GR1007843B - Προσροφητικο υλικο για την απομακρυνση φωσφορου και αμμωνιας - Google Patents

Προσροφητικο υλικο για την απομακρυνση φωσφορου και αμμωνιας

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Publication number
GR1007843B
GR1007843B GR20110100702A GR20110100702A GR1007843B GR 1007843 B GR1007843 B GR 1007843B GR 20110100702 A GR20110100702 A GR 20110100702A GR 20110100702 A GR20110100702 A GR 20110100702A GR 1007843 B GR1007843 B GR 1007843B
Authority
GR
Greece
Prior art keywords
behumeca
ability
bentonite
ions
natural
Prior art date
Application number
GR20110100702A
Other languages
English (en)
Inventor
Ιωαννης Γεωργιου Δεληγιαννακης
Ιεροθεος Ζαχαρια Ζαχαριας
Μιλτιαδης Γεωργιου Ζαμπαρας
Μαριος Βασιλειου Δροσος
Original Assignee
Ιωαννης Γεωργιου Δεληγιαννακης
Ιεροθεος Ζαχαρια Ζαχαριας
Μιλτιαδης Γεωργιου Ζαμπαρας
Μαριος Βασιλειου Δροσος
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ιωαννης Γεωργιου Δεληγιαννακης, Ιεροθεος Ζαχαρια Ζαχαριας, Μιλτιαδης Γεωργιου Ζαμπαρας, Μαριος Βασιλειου Δροσος filed Critical Ιωαννης Γεωργιου Δεληγιαννακης
Priority to GR20110100702A priority Critical patent/GR1007843B/el
Publication of GR1007843B publication Critical patent/GR1007843B/el

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229—Compounds of Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233—Compounds of Cu, Ag, Au
    • B01J20/0237—Compounds of Cu
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/105—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/16—Nitrogen compounds, e.g. ammonia

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Η παρούσα εφεύρεση αφορά ένα νέο υλικό "ΜΠΕ.ΧΟ.ΜΕΚΑ" (BEPHOS) (5) το οποίο παρασκευάζεται από φυσικές πρώτες ύλες: μπεντονίτη (1), ιόντα Fe3+ και Cu2+ (2) και χουμικό οξύ (3). Όλα τα συστατικά είναι ενσωματωμένα σε μία ενιαία στερεά δομή η οποία έχει τη μορφή σκόνης. Η σκόνη είναι διαλυτή σε νερό σε ρΗ 3-10. Το υλικό έχει ικανότητα εκλεκτικής δέσμευσης φωσφορικών και αμμωνιακών ιόντων διαλυμένα σε φυσικά νερά. Η απόδοση υλικού ΜΠΕ.ΧΟ.ΜΕΚΑ στην δέσμευση φωσφορικών του είναι 180 τοις εκατό καλύτερη από το εμπορικό Phoslock και 1600 τοις εκατό καλύτερη από την ικανότητα του καθαρού μπεντονίτη. Επιπρόσθετα το υλικό ΜΠΕ.ΧΟ.ΜΕΚΑ (5) παρουσιάζει ικανότητα προσρόφησης αμμωνιακών που ανέρχεται σε ποσοστό περίπου 75 τοις εκατό σε υδατικά διαλύματα με ρΗ 5-7. Η ικανότητα του φυσικού μπεντονίτη και του εμπορικού προϊόντος Phoslock στην προσρόφηση αμμωνιακών ιόντων παρουσιάζεται σχεδόν μηδενική.
GR20110100702A 2011-12-13 2011-12-13 Προσροφητικο υλικο για την απομακρυνση φωσφορου και αμμωνιας GR1007843B (el)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GR20110100702A GR1007843B (el) 2011-12-13 2011-12-13 Προσροφητικο υλικο για την απομακρυνση φωσφορου και αμμωνιας

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GR20110100702A GR1007843B (el) 2011-12-13 2011-12-13 Προσροφητικο υλικο για την απομακρυνση φωσφορου και αμμωνιας

