GB976363A - Improvements in and relating to the production of cellular polymeric materials - Google Patents
Improvements in and relating to the production of cellular polymeric materialsInfo
- Publication number
- GB976363A GB976363A GB266/62A GB26662A GB976363A GB 976363 A GB976363 A GB 976363A GB 266/62 A GB266/62 A GB 266/62A GB 26662 A GB26662 A GB 26662A GB 976363 A GB976363 A GB 976363A
- Authority
- GB
- United Kingdom
- Prior art keywords
- particles
- surface active
- active agent
- water
- polymer particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000001413 cellular effect Effects 0.000 title 1
- 239000002245 particle Substances 0.000 abstract 8
- 239000004094 surface-active agent Substances 0.000 abstract 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 abstract 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- -1 vinyl compound Chemical class 0.000 abstract 2
- PQMFVUNERGGBPG-UHFFFAOYSA-N (6-bromopyridin-2-yl)hydrazine Chemical compound NNC1=CC=CC(Br)=N1 PQMFVUNERGGBPG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 abstract 1
- 238000010410 dusting Methods 0.000 abstract 1
- 238000005187 foaming Methods 0.000 abstract 1
- 239000001282 iso-butane Substances 0.000 abstract 1
- 150000004668 long chain fatty acids Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 159000000001 potassium salts Chemical class 0.000 abstract 1
- 229940114930 potassium stearate Drugs 0.000 abstract 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 abstract 1
- 239000011975 tartaric acid Substances 0.000 abstract 1
- 235000002906 tartaric acid Nutrition 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
- 238000009834 vaporization Methods 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
A process for expanding expandable thermoplastic polymer particles comprises dusting them with a solid water-soluble surface active agent and thereafter contacting the particles with steam under conditions such that an aqueous condensate phase is formed on the resulting expanded particles and then water-washing the expanded particles to remove surface active agent therefrom. By "expandable polymer particles" is meant polymer particles containing a volatile expanding agent, e.g. n-butane or n-pentane which will cause expansion of the particles by vaporization, that is by physical as distinct from chemical means. The particles may be of polystyrene, copolymers of styrene and another vinyl compound or acrylonitrile, or of acrylic resins e.g. polymethyl methacrylate. Isobutane, neopentane 1- or 2-butene, isobutene and butadiene are other specified expanding agents. The surface active agent is preferably a water-soluble salt of a long-chain fatty acid, especially sodium stearate. Ammonium and amine salts, potassium stearate, the sodium and potassium salts of lauric, tridecylic, myristic, pentadecylic, palmitic, margaric and nondecylic acids, and also cationic and nonionic types are also specified. Any tendency to foaming of the aqueous condensate is prevented by adding, together with the surface active agent, a solid substance forming an acid solution in water (e.g. boric, tartaric or citric acid), to bring the pH of the effluent wash liquor to a pH between 6 and 10.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB266/62A GB976363A (en) | 1962-01-03 | 1962-01-03 | Improvements in and relating to the production of cellular polymeric materials |
| FR920256A FR1354156A (en) | 1962-01-03 | 1963-01-02 | Process for the production of cellular olefinic polymer materials |
| BE626772A BE626772A (en) | 1962-01-03 | 1963-01-02 | Method for preparing polymeric materials with cellular structure |
| NL287345A NL287345A (en) | 1962-01-03 | 1963-01-02 | Method for preparing polymeric materials with cellular structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB266/62A GB976363A (en) | 1962-01-03 | 1962-01-03 | Improvements in and relating to the production of cellular polymeric materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB976363A true GB976363A (en) | 1964-11-25 |
Family
ID=9701331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB266/62A Expired GB976363A (en) | 1962-01-03 | 1962-01-03 | Improvements in and relating to the production of cellular polymeric materials |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE626772A (en) |
| FR (1) | FR1354156A (en) |
| GB (1) | GB976363A (en) |
| NL (1) | NL287345A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007073318A1 (en) * | 2005-12-21 | 2007-06-28 | Akzo Nobel N.V. | Chemical composition and process |
| US7786181B2 (en) | 2005-12-21 | 2010-08-31 | Akzo Nobel N.V. | Chemical composition and process |
-
1962
- 1962-01-03 GB GB266/62A patent/GB976363A/en not_active Expired
-
1963
- 1963-01-02 FR FR920256A patent/FR1354156A/en not_active Expired
- 1963-01-02 NL NL287345A patent/NL287345A/en unknown
- 1963-01-02 BE BE626772A patent/BE626772A/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007073318A1 (en) * | 2005-12-21 | 2007-06-28 | Akzo Nobel N.V. | Chemical composition and process |
| US7786181B2 (en) | 2005-12-21 | 2010-08-31 | Akzo Nobel N.V. | Chemical composition and process |
| CN101341201B (en) * | 2005-12-21 | 2011-07-20 | 阿克佐诺贝尔公司 | Chemical composition and process |
Also Published As
| Publication number | Publication date |
|---|---|
| NL287345A (en) | 1965-02-25 |
| FR1354156A (en) | 1964-03-06 |
| BE626772A (en) | 1963-07-02 |
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