GB955969A - Complex organo-silicic compounds and method of preparing same - Google Patents
Complex organo-silicic compounds and method of preparing sameInfo
- Publication number
- GB955969A GB955969A GB1636460A GB1636460A GB955969A GB 955969 A GB955969 A GB 955969A GB 1636460 A GB1636460 A GB 1636460A GB 1636460 A GB1636460 A GB 1636460A GB 955969 A GB955969 A GB 955969A
- Authority
- GB
- United Kingdom
- Prior art keywords
- siliconate
- potassium
- acid
- potassium siliconate
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title 1
- 229910052700 potassium Inorganic materials 0.000 abstract 17
- 239000011591 potassium Substances 0.000 abstract 17
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 4
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 abstract 3
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 235000010323 ascorbic acid Nutrition 0.000 abstract 2
- 229960005070 ascorbic acid Drugs 0.000 abstract 2
- 239000011668 ascorbic acid Substances 0.000 abstract 2
- 150000007522 mineralic acids Chemical class 0.000 abstract 2
- 150000007524 organic acids Chemical class 0.000 abstract 2
- 235000011007 phosphoric acid Nutrition 0.000 abstract 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 abstract 2
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 102000053602 DNA Human genes 0.000 abstract 1
- 108020004414 DNA Proteins 0.000 abstract 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 abstract 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 abstract 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 abstract 1
- XMEKHKCRNHDFOW-UHFFFAOYSA-N O.O.[Na].[Na] Chemical compound O.O.[Na].[Na] XMEKHKCRNHDFOW-UHFFFAOYSA-N 0.000 abstract 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 229960001138 acetylsalicylic acid Drugs 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 239000012431 aqueous reaction media Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- FCPVYOBCFFNJFS-LQDWTQKMSA-M benzylpenicillin sodium Chemical compound [Na+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)CC1=CC=CC=C1 FCPVYOBCFFNJFS-LQDWTQKMSA-M 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 235000013922 glutamic acid Nutrition 0.000 abstract 1
- 239000004220 glutamic acid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 abstract 1
- 229920000669 heparin Polymers 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 235000001968 nicotinic acid Nutrition 0.000 abstract 1
- 229960003512 nicotinic acid Drugs 0.000 abstract 1
- 239000011664 nicotinic acid Substances 0.000 abstract 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 abstract 1
- 150000003016 phosphoric acids Chemical class 0.000 abstract 1
- JTHVJAYASQZXKB-UHFFFAOYSA-M potassium;2-acetyloxybenzoate Chemical compound [K+].CC(=O)OC1=CC=CC=C1C([O-])=O JTHVJAYASQZXKB-UHFFFAOYSA-M 0.000 abstract 1
- 229960004889 salicylic acid Drugs 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 239000001509 sodium citrate Substances 0.000 abstract 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/695—Silicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/335—Heterocyclic compounds having oxygen as the only ring hetero atom, e.g. fungichromin
- A61K31/365—Lactones
- A61K31/375—Ascorbic acid, i.e. vitamin C; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0836—Compounds with one or more Si-OH or Si-O-metal linkage
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Organic Chemistry (AREA)
- Silicon Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
A method of making organo-silicon complexes of the general formula [(R1)nSi(OMe)4-n-x], [A]y, 2H2O, where n=1, 2 or 3; x, y and z have finite values which may be the same or different; R1 is a linear or branched chain aliphatic radical or an aromatic radical; Me is hydrogen or an alkali metal and A is an organic or inorganic acid or derivative thereof, comprises slowly adding an aqueous solution of an alkali metal siliconate to an organic or inorganic acid or a derivative thereof, with vigorous agitation, whilst maintaining the aqueous reaction medium at a pH between 1 and 8. Specified acids are formic, acetic, propionic, sebacic, a -naphthalene-acetic, citric, tartaric, lactic, glutamic, nicotinic, ascorbic, forbic, salicylic, acetyl