HK40086355A - Method for improving the ohmic contact behavior between a contact grid and an emitter layer of a silicon solar cell - Google Patents
Method for improving the ohmic contact behavior between a contact grid and an emitter layer of a silicon solar cell Download PDFInfo
- Publication number
- HK40086355A HK40086355A HK62023075395.1A HK62023075395A HK40086355A HK 40086355 A HK40086355 A HK 40086355A HK 62023075395 A HK62023075395 A HK 62023075395A HK 40086355 A HK40086355 A HK 40086355A
- Authority
- HK
- Hong Kong
- Prior art keywords
- processing
- current
- solar cell
- measurement
- silicon solar
- Prior art date
Links
Description
本发明涉及一种改善硅太阳能电池的接触格与发射极层之间的欧姆接触特性的方法,其中在一个处理步骤中用电压源和与所述电压源连接的接触装置在所述硅太阳能电池的接触格与背触点之间施加一个反向于所述硅太阳能电池的正向的小于所述硅太阳能电池的击穿电压的电压,以及,当施加所述电压时,在所述硅太阳能电池的面向太阳的一侧的范围内对点光源进行导引,以及,在此过程中对所述面向太阳的一侧的分区的处理局部进行照射,从而在所述相应分区内通过感应产生处理电流,以及,所述处理电流就所述处理局部而言具有200A/cm2至20000A/cm2的电流密度且为时10ns至10ms地作用于所述分区。This invention relates to a method for improving the ohmic contact characteristics between the contact grid and the emitter layer of a silicon solar cell, wherein in a processing step, a voltage less than the breakdown voltage of the silicon solar cell, opposite to the forward direction of the silicon solar cell, is applied between the contact grid and the back contact of the silicon solar cell using a voltage source and a contact device connected to the voltage source; and, when the voltage is applied, a point light source is guided within a region on the sun-facing side of the silicon solar cell; and, in the process, a processing area of the sun-facing side is irradiated, thereby generating a processing current in the corresponding area by induction; and, the processing current has a current density of 200 A/ cm² to 20000 A/ cm² with respect to the processing area and acts on the area for 10 ns to 10 ms.
在晶体硅太阳能电池的制造过程中,以丝网印刷法将金属膏施覆至涂布有介电的氮化硅的、形式为接触格的前端。针对硅太阳能电池的位于氮化硅层下方的发射极层的接触,在施覆金属膏后在800-900℃下实施回火步骤。其中,在金属膏中所含有的玻璃粉的协助下,金属膏的银穿过氮化硅层扩散进入发射极层。其中,回火步骤期间的过程控制对接触形成有决定性影响。在过程控制正确的情况下,接触格与发射极层之间的过渡处具有接触电阻低的特征。在过程控制有缺陷的情况下,通常仅实现较高的接触电阻。如果在回火步骤中例如应用过低的温度,则金属膏无法充分地穿过氮化硅层扩散,故在接触格与发射极层之间仅形成较小的接触面以及较高的接触电阻。高接触电阻又导致太阳能电池的效率大幅降低,使得这些太阳能电池无法装在太阳能组件中,进而报废。In the manufacturing process of crystalline silicon solar cells, metal paste is applied to the front end of a contact grid coated with dielectric silicon nitride using screen printing. For the contact of the emitter layer beneath the silicon nitride layer in the silicon solar cell, a tempering step is performed at 800-900°C after applying the metal paste. During this process, with the assistance of glass powder contained in the metal paste, the silver in the metal paste diffuses through the silicon nitride layer into the emitter layer. Process control during the tempering step has a decisive influence on contact formation. With proper process control, the transition between the contact grid and the emitter layer is characterized by low contact resistance. With defective process control, only a higher contact resistance is typically achieved. If, for example, too low a temperature is applied during the tempering step, the metal paste cannot diffuse sufficiently through the silicon nitride layer, resulting in only a small contact area and high contact resistance between the contact grid and the emitter layer. High contact resistance leads to a significant reduction in the efficiency of the solar cell, making it unsuitable for use in solar modules and thus rendering it unusable.
在现有技术中,由DE 10 2018 001 057 A1已知一种改善硅太阳能电池的接触格与发射极层之间的欧姆接触特性的方法。其中,在一个处理步骤中反向于硅太阳能电池的正向对此硅太阳能电池施加预置电压,并且用点光源进行扫描。在此过程中,在此太阳能电池的相应被照射的分区内产生电流密度在200A/cm2至20000A/cm2数量级的处理电流。其中,在此太阳能电池上导引点光源,使得处理电流为时10ns至10ms地作用于此分区。通过照射和反向于硅太阳能电池的正向的电压的相互作用产生的这个电流使得硅太阳能电池的接触格与发射极层之间的欧姆接触特性得到改善。In the prior art, a method for improving the ohmic contact characteristics between the contact grid and the emitter layer of a silicon solar cell is known from DE 10 2018 001 057 A1. In this method, a preset voltage is applied to the silicon solar cell in the reverse direction of the forward direction, and scanning is performed using a point light source. During this process, a processing current with a current density on the order of 200 A/ cm² to 20000 A/ cm² is generated within the corresponding irradiated section of the solar cell. The point light source is guided onto the solar cell such that the processing current acts on this section for 10 ns to 10 ms. This current, generated by the interaction of irradiation and the voltage reversed to the forward direction of the silicon solar cell, improves the ohmic contact characteristics between the contact grid and the emitter layer of the silicon solar cell.
但缺点在于,为将通过此方法实现的欧姆接触特性的改善量化,必须在应用此方法后对此太阳电池进行电表征。这种表征例如可以是在太阳能模拟器中记录太阳能电池在照射下的IU特性曲线,其中可以由IU特性曲线所确定的硅太阳能电池的串联电阻推导出接触特性的改善。但在应用已知方法之前和之后对太阳能电池的测量使得太阳能电池的处理过程整体上难度较大。此外,应用此方法来改善各个太阳能电池中的欧姆接触特性也可能造成损伤,因为例如在这些太阳能电池的各分区内均需要设置不同于这些太阳能电池的其余部分的参数(例如更短的电流作用时长)。硅太阳能电池的接触格与发射极层之间的欧姆接触特性同样可以局部发生变化,这原则上需要在应用已知方法时相应地改变参数。参数的这种局部变化可以借助于已知方法来调节。但在应用已知方法时,硅太阳能电池的需要相应地局部改变参数的区域是未知的。However, a drawback is that to quantify the improvement in ohmic contact characteristics achieved through this method, the solar cell must be electrically characterized after applying the method. This characterization could, for example, involve recording the IU characteristic curve of the solar cell under illumination in a solar simulator, where the improvement in contact characteristics can be derived from the series resistance of the silicon solar cell determined by the IU characteristic curve. However, the measurement of the solar cell before and after applying the known method makes the overall processing of the solar cell quite difficult. Furthermore, applying this method to improve the ohmic contact characteristics in individual solar cells may also cause damage, because, for example, parameters (e.g., shorter current duration) need to be set in each section of these solar cells, different from the rest of the solar cells. The ohmic contact characteristics between the contact grid and the emitter layer of the silicon solar cell can also change locally, which in principle requires corresponding parameter changes when applying the known method. Such local parameter changes can be adjusted using known methods. However, when applying the known method, the areas of the silicon solar cell that require corresponding local parameter changes are unknown.
