GB989589A - Dicarboxylic and n-vinyl imides - Google Patents

Dicarboxylic and n-vinyl imides

Info

Publication number
GB989589A
GB989589A GB3233863A GB3233863A GB989589A GB 989589 A GB989589 A GB 989589A GB 3233863 A GB3233863 A GB 3233863A GB 3233863 A GB3233863 A GB 3233863A GB 989589 A GB989589 A GB 989589A
Authority
GB
United Kingdom
Prior art keywords
acid
imide
imides
vinyl
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3233863A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roehm and Haas GmbH
Original Assignee
Roehm and Haas GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm and Haas GmbH filed Critical Roehm and Haas GmbH
Publication of GB989589A publication Critical patent/GB989589A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D207/00Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36Oxygen or sulfur atoms
    • C07D207/402,5-Pyrrolidine-diones
    • C07D207/4042,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D209/00Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyrrole Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Dicarboxylic acid N-vinyl imides are prepared by (1) heating the corresponding N-a -acetoxyethyl imide with an acid catalyst and preferably a polymerization inhibitor, or (2) reacting the imide with vinyl acetate in the presence of a salt of a Group Ib or IIb metal. The specified imides are N-vinyl succinimide, phthalimide, tetrahydrophthalimide, naphthalic acid imide, pyromelitic acid imide, a ,a 1-dimethyl succinimide and hexahydrophthalimide. In (1) suitable temperatures are 100 DEG to 200 DEG C., and the specified polymerization inhibitor is Indulin. The acid catalyst may be a protonic acid, a Lewis acid of Friedel-Crafts type, a salt of a weak base and a strong acid, or an acid salt of a strong base and a strong acid. In (2) the specified temperature range is 120 DEG to 200 DEG C. and suitable metal salts are copper (II) sulphate, zinc chloride, and mercuric sulphate. The process may also be carried out in a solvent, e.g. ethyl acetate. Dicarboxylic acid N-a -acetoxyethyl imides are prepared by heating the corresponding dicarboxylic acid imide with vinyl acetate, an alkali, and a polymerization inhibitor.
GB3233863A 1962-08-16 1963-08-15 Dicarboxylic and n-vinyl imides Expired GB989589A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DER33335A DE1245381B (en) 1962-08-16 1962-08-16 Process for the preparation of N-vinyldicarboximides

Publications (1)

Publication Number Publication Date
GB989589A true GB989589A (en) 1965-04-22

Family

ID=7404040

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3233863A Expired GB989589A (en) 1962-08-16 1963-08-15 Dicarboxylic and n-vinyl imides

Country Status (4)

Country Link
CH (1) CH477438A (en)
DE (1) DE1245381B (en)
GB (1) GB989589A (en)
NL (1) NL296358A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10190070B2 (en) 2005-04-28 2019-01-29 Castrol Limited Multiple-function dispersant graft polymer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10190070B2 (en) 2005-04-28 2019-01-29 Castrol Limited Multiple-function dispersant graft polymer

Also Published As

Publication number Publication date
NL296358A (en)
CH477438A (en) 1969-08-31
DE1245381B (en) 1967-07-27

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