HRP20161688T1 - Termoplastična polimerna formulacija koja sadrži poliamide/evoh i poliolefine, njena primjena i proizvodi - Google Patents

Termoplastična polimerna formulacija koja sadrži poliamide/evoh i poliolefine, njena primjena i proizvodi Download PDF

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HRP20161688T1
HRP20161688T1 HRP20161688TT HRP20161688T HRP20161688T1 HR P20161688 T1 HRP20161688 T1 HR P20161688T1 HR P20161688T T HRP20161688T T HR P20161688TT HR P20161688 T HRP20161688 T HR P20161688T HR P20161688 T1 HRP20161688 T1 HR P20161688T1
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range
formulation
evoh
amount
formulation according
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HRP20161688TT
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Giuseppe DINUNZIO
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Igap S.P.A.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
    • C08J11/08—Recovery or working-up of waste materials of polymers without chemical reactions using selective solvents for polymer components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C08L23/0861—Saponified vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/20—Recycled plastic

Claims (18)

1. Termoplastična polimerna formulacija koja sadrži poliamide (PA) i/ili EVOH i poliolefine, naznačena time, da ona također sadrži polipropilen homopolimer s MFI (indeks tečenja taline) u području od 15 do 50, prvenstveno 20 do 50 (g/10min, ASTM 1238L), kao kompatibilizator između navedenih PA i/ili EVOH i poliolefinskih polimera, u čemu je količina navedenog PP homopolimera u području od 15 do 50 tež.%, a formulacija nadalje sadrži PP (ko)polimer koji je različit od gore navedenog PP homopolimera.
2. Formulacija prema patentnom zahtjevu 1, naznačena time, da količina navedenog PP homopolimera jest u području od 25 do 45 tež.% u odnosu na ukupnu težinu formulacije.
3. Formulacija prema patentnom zahtjevu 1 ili 2, naznačena time, da navedeni PA i/ili EVOH i poliolefini (PE, PP) proizlaze barem djelomično iz otpadnih materijala od proizvodnje višeslojnih folija koje sadrže dva ili više PE, PA, PP, EVOH, i gdje su ti materijali prisutni u količini u području od 10 do 70%, prvenstveno 25 do 35 tež.% u odnosu na konačnu težinu formulacije.
4. Formulacija prema bilo kojem od patentnih zahtjeva 1 do 3, naznačena time, da nadalje sadrži PP punjen anorganskim i/ili organskim punilima, a navedeni PP s punilom je prisutan u količini od 15 do 40, prvenstveno 25 i 35 tež.% u odnosu na konačnu težinu formulacije.
5. Formulacija prema patentnom zahtjevu 4, naznačena time, da navedeno mineralno punilo jest CaCO3, a navedeno organsko punilo jest drvo.
6. Formulacija prema patentnom zahtjevu 5, naznačena time, da sadrži od 3 do 18 tež.% drvenih čestica u odnosu na ukupnu težinu formulacije.
7. Formulacija prema bilo kojem od patentnih zahtjeva 2 do 4, naznačena time, da sadrži od 3 do 18 tež.% CaCO3 u odnosu na ukupnu težinu formulacije.
8. Formulacija prema bilo kojem od prethodnih patentnih zahtjeva, naznačena time, da u odnosu na konačnu težine formulacije težinski sadrži: a) PA u količini u području od 0 do 20 tež.%, prvenstveno između 1 i 15 tež.%; b) EVOH u količini u području od 0 do 2,0 tež.%, prvenstveno između 0,06 i 0,67 tež.%; c) PE u količini u području od 0 do 40 tež.%, prvenstveno između 1 i 35 tež.%; d) PP različit od PP iz točaka e) i f) u količini u području od 0 do 40 tež.%, prvenstveno između 1 i 35 tež.%; e) PP homopolimer s MFI u području od 15 do 50, prvenstveno 20 do 50 (g/10min, ASTM 1238L), u količini u području od 25,0 do 45 tež.%, prvenstveno 30 do 35 tež.%; f) PP (ko)polimer s punilom u količini u području od 15 do 40 tež.%, prvenstveno 30 do 35 tež.%; i u čemu, kada PA jest 0%, prisutan je EVOH, a kada EVOH jest 0%, prisutan je PA.
9. Formulacija prema patentnom zahtjevu 8, naznačena time, da materijali a) do d) proizlaze iz otpada od proizvodnje višeslojne folije.
10. Formulacija prema patentnom zahtjevu 9, naznačena time, da sadrži: - jedan dio materijala a) do d), a navedeni su materijali prisutni u količinama prema patentnom zahtjevu 8; - jedan dio materijala e); -jedan dio materijala f).
11. Formulacija prema bilo kojem od prethodnih patentnih zahtjeva, naznačena time, da navedeni PP homopolimer s MFI u području od 15 do 50 (g/10min, ASTM 1238L) ili pokazuje modul elastičnosti između 1200 i 1600 N/cm2 ili ima modul elastičnosti u području od 1700 do 2300 N/cm2, najpogodnije 2100 N/cm2.
12. Lijevani ili ekstrudirani proizvod, naznačen time, da je barem djelomično proizveden s termoplastičnom formulacijom prema jednom od prethodnih patentnih zahtjeva.
13. Lijevani ili ekstrudirani proizvod prema patentnom zahtjevu 12, naznačen time, da navedeni proizvod jest naslonjač ili drugi sličan element namještaja.
14. Lijevani ili ekstrudirani proizvod prema patentnom zahtjevu 12 ili 13, naznačen time, da navedeni proizvod sadrži punilo na bazi drveta.
15. Lijevani ili ekstrudirani proizvod prema patentnom zahtjevu 14, naznačen time, da navedeni proizvod jesu vrata, stranica ili neki drugi dio komada namještaja.
16. Postupak za recikliranje otpadnih materijala koji sadrže poliolefine, poliamide (PA) i/ili EVOH, koji proizlaze iz proizvodnje višeslojnih folija, naznačen time, da su navedeni materijali smiješani s propilen homopolimerom koji ima MFI u području između 15 do 50, prvenstveno 20 do 50 (g/10min, ASTM 1238L) i s bilo kojim drugim poliolefin polimerom da se dobije formulacija prema bilo kojem od patentnih zahtjeva 1 do 11, i da se po izboru ova formulacija granulira.
17. Postupak prema patentnon zahtjevu 16, naznačen time, da sadrži stupanj sušenja i/ili odvlaživanja navedenih otpadnih materijala.
18. Primjena polipropilen homopolimera koji ima MFI u području od 15 do 50, prvenstveno 20 do 50 (g/10min, ASTM 1238L) naznačena time, da jest kao kompatibilizator polimer između dva ili više polimera odabranih od PE, PA, PP, EVOH i njihovih smjesa.
HRP20161688TT 2012-04-03 2016-12-12 Termoplastična polimerna formulacija koja sadrži poliamide/evoh i poliolefine, njena primjena i proizvodi HRP20161688T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IB2012000676 2012-04-03
PCT/IB2013/000570 WO2013150357A1 (en) 2012-04-03 2013-03-29 Thermoplastic polymer formulation containing polyamides/evoh and polyolefins, use and products thereof
EP13722045.5A EP2834302B1 (en) 2012-04-03 2013-03-29 Thermoplastic polymer formulation containing polyamides/evoh and polyolefins, use and products thereof

