GB962682A - Halomethylated diphenyl oxide condensation products with phenols and varnish resins and thermosetting resins derived therefrom - Google Patents

Halomethylated diphenyl oxide condensation products with phenols and varnish resins and thermosetting resins derived therefrom

Info

Publication number
GB962682A
GB962682A GB19625/62A GB1962562A GB962682A GB 962682 A GB962682 A GB 962682A GB 19625/62 A GB19625/62 A GB 19625/62A GB 1962562 A GB1962562 A GB 1962562A GB 962682 A GB962682 A GB 962682A
Authority
GB
United Kingdom
Prior art keywords
reacted
phenol
product
oxide
products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19625/62A
Inventor
Lawrence Faye Sonnabend
James Dirk Doedens
Earl Harold Rosenbrock
Norman Thomas Hebert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to GB19625/62A priority Critical patent/GB962682A/en
Priority claimed from US270247A external-priority patent/US3316140A/en
Priority to GB148264A priority patent/GB1005735A/en
Publication of GB962682A publication Critical patent/GB962682A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/22—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
    • C07C43/275—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings having all ether-oxygen atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C08G75/23—Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

The invention comprises the condensation products of diphenyloxide substituted by at least two halomethyl groups, with a phenol having either 2 nuclear labile H atoms or at least 2 OH groups. The products may contain repeating units of formula: <FORM:0962682/C1/1> wherein Z is the residue of a dihydric phenol; or they may have the formula: <FORM:0962682/C1/2> wherein A is the nuclear-attached residue of the phenol and n is an integer 2-7. The latter products may be reacted with an alkylene oxide and the compounds obtained esterified with long-chain unsaturated fatty acids. In examples, (1) bis (4-chloromethylphenyl) oxide is reacted with phenol, (2) the product reacted with propylene oxide and (3) the product further reacted with dehydrated castor oil fatty acids; (5) and (7) a bis-chloromethylated diphenyl oxide was reacted with bisphenol A or bisphenol S, the product in the latter case containing the unit: <FORM:0962682/C1/3> Other phenols, some of which are halogen-substituted, are specified as suitable for the condensation reaction.ALSO:The invention comprises the condensation products of diphenyl oxide substituted by at least two halomethyl groups, with a phenol having either 2 nuclear lobile H atoms or at least 2 OH groups. The products may contain repeating units of formula: <FORM:0962682/C3/1> wherein Z is the residue of a dihydric phenol; or they may have the formula: <FORM:0962682/C3/2> wherein A is the nuclear-attached residue of the phenol and n is an integer 2-7. The latter-products may be reacted with an alkylene oxide and the compounds thus obtained are converted to varnish drying oils by esterification with long chain unsaturated fatty acids. Thermosetting resins are obtained by reacting products of the second formula with a formaldehyde-producing compound such as hexamethylenetetramine or with formaldehyde or paraformaldehyde. In examples, (1) 4,41-bis(chloromethylphenyl)oxide is reacted with phenol, (2) the product reacted with propylene oxide and (3) the product reacted further with dehydrated castor oil fatty acids; (4) the product of example (1) was reacted with hexamethylenetetramine and wood flour; (5) a bis-chloromethylated diphenyl oxide was reacted with bisphenal-A and (6) the product reacted with hexamethylenetetramine; (7) a bis-chloromethylated diphenyl oxide was reacted with bisphenol-S, giving a product containing the acid: <FORM:0962682/C3/3>
GB19625/62A 1962-05-22 1962-05-22 Halomethylated diphenyl oxide condensation products with phenols and varnish resins and thermosetting resins derived therefrom Expired GB962682A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB19625/62A GB962682A (en) 1962-05-22 1962-05-22 Halomethylated diphenyl oxide condensation products with phenols and varnish resins and thermosetting resins derived therefrom
GB148264A GB1005735A (en) 1962-05-22 1964-01-13 Laminates

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB19625/62A GB962682A (en) 1962-05-22 1962-05-22 Halomethylated diphenyl oxide condensation products with phenols and varnish resins and thermosetting resins derived therefrom
US270247A US3316140A (en) 1963-04-03 1963-04-03 Thermosetting resins prepared by reacting formaldehyde with the reaction product of a phenol with chloromethylated diphenyl oxide

Publications (1)

Publication Number Publication Date
GB962682A true GB962682A (en) 1964-07-01

Family

ID=32395982

Family Applications (2)

Application Number Title Priority Date Filing Date
GB19625/62A Expired GB962682A (en) 1962-05-22 1962-05-22 Halomethylated diphenyl oxide condensation products with phenols and varnish resins and thermosetting resins derived therefrom
GB148264A Expired GB1005735A (en) 1962-05-22 1964-01-13 Laminates

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB148264A Expired GB1005735A (en) 1962-05-22 1964-01-13 Laminates

Country Status (1)

Country Link
GB (2) GB962682A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3428691A (en) * 1964-12-21 1969-02-18 Goodyear Tire & Rubber Age resistors for rubber

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3428691A (en) * 1964-12-21 1969-02-18 Goodyear Tire & Rubber Age resistors for rubber

Also Published As

Publication number Publication date
GB1005735A (en) 1965-09-29

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