本发明的目的是,对改善硅太阳能电池的接触格与发射极层之间的欧姆接触特性的方法进行改善。特别是应在实施所述方法时实现对所述方法所实现的改善的量化。此外,应在实施所述方法时识别出因使用不利的方法参数而造成的可能的损伤。The object of this invention is to improve a method for improving the ohmic contact characteristics between the contact grid and the emitter layer of a silicon solar cell. In particular, the improvement achieved by the method should be quantified during its implementation. Furthermore, potential damage caused by using unfavorable method parameters should be identified during the implementation of the method.
本发明用以达成上述目的的解决方案为具有权利要求1的特征的一种改善硅太阳能电池的接触格与发射极层之间的欧姆接触特性的方法。有利技术方案在权利要求2至20中示出。The solution of the present invention to achieve the above-mentioned objective is a method having the features of claim 1 for improving the ohmic contact characteristics between the contact grid and the emitter layer of a silicon solar cell. Advantageous solutions are shown in claims 2 to 20.
在已知的方法部分中,首先提供包含发射极层、接触格和背触点的硅太阳能电池。在一个处理步骤中,借助于接触装置和电压源在接触格与背触点之间施加一个反向于硅太阳能电池的正向的小于硅太阳能电池的击穿电压的电压。当施加这个电压时,在硅太阳能电池的面向太阳的一侧的范围内对点光源进行导引,其中对所述面向太阳的一侧的分区的处理局部进行照射,从而在所述相应分区内通过感应产生处理电流,以及,这个处理电流就所述处理局部而言具有200A/cm2至20000A/cm2的电流密度且为时10ns至10ms地作用于所述分区。In the known method section, a silicon solar cell comprising an emitter layer, a contact grid, and a back contact is first provided. In one processing step, a voltage less than the breakdown voltage of the silicon solar cell, reversed from the forward direction, is applied between the contact grid and the back contact by means of a contact device and a voltage source. When this voltage is applied, a point light source is directed within a region on the sun-facing side of the silicon solar cell, illuminating a processing area of the sun-facing section, thereby generating a processing current within the corresponding section by induction, and this processing current having a current density of 200 A/ cm² to 20000 A/ cm² for the processing area and acting on the section for 10 ns to 10 ms.
根据本发明,在处理步骤之前和/或之后实施测量步骤。在这个测量步骤中,用电压源和接触装置在接触格与背触点之间施加一个电压。在此情形下,当施加这个电压时,用点光源照射硅太阳能电池的面向太阳的一侧的分区的测量局部,其中如此地设定电压和照射强度,从而在相应分区内通过感应产生测量电流,该测量电流就测量局部而言具有1mA/cm2至500mA/cm2的电流密度。在给定的电压和照射强度下,用电流表检测测量电流,并且与相应测量局部对应地存储。According to the invention, a measurement step is performed before and/or after the processing step. In this measurement step, a voltage is applied between the contact grid and the back contact using a voltage source and a contact device. In this case, when this voltage is applied, a measurement section of the sun-facing side of the silicon solar cell is illuminated with a point light source, wherein the voltage and illumination intensity are set such that a measurement current is induced within the corresponding section, the measurement current having a current density of 1 mA/ cm² to 500 mA/ cm² for the measurement section. Under the given voltage and illumination intensity, the measurement current is detected with an ammeter and stored corresponding to the corresponding measurement section.
在此情形下,针对相应测量局部测得的电流强度可用于后续处理,例如用于过程监控、过程控制或品控。在接触格与发射极层之间具有良好的欧姆接触特性或较小的局部短路电流的区域因相对于具有不良欧姆接触特性的区域具有更高的电流强度而显露出来。由于电流强度是与相应测量局部和/或处理局部对应地存储,因此,存在有关于硅太阳能电池的电气特性的空间分辨信息。在此情形下,将这些空间分辨信息用作处理步骤的调节变量。在处理步骤中,为影响处理电流,可以在照射时对点光源的照射强度和/或照射的作用时间和/或反向于硅太阳能电池的正向的电压的水平进行调整。In this scenario, the current intensity measured at the corresponding measurement location can be used for subsequent processing, such as process monitoring, process control, or quality control. Regions with good ohmic contact characteristics or small local short-circuit currents between the contact grid and the emitter layer are exposed due to higher current intensity compared to regions with poor ohmic contact characteristics. Since the current intensity is stored corresponding to the corresponding measurement location and/or processing location, spatially resolved information about the electrical characteristics of the silicon solar cell exists. In this case, this spatially resolved information is used as a regulating variable for the processing steps. During the processing steps, to influence the processing current, the irradiation intensity of the point light source and/or the duration of irradiation and/or the level of the voltage reversed to the forward direction of the silicon solar cell can be adjusted during irradiation.
视具体所期望的测量信息,测量步骤中所施加的电压反向于硅太阳能电池的正向且小于硅太阳能电池的击穿电压,或者,测量步骤中所施加的电压沿硅太阳能电池的正向定向。Depending on the specific measurement information desired, the voltage applied in the measurement step is opposite to the forward direction of the silicon solar cell and less than the breakdown voltage of the silicon solar cell, or the voltage applied in the measurement step is oriented along the forward direction of the silicon solar cell.