salicylic, gentisic, pentothenic, hydriodic and phosphoric acids. In the examples, complexes are made from:- (1) and (3) potassium siliconate and ascorbic acid; (4) sodium siliconate and ascorbic acid; (5) potassium siliconate and nicotinic acid; (6) potassium siliconate and hydriodic acid; (7) potassium siliconate and phosphoric acid; (8) potassium siliconate and acetyl-salicylic acid; (9) potassium siliconate and salicylic acid; (10) and (11) potassium siliconate and the disodium salt dihydrate of ethylene-diamino-tetraacetic acid; (12) potassium siliconate and sebacid acid; (13) and (14) potassium siliconate and potassium acetyl-salicylate; (15) potassium siliconate and sodium heparinate; (16) potassium siliconate and sodium benzyl-penicillinate; (17) potassium siliconate and the sodium salt of carboxymethyl cellulose; (18) potassium siliconate and glutamic acid; (20) potassium siliconate and potassium iodide; (21) potassium siliconate and sodium citrate; (22) potassium siliconate and the disodium salt of desoxyribonucleic acid; (23) potassium methyl siliconate and calcium pantothonate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR794405A FR1234213A (en) | 1959-05-12 | 1959-05-12 | Manufacturing process of organo-silicic complexes, complexes obtained and their applications |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB955969A true GB955969A (en) | 1964-04-22 |
Family
ID=8714673
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1636460A Expired GB955969A (en) | 1959-05-12 | 1960-05-09 | Complex organo-silicic compounds and method of preparing same |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1177639B (en) |
| GB (1) | GB955969A (en) |
| MC (1) | MC257A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0391769A1 (en) * | 1989-04-07 | 1990-10-10 | Jean Gueyne | Therapeutical product based on an organic silicon compound and polycarboxylated poly-amine, particularly useful for treatment of atherome |
| FR2645863A1 (en) * | 1989-04-12 | 1990-10-19 | Voisin Philippe | Silicon compounds and process for the manufacture thereof |
| WO2018037115A1 (en) | 2016-08-25 | 2018-03-01 | Sil'innov Scrl | Composition comprising silicon and method for preparing same |
| EP3666249A1 (en) | 2018-12-10 | 2020-06-17 | Jednostka Innowacyjno-Wdrozeniowa INWEX Spolka z Ograniczona odpowiedzialnoscia | Complexes of organic silicon compounds with boron citrate and dimethylethanolamine |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2723629A (en) * | 1950-01-30 | 1955-11-15 | Transit Res Corp | Truck bolster damping means |
| US2723211A (en) * | 1953-04-13 | 1955-11-08 | Cowles Chem Co | Stable silane triol composition and method of treating glass therewith |
-
1960
- 1960-05-09 GB GB1636460A patent/GB955969A/en not_active Expired
- 1960-05-10 MC MC222A patent/MC257A1/en unknown
- 1960-05-11 DE DEG29730A patent/DE1177639B/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0391769A1 (en) * | 1989-04-07 | 1990-10-10 | Jean Gueyne | Therapeutical product based on an organic silicon compound and polycarboxylated poly-amine, particularly useful for treatment of atherome |
| FR2645442A1 (en) * | 1989-04-07 | 1990-10-12 | Gueyne Jean | THERAPEUTIC PRODUCT BASED ON ORGANIC COMPOUND OF SILICON AND POLYCARBOXYLATED POLYAMINE, PARTICULARLY USEFUL FOR THE TREATMENT OF ATHEROMA |
| US5087452A (en) * | 1989-04-07 | 1992-02-11 | Jean Gueyne | Therapeutic product based on an organic compound of silicon and polycarboxylated polyamine, particularly useful in the treatment of atheroma |
| FR2645863A1 (en) * | 1989-04-12 | 1990-10-19 | Voisin Philippe | Silicon compounds and process for the manufacture thereof |
| WO2018037115A1 (en) | 2016-08-25 | 2018-03-01 | Sil'innov Scrl | Composition comprising silicon and method for preparing same |
| EP3666249A1 (en) | 2018-12-10 | 2020-06-17 | Jednostka Innowacyjno-Wdrozeniowa INWEX Spolka z Ograniczona odpowiedzialnoscia | Complexes of organic silicon compounds with boron citrate and dimethylethanolamine |
Also Published As
| Publication number | Publication date |
|---|---|
| MC257A1 (en) | 1961-08-22 |
| DE1177639B (en) | 1964-09-10 |
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