GB958421A - Insecticide formulations - Google Patents
Insecticide formulationsInfo
- Publication number
- GB958421A GB958421A GB372/62A GB37262A GB958421A GB 958421 A GB958421 A GB 958421A GB 372/62 A GB372/62 A GB 372/62A GB 37262 A GB37262 A GB 37262A GB 958421 A GB958421 A GB 958421A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- groups represented
- sulphur
- phenol
- specified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000009472 formulation Methods 0.000 title 1
- 239000002917 insecticide Substances 0.000 title 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 4
- -1 phosphorus compound Chemical class 0.000 abstract 3
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Chemical group 0.000 abstract 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 125000000962 organic group Chemical group 0.000 abstract 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 abstract 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 abstract 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 abstract 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 abstract 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 abstract 1
- 241000609240 Ambelania acida Species 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract 1
- YVGGHNCTFXOJCH-UHFFFAOYSA-N DDT Chemical compound C1=CC(Cl)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(Cl)C=C1 YVGGHNCTFXOJCH-UHFFFAOYSA-N 0.000 abstract 1
- UIOFUWFRIANQPC-JKIFEVAISA-N Floxacillin Chemical compound N([C@@H]1C(N2[C@H](C(C)(C)S[C@@H]21)C(O)=O)=O)C(=O)C1=C(C)ON=C1C1=C(F)C=CC=C1Cl UIOFUWFRIANQPC-JKIFEVAISA-N 0.000 abstract 1
- 239000005949 Malathion Substances 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 abstract 1
- 244000082204 Phyllostachys viridis Species 0.000 abstract 1
- LUSZGTFNYDARNI-UHFFFAOYSA-N Sesamol Natural products OC1=CC=C2OCOC2=C1 LUSZGTFNYDARNI-UHFFFAOYSA-N 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 abstract 1
- 240000004460 Tanacetum coccineum Species 0.000 abstract 1
- 235000011941 Tilia x europaea Nutrition 0.000 abstract 1
- 240000008042 Zea mays Species 0.000 abstract 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract 1
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 229940024113 allethrin Drugs 0.000 abstract 1
- 125000003368 amide group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000010905 bagasse Substances 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229940030341 copper arsenate Drugs 0.000 abstract 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 abstract 1
- 235000005822 corn Nutrition 0.000 abstract 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 abstract 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 abstract 1
- 238000010410 dusting Methods 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 125000001033 ether group Chemical group 0.000 abstract 1
- 239000003337 fertilizer Substances 0.000 abstract 1
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 239000010440 gypsum Substances 0.000 abstract 1
- 229910052602 gypsum Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 239000004571 lime Substances 0.000 abstract 1
- 229960002809 lindane Drugs 0.000 abstract 1
- 229960000453 malathion Drugs 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- SFDJOSRHYKHMOK-UHFFFAOYSA-N nitramide Chemical group N[N+]([O-])=O SFDJOSRHYKHMOK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 abstract 1
- 229960001553 phloroglucinol Drugs 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 150000003018 phosphorus compounds Chemical class 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 229940015367 pyrethrum Drugs 0.000 abstract 1
- 229940079877 pyrogallol Drugs 0.000 abstract 1
- 229960001755 resorcinol Drugs 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
- 229930003799 tocopherol Natural products 0.000 abstract 1
- 239000011732 tocopherol Substances 0.000 abstract 1
- 125000002640 tocopherol group Chemical class 0.000 abstract 1
- 235000019149 tocopherols Nutrition 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3258—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/327—Esters with unsaturated acyclic alcohols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/113—Esters of phosphoric acids with unsaturated acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4078—Esters with unsaturated acyclic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An insecticidal composition comprises a phosphorus compound having the general formula <FORM:0958421/A5-A6/1> (wherein R represents a hydrocarbon or substituted hydrocarbon group; R1 represents a hydrogen or halogen atom, or one of the groups represented by R; and R11 represents a halogen atom, one of the groups represented by R or a functional organic group; n=0, 1 or 2 and m+n=2, with the proviso that when n=2 both of the symbols R together can represent a divalent hydrocarbon group, either R representing one valence bond of that group), a solid carrier and 0.01-20% of at least one phenol. The substituted hydrocarbon groups represented by R and R1 are those substituted by one or more bromine, chlorine and nitroamine groups represented by the