在本发明的方法的另一实施方案中,在处理步骤期间,针对被照射的处理局部的至少一部分,同样用电流表检测相应的处理电流,并且与相应处理局部对应地存储。对测量电流的强度的检测和对处理电流的强度的检测可以相互可选地实施。例如可以仅在处理步骤之前实施测量步骤,而无需在处理步骤中同时检测处理电流,且无需在处理步骤后实施另一测量步骤。同样地,例如也可以仅在处理步骤中检测处理电流,而完全不需要在处理步骤上游或下游实施测量步骤。同样可以在处理步骤之前或之后实施测量步骤,并且在处理步骤中同时检测处理电流,或者仅在处理步骤上游或下游的测量步骤中检测测量电流,而无需在处理步骤中检测处理电流。In another embodiment of the method of the invention, during the processing step, a corresponding processing current is also detected with an ammeter for at least a portion of the irradiated processing area, and stored corresponding to the corresponding processing area. The detection of the intensity of the measurement current and the detection of the intensity of the processing current can be performed selectively. For example, the measurement step can be performed only before the processing step, without simultaneously detecting the processing current during the processing step, and without performing another measurement step after the processing step. Similarly, for example, the processing current can be detected only during the processing step, without performing any measurement steps upstream or downstream of the processing step. Likewise, the measurement step can be performed before or after the processing step, and the processing current can be detected simultaneously during the processing step, or the measurement current can be detected only in a measurement step upstream or downstream of the processing step, without detecting the processing current during the processing step.
在此情形下,检测到并且存储的处理电流值可用于后续处理,例如用于过程监控、过程控制或品控。In this case, the detected and stored processing current value can be used for subsequent processing, such as process monitoring, process control, or quality control.
在本发明的方法中,在测量步骤中,在给定的电压和给定的照射强度下检测测量电流的强度。众所周知的是,在电流恒定并且对相应电压进行检测的情况下也可以实施电测量,由此可以如此地实施本发明的方法的测量步骤,从而预设恒定的电流并用电压表检测相应的电压,并且与相应测量局部或处理局部对应地存储。亦即,这两种形式的测量在本发明的主题中被视为等效的。In the method of the present invention, during the measurement step, the intensity of the measuring current is detected under a given voltage and a given irradiation intensity. It is well known that electrical measurements can also be performed when the current is constant and the corresponding voltage is detected. Thus, the measurement step of the method of the present invention can be implemented such that a constant current is preset and the corresponding voltage is detected using a voltmeter, and the data is stored corresponding to the corresponding measurement or processing section. That is, these two forms of measurement are considered equivalent within the scope of the present invention.
本发明的方法同样不局限于存储测量电流或处理电流的与相应的测量局部或处理局部对应的电流强度。存储同样可以以转换后的形式,例如作为电流密度实施,其中为此例如以测量局部的面积来计算相应电流强度。或者,电流强度例如与所施加电压相关地作为电阻值存储。The method of the present invention is not limited to storing the current intensity corresponding to the corresponding measurement or processing area of the measured or processed current. Storage can also be implemented in a converted form, for example, as current density, where the corresponding current intensity is calculated, for example, by the area of the measurement area. Alternatively, the current intensity can be stored as a resistance value, for example, in relation to the applied voltage.
测量步骤中的电压源和接触装置可以与处理步骤中所使用的相同。其优点在于不需要其他接触装置。但本发明并不局限于此。为检测测量电流,原则上也可以使用另一接触装置和/或另一电压源作为用于检测处理电流的接触装置和/或电压源。当然,在点光源方面同样有利地,在处理步骤与测量步骤中使用相同的点光源,但其中本发明并不局限于此,原则上也可以使用不同的点光源。The voltage source and contact device used in the measurement step can be the same as those used in the processing step. This has the advantage of eliminating the need for additional contact devices. However, the invention is not limited to this. In principle, another contact device and/or another voltage source can also be used as the contact device and/or voltage source for detecting the processing current. Of course, it is equally advantageous to use the same point light source in both the processing and measurement steps, but the invention is not limited to this, and different point light sources can also be used in principle.
通过检测处理电流和/或测量电流,可以将检测到的电流用作接触格与发射极层之间的欧姆接触特性的品质的衡量尺度。在持续照射且施加电压的情况下,在接触格与发射极层之间具有良好的欧姆接触特性的分区比具有不良欧姆接触特性的分区具有更大的测量电流。其中,可以通过处理步骤上游的测量步骤找出具有不良欧姆接触特性的分区。随后,针对这些区域,在处理步骤中设置经过修改的反向于硅太阳能电池的正向的电压和点光源的照射强度的参数。或者,在处理步骤中仅对具有不良欧姆接触特性的分区进行加工,处理步骤中可以略过已显示出良好欧姆接触特性的分区。By detecting the processing current and/or measuring the current, the detected current can be used as a measure of the quality of the ohmic contact characteristics between the contact grid and the emitter layer. Under continuous irradiation and applied voltage, sections with good ohmic contact characteristics between the contact grid and the emitter layer exhibit a larger measured current than sections with poor ohmic contact characteristics. Sections with poor ohmic contact characteristics can be identified through a measurement step upstream of the processing step. Subsequently, for these regions, modified parameters of the voltage reversed from the forward direction of the silicon solar cell and the irradiation intensity of the point light source are set in the processing step. Alternatively, only sections with poor ohmic contact characteristics can be processed in the processing step, while sections exhibiting good ohmic contact characteristics can be skipped.
例如可以将处理步骤下游的对测量电流的检测用作进一步处理太阳能组件中的硅太阳能电池的品质特征。For example, the detection of the measured current downstream of the processing step can be used as a quality characteristic of the silicon solar cells in the solar module for further processing.
通过在处理步骤之前以及之后检测测量电流,可以空间分辨地确定处理步骤所实现的对欧姆接触特性的改善。在电压和照射强度的参数恒定的情况下,欧姆接触特性的改善作为测量电流的增大而可见。在此也可以找出可能尚未达到接触格与发射极层之间的良好的欧姆接触特性的目标值的分区,从而针对性地实施限制在这些分区上的进一步处理步骤。By detecting the measurement current before and after the processing steps, the improvement in ohmic contact characteristics achieved by the processing steps can be determined spatially with precision. With constant voltage and irradiation intensity parameters, the improvement in ohmic contact characteristics is visible as an increase in the measurement current. This also allows for the identification of zones where the target value for good ohmic contact characteristics between the contact grid and the emitter layer may not yet be achieved, thus enabling targeted implementation of further processing steps limited to these zones.
此外,也能利用处理步骤中测得且位置对应的处理电流来设定处理步骤本身的参数。例如可以将对应于某个处理局部的电流强度用作在同一处理步骤中照射后一处理局部时设定点光源的照射强度和/或照射的作用时间和/或反向于硅太阳能电池的正向的电压的水平的调节变量。Furthermore, the processing current measured at the location during the processing step can be used to set the parameters of the processing step itself. For example, the current intensity corresponding to a certain processing location can be used as an adjustment variable to set the irradiation intensity and/or irradiation duration of the point light source and/or the voltage level opposite to the forward direction of the silicon solar cell when irradiating a subsequent processing location in the same processing step.