Publications (1)

Publication Number Publication Date
GR1007843B true GR1007843B (el) 2013-02-27

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Country Status (1)

Country Link
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103831134A (zh) * 2014-03-21 2014-06-04 中国科学院新疆理化技术研究所 一种改性膨润土型固相光催化剂制备方法及其用途
CN110327876A (zh) * 2019-07-29 2019-10-15 福建海峡环保集团股份有限公司 一种应用于含磷废水处理的吸附材料的制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3872002A (en) * 1973-03-29 1975-03-18 Georesources Inc Process for extracting phosphate from solutions
EP0504131A1 (de) * 1991-03-08 1992-09-16 TECHFORM ENGINEERING GmbH Verringerung von bei industriellen Prozessen anfallenden Schadstoffen
DE4406808A1 (de) * 1994-03-02 1995-09-07 Umweltagentur Beratungs Forsch Oberflächenmodifizierter Bentonit der mit einem "Polyhuminsacculus" umgeben ist und dessen Verwendung als Adsorptions- sowie Dichtmittel für Sanierungs- und Sicherungsverfahren im Umweltbereich
US20040007533A1 (en) * 2001-05-21 2004-01-15 Yoshitaka Hasegawa Process and apparatus for treating nitrogen compound containing water
EP1736236A1 (en) * 2004-07-26 2006-12-27 Kurita Water Industries Ltd. Anion adsorbent, process for producing the same and method of water treatment
WO2009063456A1 (en) * 2007-11-12 2009-05-22 Technion Research And Development Foundation Ltd Method for adsorption of phosphate contaminants from water solutions and its recovery
US20110259826A1 (en) * 2008-12-15 2011-10-27 Sud-Chemie Ag Method for processing waste water loaded with nitrogen-containing compounds

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3872002A (en) * 1973-03-29 1975-03-18 Georesources Inc Process for extracting phosphate from solutions
EP0504131A1 (de) * 1991-03-08 1992-09-16 TECHFORM ENGINEERING GmbH Verringerung von bei industriellen Prozessen anfallenden Schadstoffen
DE4406808A1 (de) * 1994-03-02 1995-09-07 Umweltagentur Beratungs Forsch Oberflächenmodifizierter Bentonit der mit einem "Polyhuminsacculus" umgeben ist und dessen Verwendung als Adsorptions- sowie Dichtmittel für Sanierungs- und Sicherungsverfahren im Umweltbereich
US20040007533A1 (en) * 2001-05-21 2004-01-15 Yoshitaka Hasegawa Process and apparatus for treating nitrogen compound containing water
EP1736236A1 (en) * 2004-07-26 2006-12-27 Kurita Water Industries Ltd. Anion adsorbent, process for producing the same and method of water treatment
WO2009063456A1 (en) * 2007-11-12 2009-05-22 Technion Research And Development Foundation Ltd Method for adsorption of phosphate contaminants from water solutions and its recovery
US20110259826A1 (en) * 2008-12-15 2011-10-27 Sud-Chemie Ag Method for processing waste water loaded with nitrogen-containing compounds

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
M. ZAMPARAS ET AL: "Removal of phosphate from natural waters using modified bentonites", PROCEEDINGS OF THE 3RD INTERNATION CEMEPE & SECOTOX CONFERENCE, 19 June 2011 (2011-06-19), Skiathos, Greece, pages 1011 - 1016, XP055039643, ISBN: 978-9-60-686543-5, Retrieved from the Internet <URL:http://www.srcosmos.gr/srcosmos/showpub.aspx?aa=15787> [retrieved on 20121001] *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103831134A (zh) * 2014-03-21 2014-06-04 中国科学院新疆理化技术研究所 一种改性膨润土型固相光催化剂制备方法及其用途
CN110327876A (zh) * 2019-07-29 2019-10-15 福建海峡环保集团股份有限公司 一种应用于含磷废水处理的吸附材料的制备方法

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Effective date: 20130327