HUE030202T2 - Polyurethane foams containing lipid-based polyols - Google Patents
Polyurethane foams containing lipid-based polyols Download PDFInfo
- Publication number
- HUE030202T2 HUE030202T2 HUE10711917A HUE10711917A HUE030202T2 HU E030202 T2 HUE030202 T2 HU E030202T2 HU E10711917 A HUE10711917 A HU E10711917A HU E10711917 A HUE10711917 A HU E10711917A HU E030202 T2 HUE030202 T2 HU E030202T2
- Authority
- HU
- Hungary
- Prior art keywords
- polyol
- foam
- isocyanate
- modified
- isoeyanate
- Prior art date
Links
- 150000003077 polyols Chemical class 0.000 title claims description 485
- 229920005862 polyol Polymers 0.000 title claims description 468
- 150000002632 lipids Chemical class 0.000 title claims description 42
- 229920005830 Polyurethane Foam Polymers 0.000 title claims description 18
- 239000011496 polyurethane foam Substances 0.000 title claims description 7
- 239000006260 foam Substances 0.000 claims description 166
- 239000003054 catalyst Substances 0.000 claims description 86
- 239000000203 mixture Substances 0.000 claims description 64
- 238000000034 method Methods 0.000 claims description 62
- 239000004814 polyurethane Substances 0.000 claims description 44
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 41
- 238000006243 chemical reaction Methods 0.000 claims description 39
- 229920000642 polymer Polymers 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 19
- -1 acyl lithium Chemical compound 0.000 claims description 17
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical class CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 14
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 13
- 238000005187 foaming Methods 0.000 claims description 13
- 229920000570 polyether Polymers 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000004088 foaming agent Substances 0.000 claims description 3
- 208000000474 Poliomyelitis Diseases 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 102000053002 Lipase-like Human genes 0.000 claims 1
- 108700039553 Lipase-like Proteins 0.000 claims 1
- 240000008881 Oenanthe javanica Species 0.000 claims 1
- 244000046052 Phaseolus vulgaris Species 0.000 claims 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 description 219
- 150000002513 isocyanates Chemical class 0.000 description 212
- 239000003921 oil Substances 0.000 description 60
- 235000019198 oils Nutrition 0.000 description 60
- 238000004519 manufacturing process Methods 0.000 description 47
- 239000000463 material Substances 0.000 description 42
- 229920002635 polyurethane Polymers 0.000 description 39
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 33
- 238000009472 formulation Methods 0.000 description 27
- 230000000694 effects Effects 0.000 description 24
- 238000001879 gelation Methods 0.000 description 24
- 239000010779 crude oil Substances 0.000 description 21
- 238000012545 processing Methods 0.000 description 21
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 19
- 230000000704 physical effect Effects 0.000 description 19
- 238000007906 compression Methods 0.000 description 17
- 230000006835 compression Effects 0.000 description 17
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 17
- 229960003656 ricinoleic acid Drugs 0.000 description 17
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 17
- 230000004048 modification Effects 0.000 description 15
- 238000012986 modification Methods 0.000 description 15
- 239000000126 substance Substances 0.000 description 15
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
- 238000005755 formation reaction Methods 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 235000010469 Glycine max Nutrition 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 12
- 230000009257 reactivity Effects 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 241001133760 Acoelorraphe Species 0.000 description 10
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 230000009467 reduction Effects 0.000 description 10
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 9
- 238000006555 catalytic reaction Methods 0.000 description 9
- 239000003063 flame retardant Substances 0.000 description 9
- 241000894007 species Species 0.000 description 9
- 241000195940 Bryophyta Species 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- 235000011929 mousse Nutrition 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 235000019482 Palm oil Nutrition 0.000 description 7
- 239000001569 carbon dioxide Substances 0.000 description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 239000012975 dibutyltin dilaurate Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000002540 palm oil Substances 0.000 description 7