同样有利地,在处理步骤中,当照射处理局部中的一个时,用电流表检测第一电流强度,随后检测第二电流强度,并且与该处理局部对应地存储这两个电流强度。随后,可以由这两个电流强度针对相应的处理局部计算出电流强度梯度,该电流强度梯度可以用作处理步骤针对每个处理局部所实现的对欧姆接触特性的改善的衡量尺度。在此,电流强度梯度也可以在处理步骤中用于调节下游处理局部的参数,或者也可以用于完全下游的处理步骤。Advantageously, in the processing step, when one of the processing areas is irradiated, a first current intensity is detected using an ammeter, followed by a second current intensity, and these two current intensities are stored corresponding to that processing area. Subsequently, a current intensity gradient can be calculated from these two current intensities for the corresponding processing area. This current intensity gradient can be used as a measure of the improvement in ohmic contact characteristics achieved by the processing step for each processing area. Here, the current intensity gradient can also be used in the processing step to adjust parameters of downstream processing areas, or it can be used in entirely downstream processing steps.
除了在照射时检测测量电流或处理电流的强度之外,也可以在上游和/或下游的测量步骤中以及/或者在未照射硅太阳能电池时的处理步骤中检测硅太阳能电池的反向电流,并且与相应处理局部和/或测量局部对应地存储。其中,反向电流的值适于对因使用具有不利参数的处理步骤而可能对硅太阳能电池造成的损伤进行评价。根据参考值来评价反向电流,将该参考值例如与本发明上游的硅太阳能电池的电表征(例如记录IU特性曲线)中获得的反向电流值进行对比。例如,如果用本发明的方法测得的反向电流大于由之前的电表征产生的反向电流值,那么这可能表示在应用改善的方法时因不利的参数而对硅太阳能电池造成损伤。这种损伤例如可以是在硅太阳能电池内部形成短路,可以从硅太阳能电池的反向电流增大识别出这一点。In addition to detecting the intensity of the measuring or processing current during irradiation, the reverse current of the silicon solar cell can also be detected in upstream and/or downstream measurement steps and/or in processing steps when the silicon solar cell is not irradiated, and stored correspondingly to the respective processing and/or measurement locations. The value of the reverse current is suitable for evaluating potential damage to the silicon solar cell caused by processing steps with unfavorable parameters. The reverse current is evaluated against a reference value, for example, compared to a reverse current value obtained from electrical characterization (e.g., recording the IU characteristic curve) of the upstream silicon solar cell of the present invention. For example, if the reverse current measured by the method of the present invention is greater than the reverse current value obtained from previous electrical characterization, this may indicate damage to the silicon solar cell due to unfavorable parameters when the improved method is applied. Such damage may, for example, be the formation of a short circuit inside the silicon solar cell, which can be identified by an increase in the reverse current of the silicon solar cell.
除了利用由之前的电表征产生的反向电流值之外,参考值还可以是在处理步骤上游的测量步骤中检测到的反向电流。或者,在处理步骤中,在照射处理局部的至少一部分之前对反向电流进行测量。In addition to using the reverse current value generated from the previous electrical characterization, the reference value can also be the reverse current detected in a measurement step upstream of the processing step. Alternatively, the reverse current can be measured in the processing step before at least a portion of the processing area is irradiated.
在有利的实施方案中,同样可以将反向电流与相应参考反向电流的偏差用作照射处理局部的至少一部分时设定照射强度和/或照射的作用时间和/或反向于硅太阳能电池的正向的电压的水平的调节变量。同样可以通过确定处理步骤之后反向电流的极限值,和/或通过确定处理步骤所引起的反向电流的变化的极限值来提供硅太阳能电池的剔除标准,从而将相应的硅太阳能电池从进一步的处理工艺移除,这样就不会将其例如装入太阳能组件。In an advantageous implementation, the deviation of the reverse current from a corresponding reference reverse current can also be used as an adjustment variable to set the irradiation intensity and/or the duration of irradiation and/or the level of the voltage reversed to the forward direction of the silicon solar cell when irradiating at least a portion of the localized treatment area. Similarly, rejection criteria for silicon solar cells can be provided by determining the limit value of the reverse current after the treatment step, and/or by determining the limit value of the change in reverse current caused by the treatment step, thereby removing the corresponding silicon solar cells from further processing and preventing them from being, for example, installed in solar modules.
当在测量步骤或处理步骤中检测反向电流时,也可以改变反向于正向且小于硅太阳能电池的击穿电压的电压。由此,针对预设的电压分别测定一个反向电流并且与相应测量局部或处理局部对应地存储。可以通过反向于正向的电压的改变识别出硅太阳能电池的这种损伤,从而例如将形式为硅太阳能电池中的裂纹的损伤与载流子复合增加所引起的损伤区别开。When detecting reverse current during a measurement or processing step, a voltage reversed to the forward direction and less than the breakdown voltage of the silicon solar cell can be changed. Thus, a reverse current is measured for each preset voltage and stored corresponding to the respective measurement or processing location. This type of damage to the silicon solar cell can be identified by the change in the reverse voltage, thereby distinguishing, for example, damage in the form of cracks in the silicon solar cell from damage caused by increased carrier recombination.
在所述方法的其他技术方案中,在处理步骤和/或测量步骤中,当照射处理局部或测量局部的至少一部分时,通过测量检测从硅太阳能电池的面向太阳的一侧反射的照射分量,并且与相应局部对应地存储。由此,也能够识别出处理步骤所引起的光学特性的变化。In other technical solutions of the method, during the processing and/or measurement steps, when at least a portion of the processed or measured area is irradiated, the irradiation component reflected from the sun-facing side of the silicon solar cell is detected by measurement and stored corresponding to the respective area. This also allows for the identification of changes in optical properties caused by the processing steps.
当在测量步骤中照射测量局部和/或在处理步骤中照射处理局部时,优选地,改变点光源发出的光辐射的波长,并同样针对这个光辐射在测量步骤和/或处理步骤中检测电流强度,并且与相应局部对应地存储。When irradiating the measurement area in the measurement step and/or the processing area in the processing step, preferably, the wavelength of the light radiation emitted by the point light source is changed, and the current intensity is detected in the measurement step and/or processing step for the same light radiation, and stored in correspondence with the corresponding area.
