ptvpareb iherehoio m&v he soetitiosted by way oi wangsle, although the naming is not mtentied to cotntm.te a rcetrietiop to certain apectew
Aegilopx. Agmpyrmg Agrostis, Aiapscurus, Apera. Awna. Bradnaris, dromns, Cenehrus. Cosnmeltna, Cyoodoo, Cyprtgh Pact)iostcmum, HidOn«g Fehnmchloa, i kmeham. Í lumme, hfprostw. fcriovhioa, Fesuam, t'nuhrisïshs, He 'tan·}», m, hope! eg, 1 ><.ho, naan, ' eo’oehi \tt I <<hunu htonoehosia, h.innnw a1 Ispahan Hrshov bhioutn, Kna,, kottlmeln » Ssigtn erg keiiges Set.»?' t, Sniphum I hcotykJötunnt weeds., .of the..gejm or Abutnom Atnatanihuv Ambrosias Λη<8%· Ardhemis, Aphanes. Arteimsla. Aitiple.s hdhv, Kalens, (.'apadta, Carduus, Cstashg C'eotîHârèa, * hoooi \a' y '-s.! V « \ dv -- H , Ncsrw Λι ms ho I \ »»urn Euphorbia, d.denpam, Guknsoç.», Galtum, fbhtAue. Cvmova, Ka-chin. Ltnnium, Lepidsnm, Chlfebk, Manua-n. Mentha, YKrcuoahs Mtdmgo M>osotts, Capas u, fhesstntts, FNsstowy IMlygomtm. iMrtuíítea. Kanmudus, Kaphaaoy Roílppíg IKhsksb Rttnm% SkRoha, Seneeîo» Sesbitma* Sida, Υί»'ρ<\ S< annni, Vau ' N'hs \v0 5 htdiusa, iatasauom 5Mvs*pt, tntolmm, I riu\v Vet union, Viola. Xattthmm.
When the compounds according Ét the itsysmtlots aie applied to the soil sorfee betöre germination, etthet the weed seedlings are prevented completely item emerging or the weeds grow estid they have reached the eotyledust stage. N« then atop growing and excimtathg after three to lour week\ have eiup^hlU^’PbtK^Édéllh o' the ionnidatloiw ot the crop protection compositions proposed thetetVoto are applied post · eroergestcc to the «seen party of the planes, growth -stops idler the treatment« and the harmful plants remose at the gtowth stage at the urne ol application, os that dte sOmpteteh altes a oessrnn sane, -<< that ό do--. mannet compelstmn hv the xuoh which is haonltd to the stop plants. is dmsimded very early and itt a iswting marmes'.
Mortxsver. the toînitshloot» aeco d.ag o' tbs asveMi.w « a coe» Ο'Ύ vO···», .esapositioa prepared ihereimtn have t depend lag on the applied sort rate applied) e scellent growthregulating pt'operlieá as ert-p phtttts. 'ihvy intervene 1st the plants' own metabolism with regol.o<'!> eüY' t, ,ostl rast thm be a»'\i tbs- o.e targeted otlloendae oi phart ntgredtents foal to fheUuaifc harvratjtsg, ssosh o:; e.g b) triggering dtsuxatiott and stootesl growth. Fyriherniore. they are also suitable r<w the gspgi# and »«ίο»««'? «NMitfod vegetative growth >x tthout hthmg the plants trt pr pouces Au inhibition of the vegpîrnve enmdx phns a tootur sole for rnnny mono- üiti! rlieotyledonons plants stnee* tor exempte, tins can reduce ot oortipletGy prevent íe*dgirsg.
