GB818325A - Process for the preparation of non-gelling solutions of oil-soluble basic salts of organic acids in oils - Google Patents

Process for the preparation of non-gelling solutions of oil-soluble basic salts of organic acids in oils

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Publication number
GB818325A
GB818325A GB12180/56A GB1218056A GB818325A GB 818325 A GB818325 A GB 818325A GB 12180/56 A GB12180/56 A GB 12180/56A GB 1218056 A GB1218056 A GB 1218056A GB 818325 A GB818325 A GB 818325A
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United Kingdom
Prior art keywords
basic
alkyl
acid
calcium
salt
Prior art date
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Expired
Application number
GB12180/56A
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Bataafsche Petroleum Maatschappij NV
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Bataafsche Petroleum Maatschappij NV
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Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB818325A publication Critical patent/GB818325A/en
Expired legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/142Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/16Naphthenic acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26Overbased carboxylic acid salts
    • C10M2207/262Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2215/26Amines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/042Metal salts thereof
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    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049Phosphite
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    • C10N2010/02Groups 1 or 11
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The tendency of a solution of an oil-soluble basic salt of an organic acid in an oily medium to gel with water vapour, is prevented by incorporating in the solution a compound which is soluble in the oily medium and contains a polar group. The oily medium may be any liquid having a dielectric constant of 10 or less, particularly hydrocarbons such as benzene, toluene, xylene, pentane, heptane, and petroleum fractions from gasoline to lubricating oil fractions. The basic salt may be derived from a carboxylic acid, a sulphonic acid or a phosphorus-containing organic acid, and may be a sodium, potassium, lithium, ammonium, calcium, magnesium, zinc, lead, aluminium, copper, nickel, tin, cobalt or manganese salt. The basic salt contains in the molecule a metal oxide, hydroxide, carbonate, sulphide, sulphite or oxalate, and the salt contains 4 or more equivalents of metal per one equivalent of organic acid. The compound containing a polar group may be a monoor polyhydric alcohol, such as methanol, ethanol, hexanol and decanol, an alkyl amine such as decylamine, an alkyl phenol, an alkyl aromatic carboxylic acid, an alkyl aromatic hydroxycarboxylic acid, a naphthenic acid, an aliphatic carboxylic acid, a sulphonic acid, a phosphoric acid or a salt of these acids. In examples basic salts are basic calcium alkyl salicylates containing calcium hydroxide and calcium carbonate, basic copper alkyl salicylates containing copper oxide, and basic ferric alkyl salicylates containing ferric oxide (the salicylates are derived from mono- and di-C14-C18-alkylsalicylic acids), basic copper naphthenates containing copper oxide (derived from petroleum naphthenic acids), and a basic calcium petroleum sulphonate containing calcium hydroxide; the oily media are medicinal oil, mineral lubricating oil, and xylene; the compounds containing polar groups are neutral calcium alkyl salicylates, free alkyl salicylic acids, free naphthenic acids, decanol and methanol. Specifications 687,490, 718,714, 721,670, 729,376, 739,434, 759,346, 780,058, 785,196, 790,471, 818,323 and 818,326 are referred to.
GB12180/56A 1955-04-22 1956-04-20 Process for the preparation of non-gelling solutions of oil-soluble basic salts of organic acids in oils Expired GB818325A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL818325X 1955-04-22

Publications (1)

Publication Number Publication Date
GB818325A true GB818325A (en) 1959-08-12

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ID=19838966

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Application Number Title Priority Date Filing Date
GB12180/56A Expired GB818325A (en) 1955-04-22 1956-04-20 Process for the preparation of non-gelling solutions of oil-soluble basic salts of organic acids in oils

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4869837A (en) * 1987-07-09 1989-09-26 Shell Oil Company Preparation of a basic salt
US4876020A (en) * 1987-06-25 1989-10-24 Shell Oil Company Lubricating oil composition
WO1999043771A1 (en) * 1998-02-26 1999-09-02 Witco Corporation Viscosity drift control in overbased detergents
AU2003200515B2 (en) * 1998-02-26 2004-03-25 General Electric Company Viscosity drift control in overbased detergents
CN114527170A (en) * 2022-02-16 2022-05-24 一汽解放汽车有限公司 Method for monitoring box bridge lubricating oil, monitoring device, equipment and storage medium

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4876020A (en) * 1987-06-25 1989-10-24 Shell Oil Company Lubricating oil composition
US4869837A (en) * 1987-07-09 1989-09-26 Shell Oil Company Preparation of a basic salt
WO1999043771A1 (en) * 1998-02-26 1999-09-02 Witco Corporation Viscosity drift control in overbased detergents
US6239084B1 (en) 1998-02-26 2001-05-29 Crompton Corporation Viscosity drift control in overbased detergents
AU2003200515B2 (en) * 1998-02-26 2004-03-25 General Electric Company Viscosity drift control in overbased detergents
CN114527170A (en) * 2022-02-16 2022-05-24 一汽解放汽车有限公司 Method for monitoring box bridge lubricating oil, monitoring device, equipment and storage medium
CN114527170B (en) * 2022-02-16 2023-12-19 一汽解放汽车有限公司 Method, monitoring device, equipment and storage medium for monitoring lubricating oil of tank bridge

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