当检测测量电流和/或处理电流和/或反向电流的电流强度时,有利地,可以使用同一电流表。但本发明并不局限于此。视具体测量区域,也可以使用不同的测量仪。例如,处理电流的电流强度与反向电流的电流强度存在数量级上的差异,因此,在此使用两个针对相应区域优化的电流表是合理的。When measuring the current intensity of the current and/or the processing current and/or the reverse current, it is advantageous to use the same ammeter. However, the invention is not limited to this. Depending on the specific measurement area, different measuring instruments may also be used. For example, the current intensity of the processing current differs from that of the reverse current by orders of magnitude; therefore, it is reasonable to use two ammeters optimized for the corresponding areas.
下面对本发明的不同实施例进行说明。Different embodiments of the present invention will be described below.
第一实施例:First embodiment:
在本发明的改善硅太阳能电池的接触格与发射极层之间的欧姆接触特性的方法中,首先提供包含发射极层、接触格和背触点的硅太阳能电池。其例如可以是定位在加工台上的尺寸为15.7cm×15.7cm的多晶硅太阳能电池。随后借助于接触装置将接触格与电压源的一个电极电连接,并且将背触点与电压源的另一电极连接。接触装置例如可以具有弹簧触针,这些弹簧触针平放在硅太阳能电池的接触格或背触点上,并且通过电缆连接与电压源连接。In the method for improving the ohmic contact characteristics between the contact grid and the emitter layer of a silicon solar cell according to the present invention, a silicon solar cell comprising an emitter layer, a contact grid, and a back contact is first provided. For example, it may be a polycrystalline silicon solar cell with dimensions of 15.7 cm × 15.7 cm positioned on a processing table. Subsequently, the contact grid is electrically connected to one electrode of a voltage source by means of a contact device, and the back contact is connected to the other electrode of the voltage source. The contact device may, for example, have spring-loaded pins that lie flat on the contact grid or back contact of the silicon solar cell and are connected to the voltage source via a cable.
在第一测量步骤中,通过接触装置以电压源在接触格与背触点之间施加一个沿硅太阳能电池的正向定向的电压。当施加这个电压时,用点光源照射硅太阳能电池的面向太阳的一侧的分区的各测量局部。这个点光源例如可以是激光或聚焦白色光源。通过照射,在相应分区内通过感应产生测量电流,其中如此地设定所施加的电压和点光源的照射强度,使得这个测量电流就测量局部而言具有1mA/cm2至500mA/cm2的电流密度。为照射各测量局部,现在各测量局部间导引点光源所发出的光,其中所施加的电压和点光源的照射强度保持恒定。现针对硅太阳能电池中的电流的每个测量局部用电流表(安培计)和接触装置进行测量,其中将相应测量电流的检测到的电流强度与相应测量局部对应地存储。通过以下方式来将测得的电流强度与相应的测量局部对应:针对相应电流强度,例如还将这个测量局部在硅太阳能电池的面向太阳的一侧上的位置坐标一起存储。In the first measurement step, a voltage oriented in the forward direction of the silicon solar cell is applied between the contact grid and the back contact via a voltage source using a contact device. While this voltage is applied, each measurement section of the solar cell's sun-facing side is illuminated with a point light source. This point light source can be, for example, a laser or a focused white light source. Illumination induces a measurement current within the corresponding section, wherein the applied voltage and the illumination intensity of the point light source are set such that the measurement current has a current density of 1 mA/ cm² to 500 mA/ cm² for the measurement section. To illuminate each measurement section, light emitted from the point light source is now guided between the measurement sections, wherein the applied voltage and the illumination intensity of the point light source remain constant. The current in the silicon solar cell is now measured for each measurement section using an ammeter and a contact device, wherein the detected current intensity of the corresponding measurement current is stored in correspondence with the corresponding measurement section. The correspondence between the measured current intensity and the corresponding measurement section is achieved by, for example, storing the position coordinates of the measurement section on the sun-facing side of the silicon solar cell for the corresponding current intensity.
在该第一测量步骤之后的处理步骤中,用电压源和接触装置施加一个反向于硅太阳能电池的正向的小于硅太阳能电池的击穿电压的电压。当施加这个电压时,在硅太阳能电池的面向太阳的一侧的范围内对已在测量步骤中应用的点光源进行导引,其中对该面向太阳的一侧的分区的处理局部进行照射。通过照射,在相应分区内通过感应产生测量电流。这个电流就该局部而言具有200A/cm2至20000A/cm2的电流密度且为时10ns至10ms地作用于该分区。在这个参数范围内,通过点光源相对于硅太阳能电池的运动速度、点光源的照射强度以及反向于硅太阳能电池的正向(但相对于击穿电压而言更小)的电压的水平来设定电流强度和作用时间。通过这个处理步骤,硅太阳能电池的接触格与发射极层之间的欧姆接触特性特别是在处理步骤之前在接触格与发射极层间具有高接触电阻的区域内得到明显改善。In the processing step following the first measurement step, a voltage lower than the breakdown voltage of the silicon solar cell, reversed from the forward direction, is applied using a voltage source and a contact device. When this voltage is applied, a point light source, already applied in the measurement step, is guided across the sun-facing side of the silicon solar cell, illuminating a localized section of that sun-facing side. Irradiation induces a measurement current within the corresponding section. This current, with a current density of 200 A/ cm² to 20000 A/ cm² for that local area, acts on the section for 10 ns to 10 ms. Within this parameter range, the current intensity and duration are set by the movement speed of the point light source relative to the silicon solar cell, the irradiation intensity of the point light source, and the level of the voltage reversed from the forward direction (but lower than the breakdown voltage) of the silicon solar cell. Through this processing step, the ohmic contact characteristics between the contact grid and the emitter layer of the silicon solar cell are significantly improved, particularly in areas with high contact resistance before the processing step.
