GB957136A - Improvements in or relating to novel paper sizing process - Google Patents

Improvements in or relating to novel paper sizing process

Info

Publication number
GB957136A
GB957136A GB30853/62A GB3085362A GB957136A GB 957136 A GB957136 A GB 957136A GB 30853/62 A GB30853/62 A GB 30853/62A GB 3085362 A GB3085362 A GB 3085362A GB 957136 A GB957136 A GB 957136A
Authority
GB
United Kingdom
Prior art keywords
agent
cationic
sizing
sizing agent
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30853/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ingredion Inc
Original Assignee
National Starch and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Starch and Chemical Corp filed Critical National Starch and Chemical Corp
Publication of GB957136A publication Critical patent/GB957136A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D21H17/15—Polycarboxylic acids, e.g. maleic acid
    • D21H17/16—Addition products thereof with hydrocarbons

Landscapes

  • Paper (AREA)

Abstract

The water resistance of paper is improved by dispersing in the paper pulp a sizing agent consisting of a cyclic dicarboxylic acid anhydride of formula <FORM:0957136/D1-D2/1> where R represents a di- or tri-methylene radical and wherein R1 is a hydrophobic group containing more than 5 carbon atoms selected from alkyl, alkenyl, aralkyl or aralkenyl groups. Substituted succinic and glutaric acid anhydrides fall within the above formula. Intimate and uniform dispersion of the sizing agent within the paper pulp is important and may be achieved by agitation, by addition of the sizing agent of the form of an emulsion or by the simultaneous addition of a dispersing agent. The sizing agent is preferably added to the pulp in conjunction with a cationic agent which improves the retention in the paper pulp of the sizing agent as well as serving to bring it into intimate contact with the fibres. The cationic agent agent may advantageously fulfill the additional function of emulsifier for the sizing agent and suitable compounds for this purpose include primary, secondary, tertiary, and quaternary amine-modified starches, certain nitrogen substituted starch derivatives as well as certain sulphonium and phosphonium starch derivatives. Other cationic agents include alum, aluminium chloride, long chain fatty amines, sodium aluminate, polyacrylamide, chomic sulphate, animal glue, certain thermosetting resins and polyamide polymers. Non-cationic emulsifiers which may be used to emulsify the sizing agents include such hydrocolloids as ordinary starches, non-cationic starch derivatives, dextrines, carboxymethyl cellulose, gum arabic, gelatin and polyvinyl alcohol. In addition certain surfactants such as polyoxyethylene sorbitan trioleate. polyoxyethylene sorbitol hexaoleate, polyoxyethylene sorbital laurate, and polyoxyethylene sorbitol oleate laurate may be used as emulsifiers. The sizing agents are normally added in amounts ranging from 0.05 to 5% of the dry weight of the pulp and the cationic agents in amounts ranging from 0.5 to 2.0 parts per 1.0 part by weight of the sizing agent. The water resistance of the paper may be further improved by post curing of the finished paper sheet. The sizing agents may be used in conjunction with other sizing agents, fillers, pigments or additives such as alum. Specification 765,880 is referred to.
GB30853/62A 1961-09-08 1962-08-10 Improvements in or relating to novel paper sizing process Expired GB957136A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US136741A US3102064A (en) 1961-09-08 1961-09-08 Novel paper sizing process

Publications (1)

Publication Number Publication Date
GB957136A true GB957136A (en) 1964-05-06

Family

ID=22474163

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30853/62A Expired GB957136A (en) 1961-09-08 1962-08-10 Improvements in or relating to novel paper sizing process

Country Status (4)

Country Link
US (1) US3102064A (en)
DE (1) DE1289405B (en)
GB (1) GB957136A (en)
NL (2) NL129371C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
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GB2125079A (en) * 1982-06-18 1984-02-29 Fuji Photo Film Co Ltd Pressure-sensitive recording sheets
GB2130265A (en) * 1982-11-15 1984-05-31 United States Gypsum Co Gypsum board
FR2897280A1 (en) * 2006-02-13 2007-08-17 Arjowiggins Soc Par Actions Si Preparation of alkenyl succinic anhydride sizing emulsion useful for paper sizing, comprises ultrasonic usage
CN110904728A (en) * 2019-11-21 2020-03-24 陕西科技大学 Gelatin-based papermaking sizing agent based on hydrogen bond effect and preparation method thereof