- 229940066675 ricinoleate Drugs 0.000 description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 6
- 239000004359 castor oil Substances 0.000 description 6
- 235000019438 castor oil Nutrition 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 6
- 238000010348 incorporation Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 6
- 235000012424 soybean oil Nutrition 0.000 description 6
- 239000003549 soybean oil Substances 0.000 description 6
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 6
- 235000015112 vegetable and seed oil Nutrition 0.000 description 6
- 239000008158 vegetable oil Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229920002176 Pluracol® Polymers 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000011135 tin Substances 0.000 description 5
- 150000003626 triacylglycerols Chemical class 0.000 description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 4
- 229920005863 Lupranol® Polymers 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 235000019484 Rapeseed oil Nutrition 0.000 description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 230000001976 improved effect Effects 0.000 description 4
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 4
- 125000002524 organometallic group Chemical group 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
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- 239000000376 reactant Substances 0.000 description 4
- 229920005896 rigid polyol Polymers 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 4
- 241001136792 Alle Species 0.000 description 3
- 240000002791 Brassica napus Species 0.000 description 3
- 229920013713 Dow VORANOL™ RA 800 Polyol Polymers 0.000 description 3
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
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- 244000068988 Glycine max Species 0.000 description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 3
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- 238000007259 addition reaction Methods 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
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- 235000004977 Brassica sinapistrum Nutrition 0.000 description 2
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Classifications
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- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/08—Processes
- C08G18/14—Manufacture of cellular products
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
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- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
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- Y10T428/249978—Voids specified as micro
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0903717A GB0903717D0 (en) | 2009-03-04 | 2009-03-04 | Flexible polyurethane foam |
| GB0905948A GB0905948D0 (en) | 2009-03-04 | 2009-04-06 | Flexible polyurethane foam |
| GB0909563A GB0909563D0 (en) | 2009-03-04 | 2009-06-03 | Flexible polyurethane foam |
| GB0910063A GB0910063D0 (en) | 2009-03-04 | 2009-06-11 | Polyurethane foam |
| GB0912558A GB0912558D0 (en) | 2009-03-04 | 2009-07-20 | Polyurethane foam |
| GB0917550A GB0917550D0 (en) | 2009-03-04 | 2009-10-07 | Polyurethane foam |
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| HUE10711917A HUE030202T2 (en) | 2009-03-04 | 2010-03-03 | Polyurethane foams containing lipid-based polyols |
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Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0705685D0 (en) * | 2007-03-24 | 2007-05-02 | Nauer Fritz Ag | Polyurethane foam |
| BRPI0902896A2 (pt) * | 2008-02-01 | 2015-06-23 | Dow Global Technologies Inc | "dispersão de poliol polimérico, espuma de poliuretano, método para formar uma dispersão depoliol polimérico, e método para produzir uma espuma de poliuretano" |
| US20100266764A1 (en) * | 2009-04-16 | 2010-10-21 | 3M Innovative Properties Company | Method and composition suitable for coating drinking water pipelines |
| MX2010005069A (es) * | 2009-05-27 | 2010-11-26 | Bayer Materialscience Ag | Procedimiento para la fabricacion de espumas blandas de poliuretano con emision reducida. |
| US20130005900A1 (en) * | 2010-03-12 | 2013-01-03 | Dow Global Technologies Llc | Gels and soft elastomers made with natural oil based polyols |
| CN110066836A (zh) | 2011-02-02 | 2019-07-30 | 柯碧恩生物技术公司 | 产自重组产油微生物的定制油 |
| EP2691486B1 (en) | 2011-03-30 | 2019-03-27 | 3M Innovative Properties Company | Composition comprising cyclic secondary amine and methods of coating drinking water pipelines |