在该处理步骤之后,实施类似于第一测量步骤的另一第二测量步骤。优选地,在此同样在与第一测量步骤相同的电压和照射强度参数下再次检测测量电流的电流强度,并且与相应测量局部对应地存储。针对每个测量局部,现仅存在一个处理步骤前的测量电流的强度值,和一个处理步骤后的测量电流的强度值。由相应测量电流的值的变化得到接触格与发射极层之间的欧姆接触特性的改善的空间分辨的量化。同样以与相应测量局部对应地存储由测量电流计算出的变化。随后,视所得到的具体结果(测量电流的强度变化),可以将硅太阳能电池输往另一处理步骤。随后,在这另一处理步骤中,例如仅对相应的测量局部在测量步骤中尚未达到预设的测量电流变化和/或预设的测量电流目标值的处理局部进行加工。Following this processing step, a second measurement step, similar to the first measurement step, is performed. Preferably, the current intensity of the measurement current is detected again under the same voltage and irradiation intensity parameters as in the first measurement step, and stored corresponding to the respective measurement location. For each measurement location, there is now only one measurement current intensity value before the processing step and one measurement current intensity value after the processing step. The spatially resolved quantification of the improved ohmic contact characteristics between the contact grid and the emitter layer is obtained from the change in the value of the corresponding measurement current. The change calculated from the measurement current is also stored corresponding to the respective measurement location. Subsequently, depending on the specific result obtained (change in the intensity of the measurement current), the silicon solar cell can be sent to another processing step. Subsequently, in this other processing step, for example, only the processing locations where the corresponding measurement location has not yet reached the preset measurement current change and/or the preset measurement current target value in the measurement step are processed.
测量步骤中所施加的电压可以反向于硅太阳能电池的正向且小于硅太阳能电池的击穿电压,或者,测量步骤中所施加的电压可以沿硅太阳能电池的正向定向。The voltage applied in the measurement step can be opposite to the forward direction of the silicon solar cell and less than the breakdown voltage of the silicon solar cell, or the voltage applied in the measurement step can be oriented along the forward direction of the silicon solar cell.
第二实施例:Second embodiment:
与第一实施例类似地实施测量步骤。但不同之处在于,在处理步骤中,根据第一测量步骤中检测到的测量电流的电流强度对反向于正向的电压和点光源的照射强度的参数进行调整。在处理步骤中,以比测量电流的电流强度已较高的区域更强的处理电流强度和/或更长的处理电流作用时间来加工在第一测量步骤中测量电流的电流强度较低的区域。可以通过提高反向于正向的电压和/或提高点光源的照射强度来增大处理电流。通过点光源在相应的处理局部上的停留时长来控制处理电流的作用时间的延长。The measurement steps are performed similarly to the first embodiment. However, the difference lies in the processing step, where the parameters of the reverse-current voltage and the illumination intensity of the point light source are adjusted based on the current intensity of the measured current detected in the first measurement step. In the processing step, regions with lower measured current intensities in the first measurement step are processed with a stronger processing current intensity and/or a longer processing current duration than regions where the measured current intensity is already higher. The processing current can be increased by increasing the reverse-current voltage and/or increasing the illumination intensity of the point light source. The extension of the processing current duration is controlled by the dwell time of the point light source on the corresponding processing area.
第三实施例:Third embodiment:
在此同样在测量步骤中检测照射测量局部时的测量电流,并且相应地实施处理步骤。此外,在第二测量步骤中,在照射测量局部的至少第一部分之前和/或之后使得硅太阳能电池的面向太阳的一侧保持不被照射,并且通过接触装置在接触格与背触点之间用电压源施加一个反向于正向的小于硅太阳能电池的击穿电压的电压,从而在施加电压时用电流表对硅太阳能电池的反向电流进行检测。随后,与相应测量局部对应地存储这个反向电流。在此情形下,可以将相应的反向电流用作可能因处理步骤而对硅太阳能电池造成的损伤的特性值。为此,将测得的被测量的测量局部的反向电流与参考反向电流进行对比,该参考反向电流已从所述方法上游的硅太阳能电池的电表征中获得。这个电表征例如可以指硅太阳能电池的制造工艺中常见的在测定太阳能电池效率时记录IU特性曲线。有利地,在测量步骤中,在照射所有测量局部之前或之后测量反向电流。Similarly, in this measurement step, the measurement current when the measurement area is irradiated is detected, and the processing steps are performed accordingly. Furthermore, in the second measurement step, before and/or after irradiating at least a first portion of the measurement area, the sun-facing side of the silicon solar cell is kept unirradiated, and a voltage less than the breakdown voltage of the silicon solar cell is applied between the contact grid and the back contact using a voltage source, in the reverse direction of the voltage application. The reverse current of the silicon solar cell is then detected by an ammeter when the voltage is applied. This reverse current is then stored corresponding to the respective measurement area. In this case, the corresponding reverse current can be used as a characteristic value indicating potential damage to the silicon solar cell caused by the processing steps. For this purpose, the measured reverse current of the measured measurement area is compared with a reference reverse current obtained from the electrical characterization of the silicon solar cell upstream of the method. This electrical characterization may, for example, refer to the IU characteristic curve recorded when determining the solar cell efficiency, a process commonly used in the manufacturing process of silicon solar cells. Advantageously, in the measurement step, the reverse current is measured before or after irradiating all measurement areas.
第二测量步骤中测得的反向电流相对于先前测得的参考反向电流的变化用作处理步骤对硅太阳能电池造成的损伤的衡量尺度。如果硅太阳能电池的反向电流在处理步骤之后增大,则可以推断出处理步骤对硅太阳能电池造成损伤。The change in the reverse current measured in the second measurement step relative to the previously measured reference reverse current is used as a measure of the damage caused to the silicon solar cell by the processing step. If the reverse current of the silicon solar cell increases after the processing step, it can be inferred that the processing step has caused damage to the silicon solar cell.
第四实施例:Fourth embodiment:
所述方法的流程类似于第三实施例。但不同之处在于,在第一测量步骤中产生参考反向电流。为此,正如在第二步骤中那样,在照射测量局部的至少第一部分之前和/或之后使得硅太阳能电池的面向太阳的一侧保持不被照射,从而在施加电压时用电流表对硅太阳能电池的反向电流进行检测。在此情形下,第二测量步骤中检测到的反向电流相对于第一测量步骤中检测到的反向电流的变化用作处理步骤对硅太阳能电池造成的可能的损伤的衡量尺度。The procedure of the method is similar to that of the third embodiment. However, the difference lies in that a reference reverse current is generated in the first measurement step. For this purpose, as in the second step, the sun-facing side of the silicon solar cell is kept un-illuminated before and/or after irradiating at least a first portion of the measurement area, thereby detecting the reverse current of the silicon solar cell with an ammeter when a voltage is applied. In this case, the change in the reverse current detected in the second measurement step relative to the reverse current detected in the first measurement step serves as a measure of potential damage to the silicon solar cell caused by the treatment steps.
