GB968665A - 3-substituted uracils - Google Patents
3-substituted uracilsInfo
- Publication number
- GB968665A GB968665A GB17419/64A GB1741964A GB968665A GB 968665 A GB968665 A GB 968665A GB 17419/64 A GB17419/64 A GB 17419/64A GB 1741964 A GB1741964 A GB 1741964A GB 968665 A GB968665 A GB 968665A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenyl
- methyluracil
- bromo
- benzyl
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000003085 diluting agent Substances 0.000 abstract 3
- 229910052700 potassium Inorganic materials 0.000 abstract 3
- 239000011734 sodium Chemical group 0.000 abstract 3
- 229910052708 sodium Inorganic materials 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- QXEQBBSHZHGTGF-UHFFFAOYSA-N 3-benzyl-5-bromo-6-methyl-1H-pyrimidine-2,4-dione Chemical compound C(C1=CC=CC=C1)N1C(NC(=C(C1=O)Br)C)=O QXEQBBSHZHGTGF-UHFFFAOYSA-N 0.000 abstract 2
- JRKTXDSALJOMQY-UHFFFAOYSA-N 5,6-dimethyl-3-phenyl-1H-pyrimidine-2,4-dione Chemical compound CC=1C(N(C(NC1C)=O)C1=CC=CC=C1)=O JRKTXDSALJOMQY-UHFFFAOYSA-N 0.000 abstract 2
- QMASYZYAMUINDL-UHFFFAOYSA-N 5-bromo-6-methyl-3-phenyl-1h-pyrimidine-2,4-dione Chemical compound O=C1C(Br)=C(C)NC(=O)N1C1=CC=CC=C1 QMASYZYAMUINDL-UHFFFAOYSA-N 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- ISAKRJDGNUQOIC-UHFFFAOYSA-N Uracil Chemical compound O=C1C=CNC(=O)N1 ISAKRJDGNUQOIC-UHFFFAOYSA-N 0.000 abstract 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 125000001246 bromo group Chemical group Br* 0.000 abstract 2
- 239000000460 chlorine Chemical group 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 229910003002 lithium salt Chemical group 0.000 abstract 2
- 159000000002 lithium salts Chemical group 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 239000011591 potassium Chemical group 0.000 abstract 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 abstract 2
- 241000196324 Embryophyta Species 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 229940035893 uracil Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/20—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D239/22—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
- C07D239/52—Two oxygen atoms
- C07D239/54—Two oxygen atoms as doubly bound oxygen atoms or as unsubstituted hydroxy radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/70—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings condensed with carbocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/70—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings condensed with carbocyclic rings or ring systems
- C07D239/72—Quinazolines; Hydrogenated quinazolines
- C07D239/95—Quinazolines; Hydrogenated quinazolines with hetero atoms directly attached in positions 2 and 4
- C07D239/96—Two oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/6512—Six-membered rings having the nitrogen atoms in positions 1 and 3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
The invention comprises compounds of the isomeric formulae: <FORM:0968665/C1/1> or <FORM:0968665/C1/2> where R1 is phenyl or benzyl, R2 is bromine, chlorine, methyl or ethyl and R3 is methyl or ethyl, and sodium, potassium and lithium salts thereof (with the exception of 3-phenyl-5-bromo-6-methyluracil, 3-benzyl-5-bromo-6-methyluracil and 3-phenyl-5, 6-dimethyluracil and its potassium salt). These compounds are herbicides (see Division A5) and are prepared by methods analogous to those used in Specification 968,663. Specifications 492,742, 968,662, 968,664, 968,665 and 968,666 also are referred to.ALSO:The invention comprises herbicidal compositions containing at least one compound of the isomeric formul <FORM:0968665/A5-A6/1> or <FORM:0968665/A5-A6/2> where R1 is phenyl or benzyl, R2 is bromine, chlorine, methyl or ethyl and R3 is methyl or ethyl, or a sodium, potassium or lithium salt thereof (see Division C2), associated with a compatible diluent, which may be (i) at least in part a liquid other than an oil (e.g. water); (ii) at least in part an oil (see below); (iii) at least in part a solid; or (iv) a surface-active agent (which may also be present in (i)-(iii)). Compositions consisting of (i.e. having no other ingredients) 3-phenyl-5-bromo-6-methyluracil, 3 - benzyl - 5 - bromo - 6 - methyluracil or 3 - phenyl - 5,6 - dimethyluracil or its potassium salt and water, ethanol or ether or two or more of these diluents are disclaimed. The invention also comprises a method of controlling the growth of weeds at a locus by applying to the locus a herbicidally effective quantity of at least one uracil of the formula given, or a Li, Na or K salt thereof, if desired in the form of a composition as defined. An oil is defined as a liquid immiscible with water and soluble in ether, and which boils at not below 125 DEG C. Specified diluents and additives are those referred to in the parent Specification. The compositions may also contain one of the 3-substituted uracils disclosed in Specifications 968,662, 968,663, 968,664 and 968,666. Specification 942,742 also is referred to.
Applications Claiming Priority (16)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US83370459A | 1959-08-14 | 1959-08-14 | |
US83370559A | 1959-08-14 | 1959-08-14 | |
US1295860A | 1960-03-07 | 1960-03-07 | |
US1296860A | 1960-03-07 | 1960-03-07 | |
US1295960A | 1960-03-07 | 1960-03-07 | |
US1295660A | 1960-03-07 | 1960-03-07 | |
US1296760A | 1960-03-07 | 1960-03-07 | |
US1295760A | 1960-03-07 | 1960-03-07 | |
US4883760A | 1960-08-11 | 1960-08-11 | |
GB28141/60A GB968661A (en) | 1959-08-14 | 1960-08-15 | Herbicidal compositions containing 3-substituted uracils |
US8498061A | 1961-01-26 | 1961-01-26 | |
US8967461A | 1961-02-16 | 1961-02-16 | |
US12363661A | 1961-07-13 | 1961-07-13 | |
US15974661A | 1961-12-15 | 1961-12-15 | |
US232311A US3235360A (en) | 1959-08-14 | 1962-10-22 | Control of undesirable vegetation |
US284835A US3254082A (en) | 1959-08-14 | 1963-06-03 | Process for preparing substituted uracils |
Publications (1)
Publication Number | Publication Date |
---|---|
GB968665A true GB968665A (en) | 1964-09-02 |
Family
ID=27585621
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB17419/64A Expired GB968665A (en) | 1959-08-14 | 1960-08-15 | 3-substituted uracils |
GB17418/64A Expired GB968664A (en) | 1959-08-14 | 1960-08-15 | 3-substituted uracils |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB17418/64A Expired GB968664A (en) | 1959-08-14 | 1960-08-15 | 3-substituted uracils |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB968665A (en) |
-
1960
- 1960-08-15 GB GB17419/64A patent/GB968665A/en not_active Expired
- 1960-08-15 GB GB17418/64A patent/GB968664A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB968664A (en) | 1964-09-02 |
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