On «vcotmt of thosî Ir eo m,d atd phmî-gioo.h-rege Soto*' ptopeox-p the lotnndtmoe re I r " \ot> oson 00î> vn> n Xvp! re* 0 cî > on <iho V üx I 'V so t» >>hov'* 'Ni * p mxx ! Xps i t jMR'tk i X tJRXÎÎ sd I«i< s o > IP s ' t « e 1 \ > XsOSU P Pi» ee ^ s , '0 g fRt î!il\y ' i s \R * U v\ ft V pOÎk 4 O VOS iO spm> X's > s s !tm>*· byresosktnees ?ô certain pesticides; in particular eerhon hertùddes* »Ätn» ör ptioptis of plant blsMMrt msei *1# sirtpn Ifrstreii or hiiosoorpnisms Ideh py |dd|l, hucterh or Gruses. Other particular properties relate e.e. ii> ilte frarv exited materialwith regartf ί, omm dx xbh dore dőlte u nspMf oi reti gR >x ^ < dm s. > s Io> ex 'uh ono'-pcoo pkmo y\ith an inueusxR »hoch .onunt oí nllem.l M?uh cpMlitx, ot t-hom·. anh 0 different inky seid composition ot the harvested rostered tue kmmn \ ä* ge o\ metsgre (, V i ν'- ere A rerere " rex vu u da . \e ot +hc. o-otxx ud - reçu rents te Px- »ovudhm itt eco' -ms re ai fr tnpmUnt o.tesgemo soltntos ot useful plants sod orootnephttsik o g. ofem-ab such as slrent, barky, r>«> cats, milkt, tine mtimorn, or else crops of sopt MM., cotíore sox bean râpeux*h pouuo, tomato. peas and other sxtreçyof vsgetítbfrx
Preiers&lÿy tho eoioponnds ac«o#htg to thp lovontion oso hg used m hsrhtesdes ht crops-of io,end p;sm\ xhnh on* 'esis.nnt, ot hx\o ooen nr«fo oxsAsnt h> eenx'tn engnieotsog to the phytotoxie effects of the herbicides. the examples hsted Ixdoxv stnhlea !-*» short the ehetnivol smhiisssooo of the s>sdiom soit ol x>doseiiormottteihyI by lithhmt bydo-xx sieorete,
FreMttptloa fcMMtdM;
The sodium salt of iedostdl'oritnottelhyl (xtxiostdieronooethybsxxdixee·f IMx) i^ finely disttersed by tneo»-. ot a naor-suiur ttooex togelhxr Vkkh xt eostomary emolsilter snch as EmMllogOti EL dÖÖi? fimxitf xfl polygiyeol ether born Ctariam AG) in the solvents enxtomary for CD ibrotuhttioos tell dixpersttxtt lormitlittiests), such ax ntfteseed oil methyl ester or Solvesao 200 bi.l>T> farotoatlcs tnsxlttre from Esxm AG). Further immolation auxiliaries stich m the fhlekermr Betttotxe tS# (sheet silicate from frlemeotix AG) or the polymers Ltgaluh PIG 40# Mt hto {polyethylerie g|yc»rl t^toxtoolesfe front Peter Greven GmbRx Ugalnb I ? Gf>· fglveeryl >:.lk>k-ate front Peler Greven GmbH) or Ugalufr G KOT" teoorplex ester from feux <'irsv<;o GmbH) sast, sates «lia» also he asibest M this spthhv Jturt&ewnaisfc 58¾¾¾¾¾ hydrcxysteamit; (inttnau *>«p of a Ssma. ^áW^ai^v^íi«^ .*# côtofsaftgçsa p«rppp8:^i libtes ! tb !) stew Ib^ eehipösfilöfi oftbe tótblOÖ SSift (% ùî % by weight). 1 îî« J·.'prad.su-<o ci s Pc SMS äs acicnicarb here la äneasri os Í USA'. \ hi. oAgsvCaocsi is i.\pîCssoù îk »< va sahk'* I î>î s> m - \\<N* i his meam that after tbc retevasn perso*! sX'Ïô of ils« ongtttnfly pt'eseni hV!S w»s aíre&dy tisgradsti. i« AÎI <nî tCc s\-.îcnâs b sä ce. i',. JegnsGst s* es et she Mxhsms Mth <sf ioíkiaokusvís h'thoGäsg áMs-a^e at vdicHäs ^'5^ k sspec-jau.> atä<i Ms \<osou\ stcjcgc km es Pme rums? ccm äh tethkxG .am a restsli of the asMâion »l'Mthiyo, bydmtsv stearate.
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Claims (5)
- I Kessk'^euyvk egy biaps tbszjxrfzsó fonníoah&o, aw«·lyak4 * pÿîiy 5î iî*'â hatôany&gküd: jMsrtâ ! IWon - tatis 1 -aâtnumsô, « k*}cmi»‘hWr^Äi^i va^? tête- hidroxls ;testât vükvita v>.o ^üÄ#«|pläKS»tt s?#- v«gy îi'vbfe bi&osistfearat és * legalább t0mu%U&t: és ö legalább egy növény·· ya|ÿ àsvànvoi&i vagy egy növény- vagy ásványolaj egy észtere év « ado» eset^«tbv$|tój^^#:itílaléteoyag«H.
