HK1199245A1 - Process for the preparation of 4-amino-3-chloro-5-fluoro-6- (substituted) picolinates 4--3--5--6-()-2- - Google Patents
Process for the preparation of 4-amino-3-chloro-5-fluoro-6- (substituted) picolinates 4--3--5--6-()-2-Info
- Publication number
- HK1199245A1 HK1199245A1 HK14112715.3A HK14112715A HK1199245A1 HK 1199245 A1 HK1199245 A1 HK 1199245A1 HK 14112715 A HK14112715 A HK 14112715A HK 1199245 A1 HK1199245 A1 HK 1199245A1
- Authority
- HK
- Hong Kong
- Prior art keywords
- picolinates
- fluoro
- chloro
- amino
- substituted
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/84—Nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161435966P | 2011-01-25 | 2011-01-25 | |
| PCT/US2012/022285 WO2012103041A2 (en) | 2011-01-25 | 2012-01-24 | Process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted) picolinates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HK1199245A1 true HK1199245A1 (en) | 2015-06-26 |
Family
ID=46544648
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HK16100734.3A HK1213875A1 (zh) | 2011-01-25 | 2014-12-18 | -氨基- -氯- -氟- 取代的 吡啶- -甲酸酯的製備方法 |
| HK14112715.3A HK1199245A1 (en) | 2011-01-25 | 2014-12-18 | Process for the preparation of 4-amino-3-chloro-5-fluoro-6- (substituted) picolinates 4--3--5--6-()-2- |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HK16100734.3A HK1213875A1 (zh) | 2011-01-25 | 2014-12-18 | -氨基- -氯- -氟- 取代的 吡啶- -甲酸酯的製備方法 |
Country Status (20)
| Country | Link |
|---|---|
| US (3) | US20120190857A1 (he) |
| EP (1) | EP2668163B1 (he) |
| JP (1) | JP5739018B2 (he) |
| KR (1) | KR101537879B1 (he) |
| CN (2) | CN104788368B (he) |
| AR (1) | AR085022A1 (he) |
| AU (1) | AU2012209277B2 (he) |
| BR (2) | BR102012001636A2 (he) |
| CA (1) | CA2825475C (he) |
| CO (1) | CO6731125A2 (he) |
| HK (2) | HK1213875A1 (he) |
| IL (1) | IL227646A (he) |
| MX (1) | MX342328B (he) |
| PL (1) | PL2668163T3 (he) |
| RU (1) | RU2545021C1 (he) |
| SG (1) | SG192093A1 (he) |
| TW (1) | TWI592401B (he) |
| UA (1) | UA106945C2 (he) |
| WO (1) | WO2012103041A2 (he) |
| ZA (1) | ZA201305577B (he) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI592401B (zh) | 2011-01-25 | 2017-07-21 | 陶氏農業科學公司 | 用於製備４－胺基－３－氯－５－氟－６－（經取代的）吡啶甲酸酯的方法（一） |
| US9149038B2 (en) | 2013-03-15 | 2015-10-06 | Dow Agrosciences Llc | 4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides |
| US9113629B2 (en) | 2013-03-15 | 2015-08-25 | Dow Agrosciences Llc | 4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides |
| US9637505B2 (en) | 2013-03-15 | 2017-05-02 | Dow Agrosciences Llc | 4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides |
| JP2016514138A (ja) | 2013-03-15 | 2016-05-19 | ダウ アグロサイエンシィズ エルエルシー | 除草剤としての新規な４−アミノピリジンカルボキシレートおよび６−アミノピリミジンカルボキシレート |
| TW201609652A (zh) | 2013-11-12 | 2016-03-16 | 陶氏農業科學公司 | 用於氟化化合物之過程（三） |
| TW201609651A (zh) | 2013-11-12 | 2016-03-16 | 陶氏農業科學公司 | 用於氟化化合物之過程（一） |
| BR102014028164A2 (pt) * | 2013-11-12 | 2015-09-08 | Dow Agrosciences Llc | processo para fluoração de compostos |
| TWI726900B (zh) | 2015-08-04 | 2021-05-11 | 美商陶氏農業科學公司 | 用於氟化化合物之過程 |
| CA3023935A1 (en) | 2016-05-19 | 2017-11-23 | Dow Agrosciences Llc | Synthesis of 6-aryl-4-aminopicolinates and 2-aryl-6-aminopyrimidine-4-carboxylates by direct suzuki coupling |
| CN107954925A (zh) * | 2016-10-18 | 2018-04-24 | 内蒙古佳瑞米精细化工有限公司 | 一种2,3-二氯-5-三氟甲基吡啶前杂的去除方法 |
| JP2022503740A (ja) | 2018-09-19 | 2022-01-12 | コルテバ アグリサイエンス エルエルシー | ピクロラムのハロゲン類似体の調製 |
| CN115298167A (zh) | 2020-03-18 | 2022-11-04 | 科迪华农业科技有限责任公司 | 6-芳基-4-氨基吡啶甲酸酯的改进合成 |
| US20230357155A1 (en) | 2020-03-18 | 2023-11-09 | Corteva Agriscience Llc | Improved synthesis of 4-amino-6-(heterocyclic)picolinates |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3285925A (en) * | 1962-03-06 | 1966-11-15 | Dow Chemical Co | Amino-trichloropicolinic acid compounds |
| US3629424A (en) * | 1967-12-26 | 1971-12-21 | Dow Chemical Co | Cyanofluoropyridines and fungicidal compositions and methods for using the same |