第五实施例:Fifth embodiment:
除了在测量步骤中检测测量电流和/或反向电流之外或作为替代,同样在处理步骤中针对被照射的处理局部的至少一部分检测处理电流的实际电流强度,并且与相应处理局部对应地存储。当电流在相应分区上的作用时间结束时对电流强度进行检测。针对处理局部检测到的处理电流用作处理步骤所实现的对接触格与发射极层之间的欧姆接触特性的改善的衡量尺度。如果用相同的反向于硅太阳能电池的正向的电压和点光源的照射强度参数来加工处理局部,则由于对相应处理局部的处理结束时电流强度更大,因此,可以看见在接触格与发射极层之间具有更好的欧姆接触特性的区域。针对各处理局部检测到并且存储的处理电流例如在硅太阳能电池的后续处理中用作品质特征。同样可以利用检测到并且存储的处理电流来实施进一步的处理步骤,其中例如在进一步的处理步骤中针对性地再次以更改过的参数加工测得的处理电流较小的区域。更改过的参数在此又指点光源的照射强度和/或照射的作用时间和/或反向于硅太阳能电池的正向的电压的水平。In addition to detecting the measured current and/or reverse current in the measurement step, or as an alternative, the actual current intensity of the processing current is also detected for at least a portion of the irradiated processing area in the processing step, and stored correspondingly for the respective processing area. The current intensity is detected when the current's duration of action on the corresponding section ends. The processing current detected for the processing area is used as a measure of the improvement in ohmic contact characteristics between the contact grid and the emitter layer achieved by the processing step. If the processing area is processed with the same voltage reversed to the forward direction of the silicon solar cell and the same irradiation intensity parameters of the point light source, a region with better ohmic contact characteristics between the contact grid and the emitter layer can be observed because the current intensity is greater at the end of processing for the corresponding processing area. The processing current detected and stored for each processing area is used, for example, as a quality characteristic in subsequent processing of the silicon solar cell. Further processing steps can also be implemented using the detected and stored processing current, where, for example, in a further processing step, the region with the smaller measured processing current is selectively processed again with modified parameters. The modified parameters here refer to the intensity of the point light source and/or the duration of the illumination and/or the level of the voltage reversed to the forward voltage of the silicon solar cell.
第六实施例:Sixth embodiment:
如果不同于第四实施例地,在处理步骤前不实施测量步骤,则同样可以在处理步骤中确定参考反向电流,以与第二测量步骤中测得的反向电流进行对比。为此,在处理步骤中,在照射处理局部之前使得硅太阳能电池的面向太阳的一侧保持不被照射,并且在施加反向于硅太阳能电池的正向的电压时对反向电流进行检测。If, unlike the fourth embodiment, a measurement step is not performed before the processing step, a reference reverse current can still be determined in the processing step for comparison with the reverse current measured in the second measurement step. For this purpose, in the processing step, the sun-facing side of the silicon solar cell is kept un-illuminated before irradiating the processing area, and the reverse current is detected when a voltage reversed from the forward direction of the silicon solar cell is applied.
第七实施例:Seventh embodiment:
不同于前述实施例,可以仅在处理步骤中测量参考反向电流以及加工处理局部后的反向电流。为此,在处理步骤中,在照射处理局部的第一部分之前使得硅太阳能电池的面向太阳的一侧保持不被照射,并且在施加反向于正向的电压时对反向电流进行检测。随后,逐渐照射处理局部的第一部分。当对处理局部的第一部分的照射结束时重新使得硅太阳能电池的面向太阳的一侧保持不被照射,并且再次检测反向电流。在此情形下,照射处理局部的第一部分之前检测到的反向电流的值用作照射处理局部的第一部分之后检测到的反向电流的参考值。Unlike the previous embodiments, the reference reverse current and the reverse current after processing the localized area can be measured only during the processing step. Therefore, in the processing step, the sun-facing side of the silicon solar cell is kept un-illuminated before irradiating the first portion of the processed area, and the reverse current is detected when a voltage reversed from the forward direction is applied. Subsequently, the first portion of the processed area is gradually irradiated. When irradiation of the first portion of the processed area ends, the sun-facing side of the silicon solar cell is again kept un-illuminated, and the reverse current is detected again. In this case, the value of the reverse current detected before irradiating the first portion of the processed area is used as a reference value for the reverse current detected after irradiating the first portion of the processed area.
如果在处理步骤中,在加工处理局部时用点光源例如逐行地扫描硅太阳能电池的面向太阳的一侧,则依次对沿每行布置的处理局部进行照射。照射过每行之后,将点光源断开,或者在接通状态下越过硅太阳能电池的边缘从硅太阳能电池的面向太阳的一侧移开,使得硅太阳能电池的面向太阳的一侧完全不被照射,并且可以在施加反向于正向的电压时对反向电流进行检测。在此情形下,照射一行之后检测到的反向电流用作照射下一行之后产生的反向电流的参考反向电流。由此,甚至能够将硅太阳能电池的可能的损伤与特定行(或处理局部)的加工对应。If, during the processing steps, a point light source is used to scan the sun-facing side of the silicon solar cell row by row during local processing, the processing areas arranged along each row are irradiated sequentially. After each row is irradiated, the point light source is either turned off or, while still on, moved away from the sun-facing side of the silicon solar cell beyond its edge, so that the sun-facing side of the silicon solar cell is completely unirradiated, and reverse current can be detected when a voltage reversed from the forward direction is applied. In this case, the reverse current detected after irradiating one row is used as a reference reverse current for the reverse current generated after irradiating the next row. Thus, it is even possible to correlate potential damage to the silicon solar cell with the processing of a specific row (or processing area).
第八实施例:Eighth embodiment:
与第七实施例类似地实施加工。此外,将照射一行之前与之后产生的反向电流的变化用作加工步骤中照射下一行时设定参数(点光源的照射强度、照射的作用时间、反向于正向的电压的水平)的调节变量。如果识别到反向电流增大,则在照射下一行时改变参数(例如照射的作用时间),从而防止反向电流进一步增大。The processing is performed similarly to that in the seventh embodiment. Furthermore, the change in reverse current generated before and after irradiating one row is used as an adjustment variable for the parameters (irradiation intensity of the point light source, irradiation duration, and the level of the reverse voltage) set when irradiating the next row in the processing step. If an increase in reverse current is detected, the parameters (e.g., the irradiation duration) are changed when irradiating the next row to prevent further increase in reverse current.
在前述所有实施例中,作为另一实施方案,在测量步骤或处理步骤中检测反向电流时,只要反向于正向的电压始终小于硅太阳能电池的击穿电压,也可以改变这个反向于正向的电压。由此,针对预设的电压分别测定一个反向电流并且与相应测量局部或处理局部对应地存储。In all the foregoing embodiments, as another implementation, when detecting the reverse current in the measurement or processing step, this reverse voltage can be changed as long as it is always less than the breakdown voltage of the silicon solar cell. Thus, a reverse current is measured for each preset voltage and stored corresponding to the corresponding measurement or processing location.