general formula <FORM:0958421/A5-A6/2> or ether groups R-O-. When R11 represents a functional organic group it is an acyloxyalkoxy carbonyl group wherein the acyl group is R.CO-, an amide group having the amino residue set out above or a group of the formula <FORM:0958421/A5-A6/3> where X is oxygen or sulphur. Many phosphorus compounds are specified particularly preferred compounds are dimethyl 2,2-dichlorovinyl phosphate and dimethyl 2-carbomethoxy-1-methyl vinyl phosphate. Of the many specified phenols typical examples are 2,6-ditertiarybutyl phenol, a - and b -naphthol, hydroquinone, 2,21 - bis - (p - hydroxyphenyl) propane, kryptophenols, catechol, pyrogallol, resorcinol, phloroglucinol, tocopherols, sesamol and p-amino phenol. Specified solid carriers are the siliceous minerals dusting sulphur, starch, calcium carbonate, crushed corn cobs, sugar, lime, gypsum, carbon, bagasse and crushed or powdered nut shells. The composition may also contain solvents, stickers, emulsifiers, spreading or wetting agents, fertilizers, other pesticides, e.g. sulphur copper arsenate, pyrethrum, allethrin, 4,41-dichloro-a -methylbenzohydrol tetraethyl pyrophosphate, Malathion (Registered Trade Mark), DDT, BHC and lindane. The compositions may be in the form of dusts, granules, wettable powders, baits &c.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80996A US3097128A (en) | 1961-01-06 | 1961-01-06 | Phenol stabilized organo-phosphorous insecticides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB958421A true GB958421A (en) | 1964-05-21 |
Family
ID=22160999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB372/62A Expired GB958421A (en) | 1961-01-06 | 1962-01-04 | Insecticide formulations |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3097128A (en) |
| BE (1) | BE612272A (en) |
| BR (1) | BR6235470D0 (en) |
| CH (1) | CH437905A (en) |
| DE (1) | DE1280001C2 (en) |
| DK (1) | DK102884C (en) |
| ES (1) | ES273412A1 (en) |
| GB (1) | GB958421A (en) |
| MY (1) | MY6500033A (en) |
| NL (2) | NL131123C (en) |
| OA (1) | OA00413A (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL279955A (en) * | 1961-06-30 | |||
| NL289742A (en) * | 1962-03-05 | |||
| BE639900A (en) * | 1962-11-16 | |||
| NL300809A (en) * | 1962-11-22 | |||
| GB1051985A (en) * | 1963-02-11 | 1900-01-01 | ||
| CH435850A (en) * | 1963-06-21 | 1967-05-15 | Ciba Geigy | Process for prolonging the effectiveness of pesticides |
| FR2104969B1 (en) * | 1970-09-11 | 1973-08-10 | Geigy Ag J R | |
| US3976769A (en) * | 1970-09-11 | 1976-08-24 | Airwick Industries, Inc. | Pesticidal compositions containing phosphoric esters and divalent sulphur compounds |
| FR2112069B1 (en) * | 1970-09-11 | 1973-12-21 | Ciba Geigy Ag | |
| US3846557A (en) * | 1972-05-26 | 1974-11-05 | Univ California | Bait for synanthropic flies and method for making same |
| IT1194595B (en) * | 1979-11-29 | 1988-09-22 | Montedison Spa | SOLID FORMULATIONS CONTAINING FERORMONES |
| IT1129711B (en) * | 1980-01-23 | 1986-06-11 | Montedison Spa | SOLID FORMULATIONS CONTAINING FERORMONES |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2744128A (en) * | 1952-02-29 | 1956-05-01 | Shell Dev | Olefinically unsaturated phosphates |
| US2894014A (en) * | 1955-12-28 | 1959-07-07 | Shell Dev | Complex esters of beta-phosphato-alpha, beta-olefinically unsaturated monocarboxylic acids |
| US2865944A (en) * | 1955-12-28 | 1958-12-23 | Shell Dev | Complex amido-substituted esters of beta-phosphato-alpha, beta-olefinically unsaturated monocarboxylic acids |
| US2913367A (en) * | 1956-03-09 | 1959-11-17 | Thomas P Dawson | Some phosphorus containing derivatives of alkyl acetothiolacetate |
| NL98565C (en) * | 1956-11-22 | 1900-01-01 | ||
| US2967127A (en) * | 1957-05-29 | 1961-01-03 | Minerals & Chem Philipp Corp | Toxicant carrier and pesticidal composition containing same |
| US2956073A (en) * | 1960-04-13 | 1960-10-11 | Shell Oil Co | Insecticidally active esters of phosphorus acids and preparation of the same |
-
0
- NL NL273220D patent/NL273220A/xx unknown
- BE BE612272D patent/BE612272A/xx unknown
- NL NL131123D patent/NL131123C/xx active
-
1961
- 1961-01-06 US US80996A patent/US3097128A/en not_active Expired - Lifetime
-
1962
- 1962-01-04 GB GB372/62A patent/GB958421A/en not_active Expired
- 1962-01-04 DK DK4062AA patent/DK102884C/en active
- 1962-01-04 CH CH10762A patent/CH437905A/en unknown
- 1962-01-04 ES ES0273412A patent/ES273412A1/en not_active Expired
- 1962-01-04 DE DE1962S0077409 patent/DE1280001C2/en not_active Expired
- 1962-01-04 BR BR135470/62A patent/BR6235470D0/en unknown
-
1964
- 1964-10-28 OA OA50490A patent/OA00413A/en unknown
-
1965
- 1965-12-30 MY MY33/65A patent/MY6500033A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MY6500033A (en) | 1965-12-31 |
| DK102884C (en) | 1965-10-18 |
| BR6235470D0 (en) | 1973-05-10 |
| US3097128A (en) | 1963-07-09 |
| ES273412A1 (en) | 1962-06-01 |
| NL273220A (en) | |
| OA00413A (en) | 1966-05-15 |
| BE612272A (en) | |
| DE1280001B (en) | 1968-10-10 |
| CH437905A (en) | 1967-06-15 |
| NL131123C (en) | |
| DE1280001C2 (en) | 1969-06-04 |
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