GB958355A - Improvements in or relating to the recovery of gold and silver from aqueous cyanide liquors and to anion exchange resins therefor - Google Patents
Improvements in or relating to the recovery of gold and silver from aqueous cyanide liquors and to anion exchange resins thereforInfo
- Publication number
- GB958355A GB958355A GB29895/59A GB2989559A GB958355A GB 958355 A GB958355 A GB 958355A GB 29895/59 A GB29895/59 A GB 29895/59A GB 2989559 A GB2989559 A GB 2989559A GB 958355 A GB958355 A GB 958355A
- Authority
- GB
- United Kingdom
- Prior art keywords
- groups
- anion
- gold
- alkyl groups
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G7/00—Compounds of gold
- C01G7/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B01J41/05—Processes using organic exchangers in the strongly basic form
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G5/00—Compounds of silver
- C01G5/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Gold and/or silver values are recovered from a gold and/or silver bearing aqueous cyanide liquor by treatment with one or more anion-exchange mixed base resins containing base groups of the type -CH2NRR0, where R and R0 are each an alkyl group which may be the same or different having at least 3 carbon atoms, such alkyl groups being branched or unbranched, the branch not being in the one or two carbon position of the groups, and from 1 to 35% of quaternary groups of the type -CH2NR1R2R3, where R1, R2 and R3 are alkyl groups which may be the same or different and which contain either two or three carbon atoms, and then eluting the gold and/or silver values from the resin, preferably by means of an aqueous or polar organic solvent solution of an alkali metal or ammonium thiocyanate. The anion-exchange resins may be based upon a cross-linked polystyrene e.g. a polystyrene obtained by using 1% to 5% of divinyl benzene or other cross-linking agent. Such a resin may be converted into an anion-exchange resin by chloromethylation (using chloromethyl ether in the presence of catalyst) followed by amination with one or more secondary amines RR0NH and one or more tertiary amines R1R2R3N. The alkyl groups R, R0 in the secondary amines should be those required in the main anion-exchange group -CH2NRR0, and R1, R2, R3 in the tertiary amines should be those required in -CH2NR1R2R3. Specifications 808,909, 808,910 and 958,356 are referred to.ALSO:An N-methano dialkylamine anion-exchange mixed base resin containing base groups of the type -CH2NRR0 and from 1 to 35% of quater nary groups of the type -CH2NR1R2R3 where R and R0 are each alkyl groups, the same or different, having at least three carbon atoms, said alkyl groups being unbranched or branched, the branch not being in the one or two carbon position of the groups, and R1, R2 and R3 are alkyl groups which may be the same or different and which contain either two or three carbon atoms is used to recover gold and silver values (see Division C1). Preferably R and R0 should have at least four carbon atoms. The resin may be based on a cross-linked polystyrene, such as a modified polystyrene obtained by using 1 to 5% of divinyl-benzene as a cross-linking agent. Such resins are preferably converted into the required anion-exchange resins by first halomethylating e.g. chloromethylating using chloromethyl ether in the presence of stannic chloride, the more volatile reaction products boiling below 53 DEG C. being removed by fractional distillation during the early stages of the chloromethylation, and then aminating with one or more secondary amines RR0NH and one or more tertiary amines R1R2R3N. The amination, which may be performed with or without water, is preferably carried out in the presence of a polystyrene swelling agent such as dioxane or chlorobenzene. In the examples chloromethylated polystyrene beads are treated with di-n-butylamine and either triethylamine or tri-n-propylamine. Specifications 808,909, 808,910 and 958,356 are referred to.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB472/64A GB958356A (en) | 1959-09-02 | 1959-09-02 | Improvements in or relating to the recovery of gold and silver from aqueous cyanide liquors and to anion exchange resins therefor |
GB29895/59A GB958355A (en) | 1959-09-02 | 1959-09-02 | Improvements in or relating to the recovery of gold and silver from aqueous cyanide liquors and to anion exchange resins therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB29895/59A GB958355A (en) | 1959-09-02 | 1959-09-02 | Improvements in or relating to the recovery of gold and silver from aqueous cyanide liquors and to anion exchange resins therefor |
Publications (1)
Publication Number | Publication Date |
---|---|
GB958355A true GB958355A (en) | 1964-05-21 |
Family
ID=10298923
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB472/64A Expired GB958356A (en) | 1959-09-02 | 1959-09-02 | Improvements in or relating to the recovery of gold and silver from aqueous cyanide liquors and to anion exchange resins therefor |
GB29895/59A Expired GB958355A (en) | 1959-09-02 | 1959-09-02 | Improvements in or relating to the recovery of gold and silver from aqueous cyanide liquors and to anion exchange resins therefor |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB472/64A Expired GB958356A (en) | 1959-09-02 | 1959-09-02 | Improvements in or relating to the recovery of gold and silver from aqueous cyanide liquors and to anion exchange resins therefor |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB958356A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0046025A2 (en) * | 1980-08-07 | 1982-02-17 | Commonwealth Scientific And Industrial Research Organisation | Selective extraction of gold |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2166140B (en) * | 1984-10-27 | 1989-06-07 | Ion Exchange | Novel adsorbents for use in the purification of water and other chemicals and a process for preparing same |
-
1959
- 1959-09-02 GB GB472/64A patent/GB958356A/en not_active Expired
- 1959-09-02 GB GB29895/59A patent/GB958355A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0046025A2 (en) * | 1980-08-07 | 1982-02-17 | Commonwealth Scientific And Industrial Research Organisation | Selective extraction of gold |
EP0046025A3 (en) * | 1980-08-07 | 1982-03-10 | Commonwealth Scientific And Industrial Research Organization | Selective extraction of gold |
Also Published As
Publication number | Publication date |
---|---|
GB958356A (en) | 1964-05-21 |
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