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US3139373A (en) * 1962-06-08 1964-06-30 Allied Chem Process for the internal sizing of paper with a salt of a substituted succinic acid
US4040900A (en) * 1974-05-20 1977-08-09 National Starch And Chemical Corporation Method of sizing paper
USRE29960E (en) * 1976-05-05 1979-04-10 National Starch And Chemical Corp. Method of sizing paper
US4210685A (en) * 1978-05-22 1980-07-01 Basf Wyandotte Corporation Polyester-starch sized paper, sizing composition, and process therefor
US4311767A (en) * 1980-02-25 1982-01-19 National Gypsum Company Gypsum wallboard and method for producing same
US4364795A (en) * 1980-02-25 1982-12-21 National Gypsum Company Gypsum wallboard and method for producing same
US4372814A (en) * 1981-05-13 1983-02-08 United States Gypsum Company Paper having mineral filler for use in the production of gypsum wallboard
JPS5836297A (en) * 1981-08-22 1983-03-03 日本石油化学株式会社 Paper size agent
DE3274133D1 (en) * 1981-09-15 1986-12-11 Hercules Inc Aqueous sizing compositions
US4529447A (en) * 1982-06-11 1985-07-16 Sanyo Chemical Industries, Ltd. Sizing composition
IL69397A (en) * 1982-08-20 1987-12-20 Chevron Res Alkenyl succinic anhydride composition and methods of sizing paper and treating cellulosic fabrics
US4431826A (en) * 1982-08-20 1984-02-14 Chevron Research Company Process for the preparation of alkenyl succinic anhydride
JPS59144696A (en) * 1983-02-07 1984-08-18 荒川化学工業株式会社 Paper size agent
DE3404086A1 (en) * 1983-02-07 1984-08-09 Arakawa Kagaku Kogyo K.K., Osaka Size composition for paper manufacture
US4545855A (en) * 1983-03-31 1985-10-08 Chevron Research Company Substituted succinic anhydride/emulsifier composition
US4810301A (en) * 1983-07-22 1989-03-07 Seiko Kagaku Kogyo Co., Ltd. Composition for sizing agent and process for using the same composition
US4545856A (en) * 1984-02-28 1985-10-08 Chevron Research Company Stable substituted succinic anhydride/ether-ester emulsifier composition and methods for its use
US4657946A (en) * 1984-06-25 1987-04-14 Nalco Chemical Company Paper sizing method and emulsion
JPS61234927A (en) * 1984-09-25 1986-10-20 Seiko Kagaku Kogyo Co Ltd Aqueous liquid dispersant of substituted succinic anhydride and its production
US4606773A (en) * 1984-12-10 1986-08-19 Nalco Chemical Company Emulsification of alkenyl succinic anhydride sizing agents
US4728366A (en) * 1985-10-03 1988-03-01 National Starch And Chemical Corporation Storage stable paper size composition containing ethoxylated castor oil
DE3661851D1 (en) * 1985-10-03 1989-02-23 Nat Starch Chem Corp Storage stable paper size composition containing ethoxylated lanolin
US4747910A (en) * 1985-10-03 1988-05-31 National Starch And Chemical Corporation Storage stable paper size composition containing ethoxylated lanolin
US4711671A (en) * 1985-10-03 1987-12-08 National Starch And Chemical Corporation Storage stable paper size composition containing ethoxylated lanolin
US4832792A (en) * 1985-10-03 1989-05-23 Mazzarella Emil D Storage stable paper size composition containing ethoxylated castor oil
US4687519A (en) * 1985-12-20 1987-08-18 National Starch And Chemical Corporation Paper size compositions
US4721655A (en) * 1985-12-20 1988-01-26 National Starch And Chemical Corporation Paper size compositions
JPS6328999A (en) * 1986-07-22 1988-02-06 星光化学工業株式会社 Papermaking method
SE461404C (en) * 1988-06-22 1999-11-15 Betzdearborn Inc Gluing composition, process for making thereof, process for making glued paper, and glued paper
US5176748A (en) * 1988-07-05 1993-01-05 Bercen, Inc. Alkenyl succinic anhydride emulsion
US5268204A (en) * 1992-02-28 1993-12-07 The Mead Corporation Method for producing decorative paper using a slot coater, decorative paper, and decorative laminates prepared therefrom
US5601930A (en) * 1994-04-13 1997-02-11 The Mead Corporation Decor sheet and decorative laminates prepared therefrom
GB2293991B (en) 1994-10-14 1998-06-10 Ecc Int Ltd Improving the quality of coated paper
US5885340A (en) * 1994-10-14 1999-03-23 Ecc International Ltd. Quality of multiple coated paper
US5653915A (en) * 1995-05-10 1997-08-05 Pardikes; Dennis G. Method of preparing polymer succinic anhydride
US5595631A (en) * 1995-05-17 1997-01-21 National Starch And Chemical Investment Holding Corporation Method of paper sizing using modified cationic starch
US5962555A (en) * 1996-06-25 1999-10-05 Buckman Laboratories International, Inc. ASA sizing emulsions containing low and high molecular weight cationic polymers
ID21891A (en) * 1997-02-04 1999-08-05 Cytec Tech Corp ADHESIVE EMULSIONS