| DE102011110016A1 (de) * | 2011-08-11 | 2013-02-14 | Evonik Goldschmidt Gmbh | Zusammensetzung enthaltend Zinn- und/oder Zink-Salze der Ricinolsäure sowie mindestens ein weiteres Zinncarboxylat und Verwendung der Zusammensetzung bei der Herstellung von Polyurethansystemen |
| DE102011110020A1 (de) * | 2011-08-11 | 2013-02-14 | Evonik Goldschmidt Gmbh | Formulierung enthaltend Zinn-und/oder Zink-Salze der Ricinolsäure,Harnstoff,Polyethylenglykol und Zuckeralkohol und Verwendung der Formulierung bei der Herstellung von Polyurethansystemen |
| US20130289150A1 (en) * | 2012-04-26 | 2013-10-31 | Bayer Materialscience Ag | Viscoelastic polyurethane foams |
| KR20140102821A (ko) * | 2013-02-15 | 2014-08-25 | 엘지전자 주식회사 | 반응성 기포개방제 조성물, 폴리올 조성물 및 개방기포형 폴리우레탄폼 |
| JP2014201603A (ja) * | 2013-04-01 | 2014-10-27 | 株式会社ブリヂストン | 電極材製造用ポリウレタンフォーム及びその製造方法 |
| CN105637036B (zh) | 2013-08-13 | 2018-10-09 | 能源实验室 2000 有限公司 | 基木质素聚氨酯产品的制造方法 |
| MY203264A (en) * | 2014-05-26 | 2024-06-20 | Univ Kebangsaan Malaysia | Method to produce natural oil-based polyurethane prepolymer |
| MX2017014405A (es) * | 2015-05-15 | 2018-07-06 | Stepan Co | Aceites vegetales etoxilados en formulaciones de espuma de atomizacion de baja densidad. |
| CN109476814B (zh) * | 2016-07-21 | 2022-05-10 | 科思创德国股份有限公司 | 高温稳定的聚异氰脲酸酯泡沫材料 |
| CN108623771B (zh) * | 2017-03-15 | 2022-10-25 | 科思创德国股份有限公司 | 羟基封端的聚氨酯预聚体及其制备方法 |
| CN115093821B (zh) * | 2017-12-25 | 2024-07-12 | 井上株式会社 | 层叠体和车辆用内饰材料的表皮材料 |
| JP7112298B2 (ja) * | 2018-09-19 | 2022-08-03 | 株式会社イノアックコーポレーション | 積層体と車両用内装材の表皮材 |
| KR102308560B1 (ko) * | 2020-07-01 | 2021-10-06 | 주식회사 케이씨씨 | 접착제용 우레탄 수지 및 그 제조방법 |
| CN111825827A (zh) * | 2020-07-22 | 2020-10-27 | 江苏君晟家居科技有限公司 | 植物油基改性异氰酸酯的合成工艺以及其应用 |
| US11613604B2 (en) | 2021-06-28 | 2023-03-28 | Covestro Llc | Isocyanate-reactive compositions, polyurethane foams formed therefrom, multi-layer composite articles that include such foams, and methods for their preparation |
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2009
- 2009-03-04 GB GB0903717A patent/GB0903717D0/en not_active Ceased
- 2009-04-06 GB GB0905948A patent/GB0905948D0/en not_active Ceased
- 2009-06-03 GB GB0909563A patent/GB0909563D0/en not_active Ceased
- 2009-06-11 GB GB0910063A patent/GB0910063D0/en not_active Ceased
- 2009-07-20 GB GB0912558A patent/GB0912558D0/en not_active Ceased
- 2009-10-07 GB GB0917550A patent/GB0917550D0/en not_active Ceased
-
2010
- 2010-03-03 RU RU2011140163/04A patent/RU2529469C2/ru not_active IP Right Cessation
- 2010-03-03 BR BRPI1009559A patent/BRPI1009559A2/pt not_active IP Right Cessation
- 2010-03-03 CN CN2010800105431A patent/CN102341421A/zh active Pending
- 2010-03-03 ES ES10711917.4T patent/ES2604002T3/es active Active
- 2010-03-03 WO PCT/GB2010/000381 patent/WO2010100421A2/en not_active Ceased
- 2010-03-03 CA CA2753346A patent/CA2753346C/en not_active Expired - Fee Related
- 2010-03-03 EP EP10711917.4A patent/EP2403890B1/en not_active Not-in-force
- 2010-03-03 PT PT107119174T patent/PT2403890T/pt unknown
- 2010-03-03 HU HUE10711917A patent/HUE030202T2/en unknown
- 2010-03-03 DK DK10711917.4T patent/DK2403890T3/en active
- 2010-03-03 JP JP2011552504A patent/JP5829918B2/ja not_active Expired - Fee Related
- 2010-03-03 US US12/716,684 patent/US8815968B2/en not_active Expired - Fee Related
- 2010-03-03 MX MX2011009030A patent/MX2011009030A/es active IP Right Grant
- 2010-03-03 PL PL10711917T patent/PL2403890T3/pl unknown
-
2014
- 2014-07-19 US US14/335,882 patent/US20140329923A1/en not_active Abandoned
- 2014-07-24 US US14/339,939 patent/US20140336347A1/en not_active Abandoned
-
2015
- 2015-07-31 JP JP2015152125A patent/JP2015193854A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| CN102341421A (zh) | 2012-02-01 |
| US20140329923A1 (en) | 2014-11-06 |
| JP2015193854A (ja) | 2015-11-05 |
| EP2403890A2 (en) | 2012-01-11 |
| RU2011140163A (ru) | 2013-04-10 |
| RU2529469C2 (ru) | 2014-09-27 |
| US8815968B2 (en) | 2014-08-26 |
| JP2012519743A (ja) | 2012-08-30 |
| US20100227151A1 (en) | 2010-09-09 |
| WO2010100421A4 (en) | 2010-12-16 |
| GB0917550D0 (en) | 2009-11-25 |
| GB0905948D0 (en) | 2009-05-20 |
| WO2010100421A2 (en) | 2010-09-10 |
| US20140336347A1 (en) | 2014-11-13 |
| GB0909563D0 (en) | 2009-07-15 |
| GB0910063D0 (en) | 2009-07-22 |
| PL2403890T3 (pl) | 2017-08-31 |
| GB0912558D0 (en) | 2009-08-26 |
| CA2753346A1 (en) | 2010-09-10 |
| PT2403890T (pt) | 2016-11-14 |
| MX2011009030A (es) | 2011-12-14 |
| EP2403890B1 (en) | 2016-08-17 |
| GB0903717D0 (en) | 2009-04-15 |
| ES2604002T3 (es) | 2017-03-02 |
| CA2753346C (en) | 2017-08-29 |
| BRPI1009559A2 (pt) | 2016-03-22 |
| WO2010100421A3 (en) | 2010-10-28 |
| DK2403890T3 (en) | 2016-12-12 |
| JP5829918B2 (ja) | 2015-12-09 |
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