GB945131A - Improvements in or relating to the production of aryl-substituted borazoles - Google Patents
Improvements in or relating to the production of aryl-substituted borazolesInfo
- Publication number
- GB945131A GB945131A GB1442162A GB1442162A GB945131A GB 945131 A GB945131 A GB 945131A GB 1442162 A GB1442162 A GB 1442162A GB 1442162 A GB1442162 A GB 1442162A GB 945131 A GB945131 A GB 945131A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solvent
- ethereal
- aryl
- reaction
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002904 solvent Substances 0.000 abstract 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 7
- 150000002430 hydrocarbons Chemical group 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 239000007818 Grignard reagent Substances 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 150000004795 grignard reagents Chemical class 0.000 abstract 2
- MXTYWYFDBAXRKR-UHFFFAOYSA-N 3,3,4,4,5,5-hexakis-phenylazaborole Chemical compound C1(=CC=CC=C1)C1(C(C(N=B1)(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)C1=CC=CC=C1 MXTYWYFDBAXRKR-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- BGECDVWSWDRFSP-UHFFFAOYSA-N borazine Chemical compound B1NBNBN1 BGECDVWSWDRFSP-UHFFFAOYSA-N 0.000 abstract 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Aryl-substituted borazoles are made by reacting a b -haloborazole, wherein any substituents other than halogen are hydrocarbon groups free from non-aromatic unsaturation, with a Grignard reagent in the presence of an ethereal solvent, the borazole starting material, the Grignard reagent, or both containing an aryl group, heating the product of the reaction in the presence of a substantially anhydrous hydrocarbon solvent of higher boiling point than the ethereal solvent so as to distill off the ethereal solvent. Suitable solvents include benzene, cyclohexane, toluene, n-heptane and xylene. Preferably 0.5 to 1 part of solvent is employed for each part by weight of ether, but larger amounts can be used. The hydrocarbon solvent can be added before or after the reaction but should be present prior to the removal of substantial amounts of the ether. Preferably the hydrocarbon solvent is continuously added to the reaction mass while the ethereal solvent is being removed. Suitable ethereal solvents are diethyl ether, tetrahydrofuran, diglyme and dioxam. Detailed examples give the preparation of b -triphenylborazole, b -triphenyl -N-trimethylborazole and hexaphenylborazole.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10764461A | 1961-05-04 | 1961-05-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB945131A true GB945131A (en) | 1963-12-23 |
Family
ID=22317672
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1442162A Expired GB945131A (en) | 1961-05-04 | 1962-04-13 | Improvements in or relating to the production of aryl-substituted borazoles |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB945131A (en) |
-
1962
- 1962-04-13 GB GB1442162A patent/GB945131A/en not_active Expired
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB740274A (en) | Process of preparing an alkyl or aryl tin compound | |
| GB945131A (en) | Improvements in or relating to the production of aryl-substituted borazoles | |
| GB813479A (en) | An improved process for preparing organotin compounds | |
| GB701714A (en) | Process of preparing alkyl or aryl tin compounds | |
| ES323157A1 (en) | A procedure for the preparation of omega-laurino-lactama, to start ciclododecanona. (Machine-translation by Google Translate, not legally binding) | |
| GB1104200A (en) | Method of preparing lithium borohydride | |
| GB820773A (en) | Process for the production of polyolefins | |
| GB755528A (en) | Improved dehydrogenation process | |
| GB982264A (en) | Manufacture of bicyclo-(3.2.1)-octene-(2) | |
| GB870415A (en) | A process for the manufacture of grignard reagents | |
| GB947780A (en) | Heterocyclic boron compounds and a process for their production | |
| GB997366A (en) | Improvements relating to alkyl lead compositions | |
| FR1166833A (en) | Process for preparing organic fluorinated compounds | |
| GB917749A (en) | Preparation of 2,6-di-t-alkylphenoxy boron dihalides | |
| GB853098A (en) | Preparation of alkyl borate esters | |
| GB949265A (en) | Method for preparing diboron tetrafluoride | |
| GB760062A (en) | Phenol extraction of aromatic hydrocarbons with the production of aromatic cyclic ethers | |
| GB942365A (en) | Preparation of organic borate esters | |
| GB531676A (en) | Improved process for the manufacture of refractory articles | |
| ES229918A1 (en) | Procedure for the preparation of carotenoids (Machine-translation by Google Translate, not legally binding) | |
| GB787615A (en) | Process for the allylation of benzene and homologous hydrocarbons | |
| GB938897A (en) | 4-methyl-steroids and process for their preparation | |
| GB854924A (en) | Process for the preparation of organodichloroboranes | |
| GB793135A (en) | Improvements in or relating to the production of aromatic hydrocarbons | |
| GB914243A (en) | Production of 1:4-epoxycyclohexane |