US6093217A (en) * 1997-02-05 2000-07-25 Akzo Nobel N.V. Sizing of paper
SE9704930D0 (en) * 1997-02-05 1997-12-30 Akzo Nobel Nv Sizing of paper
CA2327293C (en) * 1998-04-06 2008-01-29 Calgon Corporation Alkenyl succinic anhydride size emulsification with a natural gum for paper products
US6491790B1 (en) 1998-09-10 2002-12-10 Bayer Corporation Methods for reducing amine odor in paper
US6042691A (en) * 1998-12-08 2000-03-28 Plasmine Technology, Inc. Cationic dispersions of fortified and modified rosins for use as paper sizing agents
US6225437B1 (en) 1999-06-24 2001-05-01 Albemarle Corporation Sizing agents of enhanced performance capabilities
US6231659B1 (en) 1999-06-24 2001-05-15 Albemarle Corporation Sizing agents and starting materials for their preparation
US6444024B1 (en) 1999-12-16 2002-09-03 Akzo Nobel Nv Sizing composition
US6576049B1 (en) 2000-05-18 2003-06-10 Bayer Corporation Paper sizing compositions and methods
CA2395644C (en) * 2000-10-24 2009-04-14 Georgia-Pacific Resins, Inc. Emulsification of alkenyl succinic anhydride size
US6867171B2 (en) * 2002-11-27 2005-03-15 Chevron Oronitz Company Llc Low molecular weight branched alkenyl succinic acid derivatives prepared from low molecular weight polyisobutene and unsaturated acidic reagents
US20060060814A1 (en) * 2002-12-17 2006-03-23 Lucyna Pawlowska Alkenylsuccinic anhydride surface-applied system and method for using the same
TW200504265A (en) * 2002-12-17 2005-02-01 Bayer Chemicals Corp Alkenylsuccinic anhydride surface-applied system and uses thereof
US7943789B2 (en) * 2002-12-17 2011-05-17 Kemira Oyj Alkenylsuccinic anhydride composition and method of using the same
DE10349727A1 (en) * 2003-10-23 2005-05-25 Basf Ag Solid blends of a reactive sizing agent and starch, process for their preparation and their use
JP4022595B2 (en) * 2004-10-26 2007-12-19 コニカミノルタオプト株式会社 Imaging device
US20060094798A1 (en) * 2004-11-04 2006-05-04 Cotter Terrence E Method of emulsifying substituted cyclic dicarboxylic acid anhydride sizing agents and emulsion for papermaking
WO2006084170A2 (en) * 2005-02-04 2006-08-10 Mineral And Coal Technologies, Inc. Improving the separation of diamond from gangue minerals
US7455751B2 (en) * 2005-04-15 2008-11-25 Nalco Company Use of alkenyl succinic anhydride compounds derived from symmetrical olefins in internal sizing for paper production
US20090281212A1 (en) * 2005-04-28 2009-11-12 Lucyna Pawlowska Alkenylsuccinic anhydride surface-applied system and uses thereof
DE102005055541A1 (en) * 2005-11-18 2007-05-24 Basf Ag Alkenylsuccinic anhydrides from oligomers of C4 to C8 olefins and maleic anhydride, process for their preparation and their use
US7892398B2 (en) * 2005-12-21 2011-02-22 Akzo Nobel N.V. Sizing of paper
US7938934B2 (en) * 2006-01-25 2011-05-10 Nalco Company ASA emulsification with ultrasound
JP2010526945A (en) * 2007-05-09 2010-08-05 バックマン・ラボラトリーズ・インターナショナル・インコーポレーテッド ASA sizing emulsion for paper and board
US8088250B2 (en) 2008-11-26 2012-01-03 Nalco Company Method of increasing filler content in papermaking
US8440768B2 (en) * 2008-06-19 2013-05-14 Buckman Laboratories International, Inc. Low amidine content polyvinylamine, compositions containing same and methods
US8852400B2 (en) 2010-11-02 2014-10-07 Ecolab Usa Inc. Emulsification of alkenyl succinic anhydride with an amine-containing homopolymer or copolymer
US8747616B2 (en) 2012-09-12 2014-06-10 Ecolab Usa Inc Method for the emulsification of ASA with polyamidoamine epihalohydrin (PAE)
CZ305143B6 (en) * 2012-11-21 2015-05-20 Explosia A.S. Combustible mass in leaf or shaped form based on nitrocellulose and cellulose or synthetic fibers with addition of a hydrophobization additive and process for preparing thereof
US9567708B2 (en) 2014-01-16 2017-02-14 Ecolab Usa Inc. Wet end chemicals for dry end strength in paper
US9920482B2 (en) 2014-10-06 2018-03-20 Ecolab Usa Inc. Method of increasing paper strength
US9702086B2 (en) 2014-10-06 2017-07-11 Ecolab Usa Inc. Method of increasing paper strength using an amine containing polymer composition
CN106812019B (en) 2015-11-30 2018-11-09 艺康美国股份有限公司 Remove auxiliary agent
CN106917324B (en) 2015-12-25 2019-11-08 艺康美国股份有限公司 A kind of paper-making sizing method and its paper of preparation
CN106928400B (en) * 2015-12-31 2020-09-08 艺康美国股份有限公司 Amphoteric polymer and alkenyl succinic anhydride emulsion containing same
WO2017197380A1 (en) 2016-05-13 2017-11-16 Ecolab Usa Inc. Tissue dust reduction
CN115652684B (en) * 2022-09-08 2024-03-26 上海昶法新材料有限公司 Nano modified cation dispersed rosin size compound and preparation method thereof

