GB960018A - Hydrofining catalysts - Google Patents

Hydrofining catalysts

Info

Publication number
GB960018A
GB960018A GB202062A GB202062A GB960018A GB 960018 A GB960018 A GB 960018A GB 202062 A GB202062 A GB 202062A GB 202062 A GB202062 A GB 202062A GB 960018 A GB960018 A GB 960018A
Authority
GB
United Kingdom
Prior art keywords
group
metals
al2o3
oxides
sulphides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB202062A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB960018A publication Critical patent/GB960018A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

Hydrofining catalysts include oxides or sulphides or mixtures thereof of metals of Groups II to VII, preferably of Group VI associated with metals of Group VIII or metals of Group Ib or IIb or their oxides or sulphides and metals salts of Group VII including vanadates, molybdates, tungstates or chromates thereof which are supported on an alumina containing carrier, actuated with HBF4 and dried at 400-800 DEG C. Comparative examples describe the hydrogenation of a synthetic mixture of (1) heptane, benzene, thiophene and pyrrol at atmospheric pressure and 150-350 DEG C., and a pressure of 120 kg/sq.cm.ALSO:In making hydrofining catalysts oxides or sulphides or mixtures thereof of metals of Group II to VII, preferably of Group VI associated with metals of Group VIII or metals of Group IB or IIB or their oxides or sulphides and metal salts of Group VII including vanadates, molybdates, tungstates or chromates thereof are dispersed on an alumina-containing carrier, the whole is activated by contact with fluoboric acid and thereafter is dried between 400 and 800 DEG C. Preferably Co or Ni supported on Al2O3 or SiO2/Al2O3 are used to make the catalysts and activation includes using an aqueous solution of fluoboric acid. Alternatively the catalyst may contain the oxides of Ni and Mo, W or Cr or mixtures thereof supported on Al2O3 or an Al2O3-containing base. Al2O3/MgO is also specified as a catalyst carrier. Comparative examples are given.
GB202062A 1961-01-30 1962-01-19 Hydrofining catalysts Expired GB960018A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR851120A FR1287439A (en) 1961-01-30 1961-01-30 Improvement of hydrorefining catalysts

Publications (1)

Publication Number Publication Date
GB960018A true GB960018A (en) 1964-06-10

Family

ID=8747729

Family Applications (1)

Application Number Title Priority Date Filing Date
GB202062A Expired GB960018A (en) 1961-01-30 1962-01-19 Hydrofining catalysts

Country Status (2)

Country Link
FR (1) FR1287439A (en)
GB (1) GB960018A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4663304A (en) * 1984-07-20 1987-05-05 Phillips Petroleum Company Acid-treated catalysts for olefin conversion and method for preparing the catalysts
US11439989B2 (en) 2018-04-10 2022-09-13 China Petroleum & Chemical Corporation Hydrofining catalyst, its preparation and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4663304A (en) * 1984-07-20 1987-05-05 Phillips Petroleum Company Acid-treated catalysts for olefin conversion and method for preparing the catalysts
US11439989B2 (en) 2018-04-10 2022-09-13 China Petroleum & Chemical Corporation Hydrofining catalyst, its preparation and application thereof

Also Published As

Publication number Publication date
FR1287439A (en) 1962-03-16

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