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HRP20161688T1 true HRP20161688T1 (hr) 2017-02-24

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US (1) US20150087752A1 (hr)
EP (1) EP2834302B1 (hr)
KR (1) KR102059216B1 (hr)
CN (1) CN104334633A (hr)
AR (1) AR092822A1 (hr)
CY (1) CY1118342T1 (hr)
ES (1) ES2617078T3 (hr)
HK (1) HK1205171A1 (hr)
HR (1) HRP20161688T1 (hr)
HU (1) HUE032466T2 (hr)
IL (1) IL234974A0 (hr)
PL (1) PL2834302T3 (hr)
PT (1) PT2834302T (hr)
RS (1) RS55482B1 (hr)
SM (1) SMT201600457B (hr)
TW (1) TW201348319A (hr)
WO (1) WO2013150357A1 (hr)

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KR101562336B1 (ko) 2014-12-10 2015-10-22 에스알테크노팩 주식회사 열가소성 수지제품의 재활용을 위한 첨가제 조성물 및 이를 이용한 열가소성 수지제품의 재활용방법
NL2022244B1 (en) * 2018-12-18 2020-07-03 Quinlyte Holding B V Polymer composition, method for preparing said composition, article comprising said composition and method for preparing said article.
KR102525364B1 (ko) 2021-01-28 2023-04-25 (주) 케이엠팩 폴리올레핀계 다층 폐플라스틱이 포함된 고분자 수지 조성물 및 이를 이용하여 제조된 압출시트
WO2023187059A1 (en) 2022-03-31 2023-10-05 Omya International Ag Calcium carbonate for improving the mechanical properties of thermoplastic polymer compositions

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JP3550882B2 (ja) * 1996-05-23 2004-08-04 チッソ株式会社 極細繊維不織布
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KR102059216B1 (ko) 2019-12-24
KR20150005542A (ko) 2015-01-14
EP2834302A1 (en) 2015-02-11
HK1205171A1 (en) 2015-12-11
AR092822A1 (es) 2015-05-06
IL234974A0 (en) 2014-12-31
CY1118342T1 (el) 2017-06-28
PT2834302T (pt) 2016-12-22
WO2013150357A1 (en) 2013-10-10
ES2617078T3 (es) 2017-06-15
HUE032466T2 (en) 2017-09-28
TW201348319A (zh) 2013-12-01
CN104334633A (zh) 2015-02-04
EP2834302B1 (en) 2016-09-14
SMT201600457B (it) 2017-03-08
US20150087752A1 (en) 2015-03-26
PL2834302T3 (pl) 2017-03-31

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