第九实施例:Ninth embodiment:
将处理步骤中检测到的处理局部的处理电流(参阅第五实施例)用于在加工后续的处理局部时调节参数。在此过程中,如此地实施调节,从而将加工一个处理局部时检测到的处理电流与参考值进行对比。如果检测到的处理电流小于这个参考值,则可能表示接触格与发射极层之间的欧姆接触特性的改善还不充分。因此,在下一处理局部中,相应地对照射这个处理局部时的参数进行调整。The processing current detected in the processing step (see fifth embodiment) is used to adjust parameters when processing subsequent processing areas. During this process, adjustments are performed such that the processing current detected when processing a processing area is compared with a reference value. If the detected processing current is less than this reference value, it may indicate that the improvement in the ohmic contact characteristics between the contact grid and the emitter layer is insufficient. Therefore, in the next processing area, the parameters for irradiating this processing area are adjusted accordingly.
第十实施例:Tenth embodiment:
不同于当电流在相应分区上的作用时间结束时对电流强度进行检测的第五实施例,在此,当照射处理局部时,针对每个处理局部用电流表首先检测第一电流强度,随后检测第二电流强度,并且与处理局部对应地存储这两个电流强度。将电流强度的变化(梯度)用作接触格与发射极层之间的欧姆接触特性的改善的衡量尺度。电流强度在照射处理局部期间的增大表明欧姆接触特性得到改善。电流强度仅小幅增大或未增大表明欧姆接触特性仅得到小幅改善或未得到改善。因此,将电流强度在照射处理局部期间的变化用于调节至少一个后续处理局部的参数(点光源的照射强度、照射的作用时间、反向于正向的电压的水平)。除了将电流强度的梯度用作调节变量之外,还将这个梯度与相应处理局部对应地存储。Unlike the fifth embodiment, which detects the current intensity when the current's duration of action on the corresponding partition ends, here, when irradiating a processing area, a first current intensity is first detected using an ammeter for each processing area, followed by a second current intensity, and these two current intensities are stored corresponding to the processing area. The change in current intensity (gradient) is used as a measure of the improvement in the ohmic contact characteristics between the contact grid and the emitter layer. An increase in current intensity during the irradiation of a processing area indicates an improvement in ohmic contact characteristics. A small increase or no increase in current intensity indicates only a small improvement or no improvement in ohmic contact characteristics. Therefore, the change in current intensity during the irradiation of a processing area is used to adjust parameters of at least one subsequent processing area (irradiation intensity of the point light source, irradiation duration, and the level of the reverse and forward voltages). In addition to using the gradient of current intensity as an adjustment variable, this gradient is also stored corresponding to the corresponding processing area.
在所列的所有实施例中,可选地,在处理步骤和/或测量步骤中,当照射处理局部或测量局部的至少一部分时,通过测量检测从硅太阳能电池的面向太阳的一侧反射的照射分量,并且与相应局部对应地存储。此外,可选地,当检测反射分量时,改变点光源发出的光辐射的波长,其中检测预设波长的反射分量,并且与相应局部对应地存储。当检测测量电流和/或处理电流的电流强度时,可选地,同样改变点光源发出的光辐射的波长,其中在此同样检测预设波长的测量电流和/或处理电流的电流强度,并且与相应局部对应地存储。In all the listed embodiments, optionally, during the processing and/or measurement steps, when at least a portion of the processing or measurement area is irradiated, the irradiation component reflected from the sun-facing side of the silicon solar cell is detected by measurement and stored corresponding to the respective area. Furthermore, optionally, when detecting the reflection component, the wavelength of the light radiation emitted by the point light source is changed, wherein a preset wavelength of reflection component is detected and stored corresponding to the respective area. When detecting the current intensity of the measurement current and/or processing current, optionally, the wavelength of the light radiation emitted by the point light source is also changed, wherein a preset wavelength of measurement current and/or processing current is also detected and stored corresponding to the respective area.
Claims (21)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102020002335.5 | 2020-04-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HK40086355A true HK40086355A (en) | 2023-08-18 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7989729B1 (en) | Detecting and repairing defects of photovoltaic devices | |
| JP3647209B2 (en) | Measuring method of solar cell characteristics | |
| JP4034500B2 (en) | Semiconductor device inspection method and inspection apparatus, and semiconductor device manufacturing method using the same | |
| CN102575987B (en) | Method for measuring a semiconductor structure, which is a solar cell or a precursor of a solar cell | |
| JP5481767B2 (en) | Method and apparatus for detecting the location of manufacturing errors in semiconductor component parts | |
| US20250351614A1 (en) | Method for improving the ohmic contact behavior between a contact grid and an emitter layer of a silicon solar cell | |
| JPH0744209B2 (en) | Method and apparatus for determining minority carrier diffusion length from linear constant photon flux photovoltage measurements | |
| JP2006040991A (en) | Semiconductor device evaluation method and manufacturing method | |
| JP2017055657A (en) | Solar cell module inspection device and inspection method thereof | |
| Dirnberger | Photovoltaic module measurement and characterization in the laboratory | |
| CN102460126A (en) | Material or device characterisation with non-homogeneous photoexcitation | |
| HK40086355A (en) | Method for improving the ohmic contact behavior between a contact grid and an emitter layer of a silicon solar cell | |
| JP5579829B2 (en) | Electrical and optoelectric properties of large area semiconductor devices. | |
| KR101757104B1 (en) | Photoelectric conversion element evaluation apparatus | |
| CN108508333B (en) | Reliability evaluation method of back-end dielectric material | |
| TWI906285B (en) | Method for improving the ohmic contact behavior between a contact grid and an emitter layer of a silicon solar cell | |
| JP4233330B2 (en) | Photovoltaic device inspection method | |
| JP2015076583A (en) | Photoelectric conversion element evaluation device | |
| JP2001077163A (en) | Defect detection method | |
| JP2009252995A (en) | Semiconductor inspection method | |
| Zhu et al. | Applications of DMD-based inhomogeneous illumination photoluminescence imaging for silicon wafers and solar cells | |
| JP5582203B2 (en) | Voltage / current characteristic measuring method, voltage / current characteristic measuring apparatus, and solar simulator | |
| CN117091489B (en) | Device and method for detecting thickness of top film of composite structure | |
| CN117723556A (en) | Defect analysis device and defect analysis method | |
| CN120834028A (en) | A rapid UV testing method for solar cells |