GB975456A - Improvements in or relating to photographic films and methods of producing photographic records - Google Patents
Improvements in or relating to photographic films and methods of producing photographic recordsInfo
- Publication number
- GB975456A GB975456A GB914561A GB914561A GB975456A GB 975456 A GB975456 A GB 975456A GB 914561 A GB914561 A GB 914561A GB 914561 A GB914561 A GB 914561A GB 975456 A GB975456 A GB 975456A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyisocyanate
- cross
- compound
- blocked
- reactive compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/52—Compositions containing diazo compounds as photosensitive substances
- G03C1/61—Compositions containing diazo compounds as photosensitive substances with non-macromolecular additives
- G03C1/615—Substances generating bases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6212—Polymers of alkenylalcohols; Acetals thereof; Oxyalkylation products thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/60—Processes for obtaining vesicular images
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
975,456. Photosensitive vesicular materials. A. F. DAECH. March 13,1961 [March 14,1960; Feb. 10, 1961], No. 9145/61. Heading G2C. Photosensitive material comprises a reactive compound capable of being cross-linked, a blocked polyisocyanate cross-linking agent, and a photolytic compound capable of releasing gas on exposure to light, said blocked polyisocyanate being unblocked by heat so as to react with the said reactive compound to give a cross-linked thermosetting resin. The reactive compound may be the film-former itself such as a terpolymer of vinyl chloride, vinyl acetate and vinyl alcohol or other resinous polyol or polyamine, or it may be a polyfunctional compound such as N, N, N<1>, N<1>-tetrakes (2-hydroxypropyl) ethylene diamine in an inactive binder such as a vinylidene in chloride/acrylonitrile copolymer. The photolytic compound is preferably a diazo compound and the polyisocyanate may be toluene diisocyanate which may be blocked by reaction with an aliphatic alcohol such as trimethycarbinol, 2-methyl-3-butyn-2-ol or 3-methyl-1-pentyn-3-ol, or with a phenol. Alternatively, the polyisocyanate may be blocked by a dimer or trimer formation. After imagewise exposure to light whereby gas bubbles are released, the film is heated to unblock the polyisocyanate and cause formation of a cross-linked thermosetting resin.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1455560A | 1960-03-14 | 1960-03-14 | |
US8826461A | 1961-02-10 | 1961-02-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB975456A true GB975456A (en) | 1964-11-18 |
Family
ID=26686234
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2458364A Expired GB975457A (en) | 1960-03-14 | 1961-02-10 | Improvements in or relating to photographic films |
GB914561A Expired GB975456A (en) | 1960-03-14 | 1961-03-13 | Improvements in or relating to photographic films and methods of producing photographic records |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2458364A Expired GB975457A (en) | 1960-03-14 | 1961-02-10 | Improvements in or relating to photographic films |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1245730B (en) |
GB (2) | GB975457A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4189320A (en) * | 1975-04-29 | 1980-02-19 | American Hoechst Corporation | Light-sensitive o-quinone diazide compositions and photographic reproduction processes and structures |
US4252884A (en) * | 1979-08-14 | 1981-02-24 | James River Graphics, Inc. | Negative-working diazotype photoreproduction |
US4289838A (en) * | 1972-12-14 | 1981-09-15 | Polychrome Corporation | Diazo-unsaturated monomer light sensitive compositions |
US4439512A (en) * | 1975-12-05 | 1984-03-27 | La Cellophane | Chromogenic compositions containing stabilized phenolic coupler compounds, recording materials and processes utilizing same |
US4451550A (en) * | 1982-07-29 | 1984-05-29 | James River Graphics, Inc. | Vesicular film and composition with phenoxy resin matrix |
US4544466A (en) * | 1983-12-06 | 1985-10-01 | Phillips Petroleum Company | Process of making U.V. cured polyurethanes using diazonium salt promoters |
US4549945A (en) * | 1984-01-11 | 1985-10-29 | Phillips Petroleum Company | UV Cured polyurethanes using organotin promoters |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3940246A (en) * | 1971-04-26 | 1976-02-24 | Ciba-Geigy Ag | Sublimation transfer and isocyanate fixation of amino- or hydroxy-containing dyestuffs and transfer sheets therefor |
US4029467A (en) * | 1971-04-26 | 1977-06-14 | Ciba-Geigy Ag | Sublimation transfer and diisocyanate fixation of amino- or hydroxy-containing azo dyestuffs and transfer sheets thereof |
US4201588A (en) * | 1974-04-15 | 1980-05-06 | Eastman Kodak Company | Radiation sensitive co(III)complex photoreduction element with image recording layer |
US4314019A (en) * | 1976-09-07 | 1982-02-02 | Eastman Kodak Company | Transition metal photoreduction systems and processes |
US4124392A (en) | 1976-09-07 | 1978-11-07 | Eastman Kodak Company | Cobalt complex amplification imaging system with blocked dye precursor |
-
1961
- 1961-02-10 GB GB2458364A patent/GB975457A/en not_active Expired
- 1961-03-13 DE DE1961K0043169 patent/DE1245730B/en active Pending
- 1961-03-13 GB GB914561A patent/GB975456A/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4289838A (en) * | 1972-12-14 | 1981-09-15 | Polychrome Corporation | Diazo-unsaturated monomer light sensitive compositions |
US4189320A (en) * | 1975-04-29 | 1980-02-19 | American Hoechst Corporation | Light-sensitive o-quinone diazide compositions and photographic reproduction processes and structures |
US4439512A (en) * | 1975-12-05 | 1984-03-27 | La Cellophane | Chromogenic compositions containing stabilized phenolic coupler compounds, recording materials and processes utilizing same |
US4252884A (en) * | 1979-08-14 | 1981-02-24 | James River Graphics, Inc. | Negative-working diazotype photoreproduction |
US4451550A (en) * | 1982-07-29 | 1984-05-29 | James River Graphics, Inc. | Vesicular film and composition with phenoxy resin matrix |
US4544466A (en) * | 1983-12-06 | 1985-10-01 | Phillips Petroleum Company | Process of making U.V. cured polyurethanes using diazonium salt promoters |
US4549945A (en) * | 1984-01-11 | 1985-10-29 | Phillips Petroleum Company | UV Cured polyurethanes using organotin promoters |
Also Published As
Publication number | Publication date |
---|---|
DE1245730B (en) | 1967-07-27 |
GB975457A (en) | 1964-11-18 |
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