| US3803159A (en) * | 1967-12-26 | 1974-04-09 | Dow Chemical Co | Fluorine containing cyanopyridines |
| US4336384A (en) * | 1981-04-23 | 1982-06-22 | The Dow Chemical Company | Preparation of 4-amino-3,5,6-trichloropicolinic acid |
| US5807804A (en) * | 1996-02-22 | 1998-09-15 | American Cyanamid Company | Substituted pyridine herbicidal agents |
| FR2803592A1 (fr) * | 2000-01-06 | 2001-07-13 | Aventis Cropscience Sa | Nouveaux derives de l'acide 3-hydroxypicolinique, leur procede de preparation et compositions fongicides les contenant. |
| EP1498413B1 (en) * | 2000-01-14 | 2011-08-31 | Dow AgroSciences LLC | 4-Aminopicolinates and their use as herbicides |
| US6297197B1 (en) | 2000-01-14 | 2001-10-02 | Dow Agrosciences Llc | 4-aminopicolinates and their use as herbicides |
| AR037228A1 (es) * | 2001-07-30 | 2004-11-03 | Dow Agrosciences Llc | Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada |
| UA82358C2 (uk) * | 2003-04-02 | 2008-04-10 | Дау Агросайенсиз Ллс | 6-алкіл або алкеніл-4-амінопіколінати гербіцидна композиція, спосіб боротьби з небажаною рослинністю |
| AU2007204825B2 (en) | 2006-01-13 | 2011-07-14 | Corteva Agriscience Llc | 6-(poly-substituted aryl)-4-aminopicolinates and their use as herbicides |
| AR068710A1 (es) * | 2007-10-02 | 2009-12-02 | Dow Agrosciences Llc | Acidos 2-substituido-6-amino-5-alquilo, alquenilo o alquinilo-4-pirimidinacarboxilico y acidos picolinicos 6-substituido -4-amino-3-alquilo alquenilo o alquinilo y su uso como herbicidas |
| US8252938B2 (en) * | 2009-06-08 | 2012-08-28 | Dow Agrosciences, Llc. | Process for the preparation of 6-(aryl)-4-aminopicolinates |
| GB0910766D0 (en) * | 2009-06-22 | 2009-08-05 | Syngenta Ltd | Chemical compounds |
| GB201008290D0 (en) * | 2010-05-18 | 2010-06-30 | Syngenta Ltd | Chemical compounds |
| TWI592401B (zh) | 2011-01-25 | 2017-07-21 | 陶氏農業科學公司 | 用於製備４－胺基－３－氯－５－氟－６－（經取代的）吡啶甲酸酯的方法（一） |
-
2012
- 2012-01-20 TW TW101102582A patent/TWI592401B/zh not_active IP Right Cessation
- 2012-01-24 BR BRBR102012001636-2A patent/BR102012001636A2/pt not_active Application Discontinuation
- 2012-01-24 JP JP2013551275A patent/JP5739018B2/ja not_active Expired - Fee Related
- 2012-01-24 US US13/356,669 patent/US20120190857A1/en not_active Abandoned
- 2012-01-24 WO PCT/US2012/022285 patent/WO2012103041A2/en active Application Filing
- 2012-01-24 SG SG2013056023A patent/SG192093A1/en unknown
- 2012-01-24 RU RU2013139300/04A patent/RU2545021C1/ru not_active IP Right Cessation
- 2012-01-24 CA CA2825475A patent/CA2825475C/en not_active Expired - Fee Related
- 2012-01-24 MX MX2013008603A patent/MX342328B/es active IP Right Grant
- 2012-01-24 CN CN201510105205.0A patent/CN104788368B/zh not_active Expired - Fee Related
- 2012-01-24 BR BR112013019025A patent/BR112013019025A2/pt not_active Application Discontinuation
- 2012-01-24 CN CN201280014336.2A patent/CN103874685B/zh not_active Expired - Fee Related
- 2012-01-24 EP EP12739865.9A patent/EP2668163B1/en not_active Not-in-force
- 2012-01-24 PL PL12739865T patent/PL2668163T3/pl unknown
- 2012-01-24 KR KR1020137021995A patent/KR101537879B1/ko active IP Right Grant
- 2012-01-24 UA UAA201310403A patent/UA106945C2/uk unknown
- 2012-01-24 AR ARP120100234A patent/AR085022A1/es unknown
- 2012-01-24 AU AU2012209277A patent/AU2012209277B2/en not_active Ceased
-
2013
- 2013-07-23 ZA ZA2013/05577A patent/ZA201305577B/en unknown
- 2013-07-24 CO CO13175298A patent/CO6731125A2/es unknown
- 2013-07-24 IL IL227646A patent/IL227646A/he active IP Right Grant
-
2014
- 2014-02-04 US US14/171,791 patent/US9067890B2/en not_active Expired - Fee Related
- 2014-12-18 HK HK16100734.3A patent/HK1213875A1/zh unknown
- 2014-12-18 HK HK14112715.3A patent/HK1199245A1/xx unknown
-
2015
- 2015-06-09 US US14/734,347 patent/US9452984B2/en not_active Expired - Fee Related
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