GB948495A - Improvements in or relating to chelates of hydroxybenzoylacetones - Google Patents
Improvements in or relating to chelates of hydroxybenzoylacetonesInfo
- Publication number
- GB948495A GB948495A GB2740460A GB2740460A GB948495A GB 948495 A GB948495 A GB 948495A GB 2740460 A GB2740460 A GB 2740460A GB 2740460 A GB2740460 A GB 2740460A GB 948495 A GB948495 A GB 948495A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxyphenyl
- butandiono
- bis
- metal
- tris
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- DMHDAJCXNSEXEE-UHFFFAOYSA-N 2-hydroxy-1-phenylbutane-1,3-dione Chemical class CC(=O)C(O)C(=O)C1=CC=CC=C1 DMHDAJCXNSEXEE-UHFFFAOYSA-N 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 239000007983 Tris buffer Substances 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 229920001568 phenolic resin Polymers 0.000 abstract 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- -1 Al111 Proteins 0.000 abstract 2
- 102100034289 Deoxynucleoside triphosphate triphosphohydrolase SAMHD1 Human genes 0.000 abstract 2
- 101000641031 Homo sapiens Deoxynucleoside triphosphate triphosphohydrolase SAMHD1 Proteins 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 125000005594 diketone group Chemical group 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 229920000647 polyepoxide Polymers 0.000 abstract 2
- 229910000838 Al alloy Inorganic materials 0.000 abstract 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 1
- 101100448410 Mus musculus Gkn1 gene Proteins 0.000 abstract 1
- 125000005595 acetylacetonate group Chemical group 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract 1
- 239000013522 chelant Substances 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09J161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/92—Ketonic chelates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/70—Chelates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention comprises compounds of the general formula: <FORM:0948495/C2/1> wherein the 'R's are H or hydrocarbon groups, X is a metal atom or metal-containing complex which will form a stable chelate structure with diketones, and n is an integer 1-4; and specifically bis [1-(p-hydroxyphenyl)- 1, 3-butandiono] Cu11 and its Be11, Mg11 and Zn11 analogues tris [1-(p-hydroxyphenyl)- 1, 3-butandiono] Al111 tris [1-(p-hydroxyphenyl)- 1, 3-pentandiono] Cr111, bis [1-(31-methyl -41- hydroxyphenyl)- 1, 3-butandiono] Cu11 and tris [1-(p-hydroxyphenyl) -2- methyl- 1, 3-butandiono] Cr111. The compounds are prepared by reaction of the parent diketones with metal compounds which may be e.g. salts or acetylacetonates of Be11, Mg11, Al111, Ca11, Cr111, Mn111, Fe111, Co111, Ni11, Cu11, Zn11, Sr11, Ba11, ZrIV, Cd11, CeIV, Hg11, Pb11, ThIV, and complex ions including VIVO, VVIO2, MoVIO2, or Cu11(NH3)4. Specification 948,494 is referred to.ALSO:Adhesive compositions containing phenol-formaldehyde and/or epoxy resins and optionally e.g. superpolyamides and polyvinylformals are characterised by the presence of a compound of formula: <FORM:0948495/C3/1> wherein the 'R's are H or hydrocarbon groups, X is a metal atom or metal-containing complex or N is an integer 1-4 (see Division C2). In Example 9 an adhesive containing a phenol formaldehyde resin, aluminium powder a polyvinylformal, an epoxy resin prepared from 2,2-bis(p-hydroxyphenyl) propane, and epichlorohydrin, acetone and bis[1-(p-hydroxyphenyl)-1,3 - butandiono] copper (II) was used to impregnate a glass cloth prior to its application to bonding aluminium alloy sheets. The preparation of the phenol-formaldehyde resin is also described. Specification 948,494 is referred to.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2740460A GB948495A (en) | 1960-08-08 | 1960-08-08 | Improvements in or relating to chelates of hydroxybenzoylacetones |
| FR870275A FR1306023A (en) | 1960-08-08 | 1961-08-07 | Improvements relating to mono-, bis- and polyphenolic derivatives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2740460A GB948495A (en) | 1960-08-08 | 1960-08-08 | Improvements in or relating to chelates of hydroxybenzoylacetones |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB948495A true GB948495A (en) | 1964-02-05 |
Family
ID=10259025
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2740460A Expired GB948495A (en) | 1960-08-08 | 1960-08-08 | Improvements in or relating to chelates of hydroxybenzoylacetones |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB948495A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2149797A (en) * | 1982-08-09 | 1985-06-19 | Hitco | Epoxy resins containing zirconium |
| CN106467714A (en) * | 2015-08-18 | 2017-03-01 | 意禾新材料科技（常州）有限公司 | Sheet material production adhesive and apply this adhesive sheet material production method |
| CN106497466A (en) * | 2015-09-06 | 2017-03-15 | 意禾新材料科技（常州）有限公司 | Compact grade laminate production adhesive and the production method of compact grade laminate |
| CN106497467A (en) * | 2015-09-06 | 2017-03-15 | 意禾新材料科技（常州）有限公司 | Sheet material production adhesive and apply the adhesive sheet material production method |
-
1960
- 1960-08-08 GB GB2740460A patent/GB948495A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2149797A (en) * | 1982-08-09 | 1985-06-19 | Hitco | Epoxy resins containing zirconium |
| CN106467714A (en) * | 2015-08-18 | 2017-03-01 | 意禾新材料科技（常州）有限公司 | Sheet material production adhesive and apply this adhesive sheet material production method |
| CN106497466A (en) * | 2015-09-06 | 2017-03-15 | 意禾新材料科技（常州）有限公司 | Compact grade laminate production adhesive and the production method of compact grade laminate |
| CN106497467A (en) * | 2015-09-06 | 2017-03-15 | 意禾新材料科技（常州）有限公司 | Sheet material production adhesive and apply the adhesive sheet material production method |
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