GB999587A - Cellulose ethers - Google Patents
Cellulose ethersInfo
- Publication number
- GB999587A GB999587A GB364262A GB364262A GB999587A GB 999587 A GB999587 A GB 999587A GB 364262 A GB364262 A GB 364262A GB 364262 A GB364262 A GB 364262A GB 999587 A GB999587 A GB 999587A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cellulose
- ether
- solution
- precipitated
- shear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/02—Synthetic cellulose fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/02—Alkyl or cycloalkyl ethers
- C08B11/04—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals
- C08B11/14—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals with nitrogen-containing groups
- C08B11/155—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals with nitrogen-containing groups with cyano groups, e.g. cyanoalkyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B13/00—Preparation of cellulose ether-esters
- C08B13/02—Cellulose ether xanthates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B16/00—Regeneration of cellulose
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
<PICT:0999587/C3/1> A process for preparing sheet-forming particles, fibres, films and other shaped structures of a cellulose ether, comprises forming a cellulose ether, dissolving the ether, introducing the ether into an acidic regeneration bath to precipitate the ether as a shaped structure, and treating the shaped structure with an aqueous salt solution containing a neutral salt and a basic salt, the concentration of the neutral salt being greater than that of the basic salt. The cellulose ether may be prepared by treating alkali cellulose, having a caustic content of less than 30% by weight, at 5-45 DEG C. in the solid state with 0.5-3.0 moles of etherifying agent per mole of anhydroglucose. The product may be dissolved in dilute caustic soda. The cellulose may be subjected to xanthation before, after, or simultaneously with etherification. The etherified or etherified and xanthated product may be aged, before precipitation and regeneration. The regenerating bath may contain sulphuric acid and sodium sulphate, or sulphuric acid, sodium sulphate, and zinc sulphate. The salt solution with which the precipitated shaped structure is treated, may contain a buffer, e.g. disodium hydrogen phosphate in presence of sodium sulphate. The treating solution, which neutralizes the acid in the shaped structure, may be maintained at pH 5-6. In one embodiment, fibres or films are formed by extrusion of the cellulose ether solution into the acid regenerating bath. In another embodiment, shear-precipitated sheet-forming particles are formed by precipitating the cellulose ether solution under such conditions of shear and coagulation that a "total shear value," R1s, of 3 t0 10,000 is provided. The "total shear value" is defined by the formula <FORM:0999587/C3/1> wherein Vp and Vs are viscosities in poises, of the precipitant and solution respectively, measured at their respective temperatures just prior to combining to form the precipitate; t is the time in micro-seconds during which the precipitate is deformable, and Rp is defined by alternative expressions related to the characteristics of the stirring device used, the particular expression depending upon whether the Reynold's number of the system is not more than 3350 (laminar flow) or exceeds 3350 (turbulent flow). If a tube precipitator (Fig. 14) is used instead of a stirring device, modified expressions for R1s are operative, related also to rate of flow of precipitating liquid and to the radius of the tube. The ethers to be precipitated may have D.S 0.1-0.7, and the properties of the precipitated structure may be modified by incorporating an additive, such as synthetic or natural fibres, dyes, pigments abrasives, resins, lubricants or antioxidants into the cellulose ether solution or into the regenerating bath. Many such additives are specified. The shaped structures, which are highly swellable in water, may be obtained in deswollen form by displacement of water by acetone, or by treatment with a strong salt solution. Examples describe the preparation of solutions of cyanoethyl cellulose xanthate, shear precipitation of cyanoethyl particles therefrom in baths of specified compositions, and extrusion of the solution into filaments; the preparation and extrusion of hydroxypropyl cellulose, carboxymethyl cellulose and cyanoethyl cellulose; and the extrusion into filaments of hydroxyethyl cellulose. Other cellulose ethers, mixed ethers, and ether-esters are specified. The products have a water adsorbency of at least 7 grams per gram. Shear precipitated particles may be formed into sheets by conventional paper-making techniques. Specification 868,651 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB364262A GB999587A (en) | 1962-01-31 | 1962-01-31 | Cellulose ethers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB364262A GB999587A (en) | 1962-01-31 | 1962-01-31 | Cellulose ethers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB999587A true GB999587A (en) | 1965-07-28 |
Family
ID=9762181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB364262A Expired GB999587A (en) | 1962-01-31 | 1962-01-31 | Cellulose ethers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB999587A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2493491A (en) * | 2011-05-20 | 2013-02-13 | Innovia Films Ltd | Process for making cellulose articles |
GB2493489A (en) * | 2011-05-20 | 2013-02-13 | Innovia Films Ltd | Process for making cellulose film |
-
1962
- 1962-01-31 GB GB364262A patent/GB999587A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2493491A (en) * | 2011-05-20 | 2013-02-13 | Innovia Films Ltd | Process for making cellulose articles |
GB2493489A (en) * | 2011-05-20 | 2013-02-13 | Innovia Films Ltd | Process for making cellulose film |
GB2493491B (en) * | 2011-05-20 | 2016-01-20 | Innovia Films Ltd | Process |
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