GB986047A - Organic sulphide-dodecaborane addition compounds, derivatives and salts thereof - Google Patents
Organic sulphide-dodecaborane addition compounds, derivatives and salts thereofInfo
- Publication number
- GB986047A GB986047A GB3473463A GB3473463A GB986047A GB 986047 A GB986047 A GB 986047A GB 3473463 A GB3473463 A GB 3473463A GB 3473463 A GB3473463 A GB 3473463A GB 986047 A GB986047 A GB 986047A
- Authority
- GB
- United Kingdom
- Prior art keywords
- srr1
- salts
- organic
- cation
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003839 salts Chemical class 0.000 title abstract 5
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 101150004071 SRR1 gene Proteins 0.000 abstract 8
- -1 carbocyclic aromatic compound Chemical class 0.000 abstract 7
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 abstract 5
- 229930195733 hydrocarbon Natural products 0.000 abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 abstract 3
- 229910000085 borane Inorganic materials 0.000 abstract 3
- 150000001768 cations Chemical class 0.000 abstract 3
- 125000000962 organic group Chemical group 0.000 abstract 3
- 239000000047 product Substances 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 150000001879 copper Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000003254 radicals Chemical class 0.000 abstract 2
- 238000006467 substitution reaction Methods 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- JXSRRBVHLUJJFC-UHFFFAOYSA-N 7-amino-2-methylsulfanyl-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitrile Chemical compound N1=CC(C#N)=C(N)N2N=C(SC)N=C21 JXSRRBVHLUJJFC-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910006069 SO3H Inorganic materials 0.000 abstract 1
- 101100054666 Streptomyces halstedii sch3 gene Proteins 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 150000001555 benzenes Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229910010277 boron hydride Inorganic materials 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000005341 cation exchange Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000004997 halocarbonyl group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000004970 halomethyl group Chemical group 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical class [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000004953 trihalomethyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/088—Iron or steel solutions containing organic acids
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/02—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant
- C06B47/10—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant a component containing free boron, an organic borane or a binary compound of boron, except with oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
- C07F3/103—Mercury compounds without C-Mercury linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
- C23F1/28—Acidic compositions for etching iron group metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds of the formula B12H10.2SRR1 (I) wherein R and R1 are monovalent organic groups or may be joined together to form a single divalent organic radical; salts of the formula M[B12H11.SRR1] (II) wherein M is a group which forms a cation in aqueous solution, O is at least 1 and is the valence of M; substitution products of the formulae B12H10- yXy.2SRR1 (III) and M[B12H11- y1Xy1.SRR1]b (IV wherein X is a group which can be bonded to a nuclear carbon atom of a carbocyclic aromatic compound in place of hydrogen, y is 1 to 10 and y1 is to to 11. X includes the following: halogens, hydrocarbon, -COOH, carbamyl, halocarbonyl, halomethyl, -OH, -OR2, -CH(OR2)2, -OCOR2, -CO.OR2, -NCO, -CNO, -CNS, -NCS, -SR2, -CH2OH, -CH2OR2, -CH2NR22, -CN, -NH2, -NR22, trihalomethyl, -COR2, -CHO, -NO2, -NO, -N = N-Ar, -SO3H, -SO2R2, -HgOCOCH3, where R2 is a monovalent organic group. M can be H+, H3O+, a metal, aminine complex, NH4+, NH2-NH3+, N-substituted ammonium or hydrazonium, S-substituted sulphonium and P-substituted phosphonium. Compounds of the type B12H10.2SRR1 are made by heating a boron hydride BmHm+4, where m is 2, 5 or 10, with an organic sulphide-borane adduct BH3.SRR1 to an elevated temperature at which hydrogen is released as a by-product. Contacting the product with a cation gives M[B12H11.SRR1]b. The organic sulphide borane adduct is made by reacting SRR1 with diborane at a temperature lower than that required above. The substitution products III and IV are made by reacting compounds I or II with a reagent capable of introducing a monovalent substituent into a benzene nucleus. The salts II and IV may be transformed into other salts by cation exchange. By contacting salts II or IV with the hydrogen form of an acidic ion-exchange resin, acids of the type HB12H11.SRR1 or HB12H11- yXy.SRR1 are formed. These acids are useful as catalysts for the reaction of alcohols and organic carboxylic acids to form esters. Detailed examples are given.ALSO:A mixture of hydrocarbons in the boiling range of gasoline which contains a copper salt of an organic acid (e.g. copper stearate) is thoroughly agitated with an aqueous ammoniacal solution of an alkali metal or alkaline earth metal salt of the formula M[B12H11.SRR1]b where M is a cation, b is the valence, R and R1 are monovalent organic groups or may be joined together to form a single divalent organic radical, e.g. CsB12H11.S(CH3)2, or NaB12H11.S(CH3)2 to free the hydrocarbon layer from copper salt. Substituted ammonium, phosphonium or sulphonium salts of the above formula are also useful to remove undesirable metals from hydrocarbon media, e.g. (CH3)4NB12H11S(CH3)2 and (C2H5)3 NHB12 H10 SCH3.S(CH3)2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3473463A GB986047A (en) | 1963-09-03 | 1963-09-03 | Organic sulphide-dodecaborane addition compounds, derivatives and salts thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3473463A GB986047A (en) | 1963-09-03 | 1963-09-03 | Organic sulphide-dodecaborane addition compounds, derivatives and salts thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB986047A true GB986047A (en) | 1965-03-17 |
Family
ID=10369317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3473463A Expired GB986047A (en) | 1963-09-03 | 1963-09-03 | Organic sulphide-dodecaborane addition compounds, derivatives and salts thereof |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB986047A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110267915A (en) * | 2016-11-29 | 2019-09-20 | 半核子有限公司 | Prepare the composition and method of the brilliant artificial borane atom of skin |
| CN113651842A (en) * | 2021-08-31 | 2021-11-16 | 河南师范大学 | Borane compound K [ BH3S(CH3)BH3]Method of synthesis of |
-
1963
- 1963-09-03 GB GB3473463A patent/GB986047A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110267915A (en) * | 2016-11-29 | 2019-09-20 | 半核子有限公司 | Prepare the composition and method of the brilliant artificial borane atom of skin |
| CN110267915B (en) * | 2016-11-29 | 2023-04-25 | 半核子有限公司 | Compositions and methods for preparing Pi Jing artificial borane atoms |
| CN113651842A (en) * | 2021-08-31 | 2021-11-16 | 河南师范大学 | Borane compound K [ BH3S(CH3)BH3]Method of synthesis of |
| CN113651842B (en) * | 2021-08-31 | 2024-01-30 | 河南师范大学 | Borane compound K BH 3 S(CH 3 )BH 3 ]Is synthesized by the method of (2) |
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