GB948961A - Polymers derived from polyvinyl phenol - Google Patents

Polymers derived from polyvinyl phenol

Info

Publication number
GB948961A
GB948961A GB2414/60A GB241460A GB948961A GB 948961 A GB948961 A GB 948961A GB 2414/60 A GB2414/60 A GB 2414/60A GB 241460 A GB241460 A GB 241460A GB 948961 A GB948961 A GB 948961A
Authority
GB
United Kingdom
Prior art keywords
cross
divinyl
formyl
effected
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2414/60A
Inventor
Donald Ian Packham
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Research Development Corp UK
National Research Development Corp of India
Original Assignee
National Research Development Corp UK
National Research Development Corp of India
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Research Development Corp UK, National Research Development Corp of India filed Critical National Research Development Corp UK
Priority to GB2414/60A priority Critical patent/GB948961A/en
Priority to GB43675/60A priority patent/GB948962A/en
Publication of GB948961A publication Critical patent/GB948961A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/02—Esters of monocarboxylic acids
    • C08F18/12—Esters of monocarboxylic acids with unsaturated alcohols containing three or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/24—Haloalkylation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/28—Condensation with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Cross-linked polyvinyl phenols are prepared by polymerizing one or more esters of vinyl phenol in the presence of a cross-linking agent and then hydrolysing the resultant product. The ester may be that of acetic, benzoic or phenyl acetic acid, and the cross-linking agent may be divinyl benzene, divinyl toluene, divinyl naphthalene, divinyl ether or methylene-bis-acrylamide. The polymerization may be effected in benzene using as catalyst azo-bis-isobutyronitrile or a Friedel-Crafts catalyst. In examples the hydrolysis is effected with caustic soda in aqueous dioxan. The cross-linked polyvinyl phenols may be converted to resins having ion-exchange or chelating properties by introducing reactive groups such as nitro, amino, sulphonic acid, carboxylic acid, halogen, chloromethyl, formyl, formyl oximino, phosphoryl or diazo groups. Specification 948,962 is referred to.
GB2414/60A 1960-01-22 1960-01-22 Polymers derived from polyvinyl phenol Expired GB948961A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB2414/60A GB948961A (en) 1960-01-22 1960-01-22 Polymers derived from polyvinyl phenol
GB43675/60A GB948962A (en) 1960-01-22 1960-01-22 Polymers derived from polyvinyl phenols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2414/60A GB948961A (en) 1960-01-22 1960-01-22 Polymers derived from polyvinyl phenol

Publications (1)

Publication Number Publication Date
GB948961A true GB948961A (en) 1964-02-05

Family

ID=9739142

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2414/60A Expired GB948961A (en) 1960-01-22 1960-01-22 Polymers derived from polyvinyl phenol

Country Status (1)

Country Link
GB (1) GB948961A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0252706A2 (en) * 1986-07-07 1988-01-13 Hoechst Celanese Corporation Process for the preparation of poly (vinylphenol) from poly (acetoxystyrene)
EP0260104A2 (en) * 1986-09-09 1988-03-16 Celanese Corporation Process for the preparation of poly (vinylphenol) by simultaneous methanolysis and polymerization of 4-acetoxystryene
EP0263632A2 (en) * 1986-09-29 1988-04-13 Celanese Corporation Process for the ammonium hydroxide hydrolysis of polymers of acetoxystyrene to polymers of vinylphenol
EP0277721A2 (en) * 1987-01-28 1988-08-10 Hoechst Celanese Corporation Emulsion polymerization of 4-acetoxystyrene and hydrolysis to poly(p-vinylphenol)
EP0314488A2 (en) * 1987-10-30 1989-05-03 Hoechst Celanese Corporation Hydrolysis of poly (acetoxystyrene) in aqueous suspension
EP0365340A2 (en) * 1988-10-21 1990-04-25 Hoechst Celanese Corporation Copolymers of 4-hydroxystyrene and alkyl substituted-4-hydroxystyrene
EP0466359A2 (en) * 1990-06-29 1992-01-15 Hoechst Celanese Corporation Process for making low optical density polymers and copolymers for photoresists and optical applications

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0252706A2 (en) * 1986-07-07 1988-01-13 Hoechst Celanese Corporation Process for the preparation of poly (vinylphenol) from poly (acetoxystyrene)
EP0252706A3 (en) * 1986-07-07 1989-03-15 Hoechst Celanese Corporation Process for the preparation of poly (vinylphenol) from poly (acetoxystyrene)
EP0260104A3 (en) * 1986-09-09 1989-03-15 Celanese Corporation Process for the preparation of poly (vinylphenol) by simultaneous methanolysis and polymerization of 4-acetoxystryene
EP0260104A2 (en) * 1986-09-09 1988-03-16 Celanese Corporation Process for the preparation of poly (vinylphenol) by simultaneous methanolysis and polymerization of 4-acetoxystryene
EP0263632A2 (en) * 1986-09-29 1988-04-13 Celanese Corporation Process for the ammonium hydroxide hydrolysis of polymers of acetoxystyrene to polymers of vinylphenol
EP0263632A3 (en) * 1986-09-29 1989-03-15 Celanese Corporation Process for the ammonium hydroxide hydrolysis of polymers of acetoxystyrene to polymers of vinylphenol
EP0277721A2 (en) * 1987-01-28 1988-08-10 Hoechst Celanese Corporation Emulsion polymerization of 4-acetoxystyrene and hydrolysis to poly(p-vinylphenol)
EP0277721A3 (en) * 1987-01-28 1989-03-15 Hoechst Celanese Corporation Emulsion polymerization of 4-acetoxystyrene and hydrolysis to poly(p-vinylphenol)
EP0314488A2 (en) * 1987-10-30 1989-05-03 Hoechst Celanese Corporation Hydrolysis of poly (acetoxystyrene) in aqueous suspension
EP0314488A3 (en) * 1987-10-30 1990-03-21 Hoechst Celanese Corporation Hydrolysis of poly (acetoxystyrene) in aqueous suspension
EP0365340A2 (en) * 1988-10-21 1990-04-25 Hoechst Celanese Corporation Copolymers of 4-hydroxystyrene and alkyl substituted-4-hydroxystyrene
EP0365340A3 (en) * 1988-10-21 1991-05-29 Hoechst Celanese Corporation Copolymers of 4-hydroxystyrene and alkyl substituted-4-hydroxystyrene
EP0466359A2 (en) * 1990-06-29 1992-01-15 Hoechst Celanese Corporation Process for making low optical density polymers and copolymers for photoresists and optical applications
EP0466359A3 (en) * 1990-06-29 1992-07-01 Hoechst Celanese Corporation Process for making low optical density polymers and copolymers for photoresists and optical applications

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