GB826144A - Process for removing oil from oil-in-water emulsions - Google Patents
Process for removing oil from oil-in-water emulsionsInfo
- Publication number
- GB826144A GB826144A GB706156A GB706156A GB826144A GB 826144 A GB826144 A GB 826144A GB 706156 A GB706156 A GB 706156A GB 706156 A GB706156 A GB 706156A GB 826144 A GB826144 A GB 826144A
- Authority
- GB
- United Kingdom
- Prior art keywords
- resin
- oil
- regenerated
- passed
- sodium chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/04—Dewatering or demulsification of hydrocarbon oils with chemical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
To recover oil from an oil-in-water emulsion which may contain an emulsifier, stabilizer, salts or the like, the emulsion is passed through an adsorbent artificial resin capable of anion exchange and the exhausted resin is regenerated in a manner appropriate to it. In one example an anion-exchange resin based on a polyalkylene-imine resin is converted into salt form and there is passed through it an emulsion containing crude oil, an anion-active wetting agent and sodium chloride, and having a pH value of from 10 to 11. The treated liquid has a pH below 3. The oil is removed from the resin by carbon tetrachloride, and the resin is regenerated by a mixture of sodium chloride and hydrochloric acid. The solvent layer of the regenerant effluent is separated, and after being re-used several times, the solvent and crude oil are recovered by distillation. In a second example a tanker rinsing water containing crude mineral oil (containing naphthenic acids), an anion-active wetting agent and sodium chloride, and having a pH value of 9.5 is passed through a wide-latticed condensation resin based on an aromatic amine, e.g. metaphenylene diamine, and formaldehyde, and previously converted to the chlorineladen condition. After use the resin is washed, and then regenerated with caustic soda and hydrochloric acid with a short intermediate washing. The rinsing water and regenerant washings are combined, and removed from the oil, which precipitates rapidly. In a third example, an oil-in-water emulsion containing mineral oil, an alcohol sulphonate as an emulsifier, and dissolved salt, is passed through a copolymer of 2-vinyl-pyridine which is crosslinked with para-divinyl-benzene and quaternated at the pyridine nitrogen atom. The resin is regenerated with hydrochloric acid and caustic soda solution saturated with sodium chloride, and after brief washing the resin is washed with petroleum ether from which latter the oil is recovered by distillation.ALSO:To remove oil from an oil-in-water emulsion which may contain an emulsifier, stabiliser, salts or the like, the emulsion is passed through an adsorbent artificial resin capable of anion exchange and the exhausted resin is regenerated in a manner appropriate to it. In one example an anion-exchange resin based on a polyalkylene imine resin is converted into salt form and there is passed through it an emulsion containing crude oil, an anion-active wetting agent and sodium chloride, and having a pH value of from 10 to 11. The treated liquid has a pH below 3. The oil is removed from the resin by carbon tetrachloride, and the resin is regenerated by a mixture of sodium chloride and hydrochloric acid. The solvent layer of the regenerant effluent is separated, and after being re-used several times, the solvent and crude oil are recovered by distillation. In a second example, a tanker rinsing water containing crude mineral oil (containing naphthenic acids), an anion-active wetting agent and sodium chloride, and having a pH value of 9,5 is passed through a wide-latticed condensation resin based on an aromatic amine, e.g. metaphenylene diamine, and formaldehyde, and previously converted to the chloride-laden condition. After use the resin is washed, and then regenerated with caustic soda solution and hydrochloric acid with a short intermediate washing. The rinsing water and regenerant washings are combined, and removed from the oil which precipitates rapidly. In a third example an oil-in-water emulsion containing mineral oil, an alcohol sulphonate as an emulsifier and dissolved salt is passed through a copolymer of 2-vinyl-pyridine which is cross-linked with paradivinyl-benzene and quaternated at the pyridine nitrogen atom. The resin is regenerated with hydrochloric acid and caustic soda solution saturated with sodium chloride, and after brief washing the resin is washed with petroleum ether (boiling at 40-60 DEG C.), residual amounts of the latter, remaining in the resin, being removed by methanol. The dissolved oil is recovered by distilling the petroleum ether.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB706156A GB826144A (en) | 1956-03-06 | 1956-03-06 | Process for removing oil from oil-in-water emulsions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB706156A GB826144A (en) | 1956-03-06 | 1956-03-06 | Process for removing oil from oil-in-water emulsions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB826144A true GB826144A (en) | 1959-12-31 |
Family
ID=9825865
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB706156A Expired GB826144A (en) | 1956-03-06 | 1956-03-06 | Process for removing oil from oil-in-water emulsions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB826144A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0535910A2 (en) * | 1991-10-02 | 1993-04-07 | Exxon Research And Engineering Company | Method for improving the demulsibility of base oils |
US5466364A (en) * | 1993-07-02 | 1995-11-14 | Exxon Research & Engineering Co. | Performance of contaminated wax isomerate oil and hydrocarbon synthesis liquid products by silica adsorption |
US6416670B1 (en) | 1999-03-12 | 2002-07-09 | Mpr Services, Inc. | Regenerable hydrocarbon filter |
WO2016149506A1 (en) * | 2015-03-17 | 2016-09-22 | Donaldson Company, Inc. | Hydrocarbon-in-water purification anion-exchange system |
US20180079972A1 (en) * | 2015-03-17 | 2018-03-22 | Donaldson Company, Inc. | Hydrocarbon-in-water purification system |
CN112694911A (en) * | 2019-10-23 | 2021-04-23 | 中国石油化工股份有限公司 | Method for treating crude oil containing petroleum sulfonate |
-
1956
- 1956-03-06 GB GB706156A patent/GB826144A/en not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0535910A2 (en) * | 1991-10-02 | 1993-04-07 | Exxon Research And Engineering Company | Method for improving the demulsibility of base oils |
EP0535910A3 (en) * | 1991-10-02 | 1993-05-19 | Exxon Research And Engineering Company | Method for improving the demulsibility of base oils |
US5282960A (en) * | 1991-10-02 | 1994-02-01 | Exxon Research And Engineering Company | Method for improving the demulsibility of base oils |
US5466364A (en) * | 1993-07-02 | 1995-11-14 | Exxon Research & Engineering Co. | Performance of contaminated wax isomerate oil and hydrocarbon synthesis liquid products by silica adsorption |
US6416670B1 (en) | 1999-03-12 | 2002-07-09 | Mpr Services, Inc. | Regenerable hydrocarbon filter |
WO2016149506A1 (en) * | 2015-03-17 | 2016-09-22 | Donaldson Company, Inc. | Hydrocarbon-in-water purification anion-exchange system |
US20180079972A1 (en) * | 2015-03-17 | 2018-03-22 | Donaldson Company, Inc. | Hydrocarbon-in-water purification system |
US20180079971A1 (en) * | 2015-03-17 | 2018-03-22 | Donaldson Company, Inc. | Hydrocarbon-in-water purification anion-exchange system |
US10526548B2 (en) * | 2015-03-17 | 2020-01-07 | Donaldson Company, Inc. | Hydrocarbon-in-water purification system |
US10604707B2 (en) * | 2015-03-17 | 2020-03-31 | Donaldson Company, Inc. | Hydrocarbon-in-water purification anion-exchange system |
US11220636B2 (en) | 2015-03-17 | 2022-01-11 | Donaldson Company, Inc. | Hydrocarbon-in-water purification system |
CN112694911A (en) * | 2019-10-23 | 2021-04-23 | 中国石油化工股份有限公司 | Method for treating crude oil containing petroleum sulfonate |
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