- 2. As í , ígéoypom szemű készítmények egy οΐφ* diszperzió tbm>ájáhne, smdy a köyatkgdd Sasiak :nw/ak: - tus ! 1 ö tomag* ' χ\Κ iisk ! ou-m, 5(¾ raru.r - 0 - 0,01 lblomeg%eg> tagi· több bid másam antt összesen és ·' 0. í - 20 töíSíeg% így sagy b:sbb emdgátm összesen és o 50 - '/9 tom*g% egy vagy több növény · vagy ásványolaj vagy egy növény- vagy asvá»yala| egy Páteré M$M>· :S8i5 iís - usioit esőiben további -'eved- év adalékanyagok.
- 3, id járásáé 1 vág·» 2 igenypom szeri«« készfönénu-k döárdtásánr, amelynek során jikissni&imvmeoi-«átriumséi és u etnuigátort a növöay« v&gy ásványéiban vagy egy növény' ysgy ágyápoMj észisrébap db^serál.hsk és \??t kövemen a hidrox*xie«FáiQt év adott esetben a további segéd· adjak.
- 4, Kijárás·.«*:'!* vagy ^b'i'^y^tSZöisi^^sftetÉtpk'éMblisára, ameKnél s#}Mj0dssaliír«i5ímsÍk yátrönóséb a/ asnlgárntb a hidroxisztearátot és adott essoben a további segéd- év addiktofsipte s ap vény- vagy ásványaiban vagy r;gy noway- v*gy ásvásryolsj észterében diszperáljuk
- 5. Növéayvédössen amely az i. ígPypöabsetter kászitméoyek viszel való hígításával állíthat« étik ói Ag: i. igéoygbat ápptb Äzjonäny mgfm. % i^syppt szerinti növöm véödsesm mn kivrnmm«P vényt stöwkedés szabitíyozásars #IÍ;Áft»lma*ásra; Î. E|árás nem kívánatos növényt növekedés szabályozására.. amelynek során azil- igényem szerinti készítményt vagy sz 5. igénypont sserimi növányvidöszen hjuttatóik a káros növényekre növényt részekre. >Κί-vépirtíagyakta: vágy á#á a tpüjaöér áldd a növények ttlvekadaslti
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PT (1) | PT2854543T (hu) |
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HUE048629T2 (hu) | 2014-12-22 | 2020-08-28 | Mitsui Agriscience Int S A /N V | Folyékony szulfonil-karbamidot tartalmazó herbicid készítmények |
PT109118B (pt) * | 2016-01-26 | 2018-02-27 | Sapec Agro S A | Mistura herbicida compreendendo iodossulfurão-metilo ou os seus sais e flazassulfurão |
EP3222143A1 (en) * | 2016-03-24 | 2017-09-27 | Bayer CropScience Aktiengesellschaft | Use of certain herbicide combinations based on iodosulfuron in teff plants |
MX2018012367A (es) | 2016-06-21 | 2019-03-07 | Battelle Uk Ltd | Composiciones herbicidas liquidas que contienen sal de li y sulfonilurea. |
CN110035660B (zh) * | 2016-12-07 | 2021-10-26 | 拜耳作物科学股份公司 | 含氟酮磺草胺和茚嗪氟草胺的除草结合物 |
CN108157386A (zh) * | 2017-12-25 | 2018-06-15 | 山东理工大学 | 一种玉米无公害除草悬浮剂的制备及应用 |
US11109588B2 (en) | 2019-02-19 | 2021-09-07 | Gowan Company, L.L.C. | Stable liquid formulations and methods of using the same |
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US4683000A (en) | 1983-12-22 | 1987-07-28 | E. I. Du Pont De Nemours And Comany | Herbicidal sulfonamides |
DE3573368D1 (en) | 1984-04-27 | 1989-11-09 | Ciba Geigy Ag | Herbicidal compositions |
US4671817A (en) | 1985-04-23 | 1987-06-09 | E. I. Du Pont De Nemours And Company | Herbicidal pyrazole sulfonamides |
CA1309715C (en) | 1986-05-02 | 1992-11-03 | Barry A. Wexler | Herbicidal heterocyclic sulfonamides |
