GB997626A - Preparation of a water-miscible varnish composition - Google Patents
Preparation of a water-miscible varnish compositionInfo
- Publication number
- GB997626A GB997626A GB2349563A GB2349563A GB997626A GB 997626 A GB997626 A GB 997626A GB 2349563 A GB2349563 A GB 2349563A GB 2349563 A GB2349563 A GB 2349563A GB 997626 A GB997626 A GB 997626A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- amine
- varnish
- water
- coupling solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 239000002966 varnish Substances 0.000 title abstract 5
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 4
- 230000008878 coupling Effects 0.000 abstract 3
- 238000010168 coupling process Methods 0.000 abstract 3
- 238000005859 coupling reaction Methods 0.000 abstract 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 3
- 238000001035 drying Methods 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000000539 dimer Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 abstract 1
- 150000001253 acrylic acids Chemical class 0.000 abstract 1
- 238000007605 air drying Methods 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000001680 brushing effect Effects 0.000 abstract 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- -1 ferrous metals Chemical class 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000005504 petroleum refining Methods 0.000 abstract 1
- 150000002989 phenols Polymers 0.000 abstract 1
- 239000011505 plaster Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 238000007761 roller coating Methods 0.000 abstract 1
- 235000010199 sorbic acid Nutrition 0.000 abstract 1
- 150000003398 sorbic acids Chemical class 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F7/00—Chemical modification of drying oils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D155/00—Coating compositions based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C09D123/00 - C09D153/00
- C09D155/04—Polyadducts obtained by the diene synthesis
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/005—Drying oils
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
A cyclopentadiene modified drying oil varnish resin is reacted with an alpha beta unsaturated ethylenic carboxylic acid in an amount sufficient to increase the acid number of the varnish resin to within the range of 30-125, the said reaction being carried out at a temperature of 220 DEG to 280 DEG C. and the acid reaction product is then neutralized with ammonia or a strongly basic organic amine and incorporated with an organic coupling solvent, miscible with water, in which the product is soluble to form a drying oil varnish composition capable of dilution with water. The cyclopentadiene used to modify the oil may be mixed with dimers, polymers, alkyl homologues and their dimers and other compounds such as styrene; it may be the mixture of such compounds obtained in petroleum refining. The unsaturated acid preferably has from 4-9 carbon atoms in the molecule and may be maleic, fumaric, itaconic, citraconic, crotonic, acrylic or sorbic acids, monobutyl maleate, or the corresponding anhydrides. The amine may be a volatile amine if the varnish is to be air-drying or a non-volatile one for baking finishes. The coupling solvent may be a glycol, glycol ether, alcohol, ester, ether, thioalcohol, ketone, polyoxyethylated phenol or rosin acid, or mixtures thereof. The compositions may also contain pigments. Specification 907,782 is referred to.ALSO:Surfaces of wood, metals especially ferrous metals, glass, masonry or plaster board are coated by brushing, dipping, spraying or roller-coating with an aqueous solution of a composition comprising the reaction product of a cyclopentadiene modified drying oil with an unsaturated acid (e.g. maleic acid) neutralized with ammonia or an amine, and a coupling solvent. Pigments, e.g. iron oxide, and dryers may be included. The coatings may air dry or may be baked. Specification 907,782 is referred to.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE633741D BE633741A (en) | 1963-06-12 | ||
NL294046D NL294046A (en) | 1963-06-12 | ||
US33368A US3098834A (en) | 1960-06-02 | 1960-06-02 | Preparation of water-soluble oilresin vehicles |
GB2349563A GB997626A (en) | 1963-06-12 | 1963-06-12 | Preparation of a water-miscible varnish composition |
FR938537A FR1360945A (en) | 1963-06-12 | 1963-06-18 | Water-soluble oil-resin vehicles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2349563A GB997626A (en) | 1963-06-12 | 1963-06-12 | Preparation of a water-miscible varnish composition |
Publications (1)
Publication Number | Publication Date |
---|---|
GB997626A true GB997626A (en) | 1965-07-07 |
Family
ID=10196544
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2349563A Expired GB997626A (en) | 1960-06-02 | 1963-06-12 | Preparation of a water-miscible varnish composition |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE633741A (en) |
GB (1) | GB997626A (en) |
NL (1) | NL294046A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4183833A (en) * | 1977-04-08 | 1980-01-15 | Nippon Zeon Co. Ltd. | Novel modified resins, process for preparing the same, and a composition for printing ink containing said modified resins as vehicle components |
US4252701A (en) * | 1978-10-06 | 1981-02-24 | Nippon Zeon Co. Ltd. | Modified cyclopentadiene resins, process for preparing the same, and a composition for printing ink containing said modified resins as vehicle components |
US4256619A (en) | 1978-09-18 | 1981-03-17 | Nippon Zeon Co. Ltd. | Oil-modified resins, process for preparation thereof, and a composition for printing ink containing said oil-modified resins as vehicle components |
US4659380A (en) * | 1982-05-24 | 1987-04-21 | Ashland Oil, Inc. | Water-borne permanent coating compositions and processes therefor |
CN112430404A (en) * | 2020-12-04 | 2021-03-02 | 温州市海格阀门有限公司 | Check valve casting and machining process thereof |
-
0
- NL NL294046D patent/NL294046A/xx unknown
- BE BE633741D patent/BE633741A/xx unknown
-
1963
- 1963-06-12 GB GB2349563A patent/GB997626A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4183833A (en) * | 1977-04-08 | 1980-01-15 | Nippon Zeon Co. Ltd. | Novel modified resins, process for preparing the same, and a composition for printing ink containing said modified resins as vehicle components |
US4256619A (en) | 1978-09-18 | 1981-03-17 | Nippon Zeon Co. Ltd. | Oil-modified resins, process for preparation thereof, and a composition for printing ink containing said oil-modified resins as vehicle components |
US4252701A (en) * | 1978-10-06 | 1981-02-24 | Nippon Zeon Co. Ltd. | Modified cyclopentadiene resins, process for preparing the same, and a composition for printing ink containing said modified resins as vehicle components |
US4659380A (en) * | 1982-05-24 | 1987-04-21 | Ashland Oil, Inc. | Water-borne permanent coating compositions and processes therefor |
CN112430404A (en) * | 2020-12-04 | 2021-03-02 | 温州市海格阀门有限公司 | Check valve casting and machining process thereof |
Also Published As
Publication number | Publication date |
---|---|
NL294046A (en) | |
BE633741A (en) |
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