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US2680751A (en) * 1951-09-25 1954-06-08 Du Pont Preparation of cyclic anhydrides of aromatic dicarboxylic acids
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US3016325A (en) * 1955-11-01 1962-01-09 Electro Chem Fiber Seal Corp Process of combining water-insoluble additament with organic fibrous material
US3022321A (en) * 1957-12-12 1962-02-20 Gen Aniline & Film Corp Preparation of adducts of maleic anhydride and dienes derived from the addition of formals, acetals and acylals to olefins

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2125079A (en) * 1982-06-18 1984-02-29 Fuji Photo Film Co Ltd Pressure-sensitive recording sheets
GB2130265A (en) * 1982-11-15 1984-05-31 United States Gypsum Co Gypsum board
FR2897280A1 (en) * 2006-02-13 2007-08-17 Arjowiggins Soc Par Actions Si Preparation of alkenyl succinic anhydride sizing emulsion useful for paper sizing, comprises ultrasonic usage
CN110904728A (en) * 2019-11-21 2020-03-24 陕西科技大学 Gelatin-based papermaking sizing agent based on hydrogen bond effect and preparation method thereof
CN110904728B (en) * 2019-11-21 2022-03-22 陕西科技大学 Gelatin-based papermaking sizing agent based on hydrogen bond effect and preparation method thereof

Also Published As

Publication number Publication date
US3102064A (en) 1963-08-27
DE1289405B (en) 1969-02-13
NL129371C (en)
NL282997A (en)

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