GB940197A - Synthetic elastomers - Google Patents
Synthetic elastomersInfo
- Publication number
- GB940197A GB940197A GB3446959A GB3446959A GB940197A GB 940197 A GB940197 A GB 940197A GB 3446959 A GB3446959 A GB 3446959A GB 3446959 A GB3446959 A GB 3446959A GB 940197 A GB940197 A GB 940197A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyethylene
- chlorosulphonated
- melt index
- sulphur content
- oct
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
- C08F8/38—Sulfohalogenation
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
940,197. Chlorosulphonated polyethylene. E.I. DU PONT DE NEMOURS & CO., Oct. 12, 1959 [Oct. 20, 1958], No. 34469/59. Addition to 847,164. Heading C3P. Rubber-like, chlorosulphonated polyethylene which is curable with metal oxides and which has a chlorine content of 38 to 48 % is prepared from polyethylene of density from 0À935 to 0À960 and of solubility in carbon tetrachloride of at least 1% by weight at 110-125 ‹C, by dissolving the polyethylene in a solvent such as carbon tetrachloride or tetrachloro-ethylene and homogeneously chlorosulphonating with chlorine and sulphur dioxide in admixture or separately and in order, the process being characterized in that either (A) the polyethylene is of #M w /#M n of at least 1 but not from 2 to 10 and is of melt index of from 0À2 to 200, and wherein the chlorosulphonated polyethylene has a sulphur content of from 0À1 to 3%, or (B) the polyethylene is of #M w /#M n of from 2 to 10 and either the polyethylene is of melt index of from 0À2 to 200, and wherein the chlorosulphonated polyethylene has a sulphur content of 0À1 up to but not including 0À7%, or the polyethylene is of melt index from 0À2 up to but not including 2À0 and wherein the chlorosulphonated polyethylene has a sulphur content of 0À1 to 3À0%. The polyethylene may be prepared as disclosed in Specification 639,306 or 682,420 or by the use of co-ordination catalysts derived from compounds of Group IV A , VA or VIA metals + organometallic compounds of Group I, II or III metals. The examples illustrate the compounding and curing of various chlorosulphonated polyethylenes with materials such as epichlorhydrin/propane-2, 2-bisphenol condensation product, hydrogenated rosin, titanium dioxide, magnesium oxide butyraldehyde/ aniline antioxidant, and dipentamethylene thiuram disulphide. Specifications 471,590, 542,414, 591,058, 804,535 and U.S.A. Specifications 2,586,363 and 2,592,814 also are referred to. Reference has been directed by the Comptroller to Specification 834,824.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US768030A US2982759A (en) | 1957-06-19 | 1958-10-20 | Synthetic elastomers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB940197A true GB940197A (en) | 1963-10-23 |
Family
ID=31496269
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3446959A Expired GB940197A (en) | 1958-10-20 | 1959-10-12 | Synthetic elastomers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB940197A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1595181A1 (en) * | 1964-11-20 | 1970-01-29 | Du Pont | Process for the chlorosulfonation of polyolefins |
EP0133294A1 (en) * | 1983-07-29 | 1985-02-20 | E.I. Du Pont De Nemours And Company | Chlorinated polyethylene elastomers |
GB2193965A (en) * | 1986-07-15 | 1988-02-24 | Toyo Soda Mfg Co Ltd | Chlorosulfonated polyethylene |
-
1959
- 1959-10-12 GB GB3446959A patent/GB940197A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1595181A1 (en) * | 1964-11-20 | 1970-01-29 | Du Pont | Process for the chlorosulfonation of polyolefins |
EP0133294A1 (en) * | 1983-07-29 | 1985-02-20 | E.I. Du Pont De Nemours And Company | Chlorinated polyethylene elastomers |
GB2193965A (en) * | 1986-07-15 | 1988-02-24 | Toyo Soda Mfg Co Ltd | Chlorosulfonated polyethylene |
US4897451A (en) * | 1986-07-15 | 1990-01-30 | Toyo Soda Manufacturing Co., Ltd. | Chlorosulfonated polyethylene |
GB2193965B (en) * | 1986-07-15 | 1990-04-25 | Toyo Soda Mfg Co Ltd | Chlorosulfonated polyethylene |
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