JP2569342B2 (ja) | 1987-10-22 | 1997-01-08 | 石原産業株式会社 | 除草懸濁状組成物 |
DE59207085D1 (de) | 1991-05-18 | 1996-10-17 | Hoechst Schering Agrevo Gmbh | Neue Suspoemulsionen auf Basis Fenoxapropethyl |
ES2092592T3 (es) | 1991-05-18 | 1996-12-01 | Hoechst Schering Agrevo Gmbh | Dispersiones acuosas de derivados de sulfonilurea. |
BR9207062A (pt) | 1992-01-06 | 1995-10-24 | Du Pont | Formulação em comprimido |
ES2073326T3 (es) | 1992-01-28 | 1995-08-01 | Ishihara Sangyo Kaisha | Suspension herbicida a base de aceite quimicamente estabilizada. |
US5830827A (en) | 1995-09-21 | 1998-11-03 | Ishihara Sangyo Kaisha, Ltd. | Granular herbicidal composition comprising flazasulfuron and a sulfosuccinate or benzoate stabilizer |
BRPI9807183B1 (pt) | 1997-02-05 | 2015-10-20 | Basf Ag | mistura sólida, e, processos para a preparação de formulações herbicidas |
DE19951427A1 (de) | 1999-10-26 | 2001-05-17 | Aventis Cropscience Gmbh | Nichtwässrige oder wasserarme Suspensionskonzentrate von Wirkstoffmischungen für den Pflanzenschutz |
HU226076B1 (en) * | 1999-10-26 | 2008-04-28 | Bayer Cropscience Ag | Herbicidal agents comprising phenylsulfonyl derivatives and vegetable oils |
DE10020671A1 (de) | 2000-04-27 | 2001-11-08 | Aventis Cropscience Gmbh | Flüssige Formulierungen |
DE10108472A1 (de) * | 2001-02-22 | 2002-09-05 | Aventis Cropscience Gmbh | Agrochemische Formulierungen |
WO2004036994A1 (ja) * | 2002-10-22 | 2004-05-06 | Kumiai Chemical Industry Co., Ltd. | 水和性顆粒剤よりなる農園芸用粒状組成物 |
RS20050447A (en) | 2002-12-13 | 2007-06-04 | BAYER CROPSCIENCE GmbH., | Oil suspension concentrate |
DE102004025220A1 (de) * | 2004-05-22 | 2005-12-08 | Bayer Cropscience Gmbh | Ölsuspensionskonzentrat |
DE10334301A1 (de) * | 2003-07-28 | 2005-03-03 | Bayer Cropscience Gmbh | Flüssige Formulierung |
ES2323399B2 (es) * | 2007-06-19 | 2010-02-26 | Gat Microencapsulation Ag | Suspensiones en aceites de sulfonilureas y combinaciones agroquimicas. |
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EA025265B1 (ru) | 2016-12-30 |
AU2013265337A1 (en) | 2014-12-18 |
PT2854543T (pt) | 2016-11-23 |
CL2014003189A1 (es) | 2015-08-21 |
BR112014029113A2 (pt) | 2017-06-27 |
MX2019002609A (es) | 2019-07-18 |
BR112014029113B1 (pt) | 2020-01-21 |
AU2013265337B2 (en) | 2016-09-08 |
EA201401311A1 (ru) | 2015-05-29 |
US20170339959A1 (en) | 2017-11-30 |
MX2014014351A (es) | 2015-03-03 |
DK2854543T3 (en) | 2016-12-05 |
ES2603384T3 (es) | 2017-02-27 |
UA116886C2 (uk) | 2018-05-25 |
US9763450B2 (en) | 2017-09-19 |
ZA201409430B (en) | 2017-02-22 |
EP2854543A1 (de) | 2015-04-08 |
PL2854543T3 (pl) | 2017-03-31 |
MX363109B (es) | 2019-03-08 |
HRP20161462T1 (hr) | 2016-12-16 |
US10194663B2 (en) | 2019-02-05 |
AR091147A1 (es) | 2015-01-14 |
SI2854543T1 (sl) | 2016-12-30 |
RS55366B1 (sr) | 2017-03-31 |
US20150105259A1 (en) | 2015-04-16 |
LT2854543T (lt) | 2016-11-25 |
EP2854543B1 (de) | 2016-08-24 |
WO2013174833A1 (de) | 2013-11-28 |
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