GB940197A - Synthetic elastomers - Google Patents

Synthetic elastomers

Info

Publication number
GB940197A
GB940197A GB3446959A GB3446959A GB940197A GB 940197 A GB940197 A GB 940197A GB 3446959 A GB3446959 A GB 3446959A GB 3446959 A GB3446959 A GB 3446959A GB 940197 A GB940197 A GB 940197A
Authority
GB
United Kingdom
Prior art keywords
polyethylene
chlorosulphonated
melt index
sulphur content
oct
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3446959A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US768030A external-priority patent/US2982759A/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB940197A publication Critical patent/GB940197A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/38—Sulfohalogenation

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

940,197. Chlorosulphonated polyethylene. E.I. DU PONT DE NEMOURS & CO., Oct. 12, 1959 [Oct. 20, 1958], No. 34469/59. Addition to 847,164. Heading C3P. Rubber-like, chlorosulphonated polyethylene which is curable with metal oxides and which has a chlorine content of 38 to 48 % is prepared from polyethylene of density from 0À935 to 0À960 and of solubility in carbon tetrachloride of at least 1% by weight at 110-125 ‹C, by dissolving the polyethylene in a solvent such as carbon tetrachloride or tetrachloro-ethylene and homogeneously chlorosulphonating with chlorine and sulphur dioxide in admixture or separately and in order, the process being characterized in that either (A) the polyethylene is of #M w /#M n of at least 1 but not from 2 to 10 and is of melt index of from 0À2 to 200, and wherein the chlorosulphonated polyethylene has a sulphur content of from 0À1 to 3%, or (B) the polyethylene is of #M w /#M n of from 2 to 10 and either the polyethylene is of melt index of from 0À2 to 200, and wherein the chlorosulphonated polyethylene has a sulphur content of 0À1 up to but not including 0À7%, or the polyethylene is of melt index from 0À2 up to but not including 2À0 and wherein the chlorosulphonated polyethylene has a sulphur content of 0À1 to 3À0%. The polyethylene may be prepared as disclosed in Specification 639,306 or 682,420 or by the use of co-ordination catalysts derived from compounds of Group IV A , VA or VIA metals + organometallic compounds of Group I, II or III metals. The examples illustrate the compounding and curing of various chlorosulphonated polyethylenes with materials such as epichlorhydrin/propane-2, 2-bisphenol condensation product, hydrogenated rosin, titanium dioxide, magnesium oxide butyraldehyde/ aniline antioxidant, and dipentamethylene thiuram disulphide. Specifications 471,590, 542,414, 591,058, 804,535 and U.S.A. Specifications 2,586,363 and 2,592,814 also are referred to. Reference has been directed by the Comptroller to Specification 834,824.
GB3446959A 1958-10-20 1959-10-12 Synthetic elastomers Expired GB940197A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US768030A US2982759A (en) 1957-06-19 1958-10-20 Synthetic elastomers

Publications (1)

Publication Number Publication Date
GB940197A true GB940197A (en) 1963-10-23

Family

ID=31496269

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3446959A Expired GB940197A (en) 1958-10-20 1959-10-12 Synthetic elastomers

Country Status (1)

Country Link
GB (1) GB940197A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1595181A1 (en) * 1964-11-20 1970-01-29 Du Pont Process for the chlorosulfonation of polyolefins
EP0133294A1 (en) * 1983-07-29 1985-02-20 E.I. Du Pont De Nemours And Company Chlorinated polyethylene elastomers
GB2193965A (en) * 1986-07-15 1988-02-24 Toyo Soda Mfg Co Ltd Chlorosulfonated polyethylene

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1595181A1 (en) * 1964-11-20 1970-01-29 Du Pont Process for the chlorosulfonation of polyolefins
EP0133294A1 (en) * 1983-07-29 1985-02-20 E.I. Du Pont De Nemours And Company Chlorinated polyethylene elastomers
GB2193965A (en) * 1986-07-15 1988-02-24 Toyo Soda Mfg Co Ltd Chlorosulfonated polyethylene
US4897451A (en) * 1986-07-15 1990-01-30 Toyo Soda Manufacturing Co., Ltd. Chlorosulfonated polyethylene
GB2193965B (en) * 1986-07-15 1990-04-25 Toyo Soda Mfg Co Ltd Chlorosulfonated polyethylene

Similar Documents

Publication Publication Date Title
GB831754A (en) Production of preforms and longitudinally curved articles of polytetrafluoroethyleneresin
GB940197A (en) Synthetic elastomers
NL96379C (en)
GB809732A (en) Improvements in manufacture of n-alkyl-and n-cycloalkylbis-(2-benzothiazolesulphen)amides
GB974564A (en) Improvements in or relating to closures
ES442261A1 (en) Process for the preparation of halogenoanthraquinones
GB847164A (en) Synthetic elastomers
GB1475670A (en) 3,3,4,4-tetrachlorotetrahydrothiophene-1,1-dioxide compositions
GB1004142A (en) Improvements in or relating to metal powders and articles formed therefrom
GB1104780A (en) Decomposition of ilmenite
GB982753A (en) Improvements in and relating to polyolefine compositions
GB1050101A (en)
GB851778A (en) Improvements in alloy addition mixtures
GB1273914A (en) Process for the production of fluorinated nitrogen heterocycles
JPS5248410A (en) Operators misoperation preventing system
GB1378105A (en) Production of propylene
GB1013309A (en) Improvements in and relating to the manufacture of aluminium organic compounds
GB811777A (en) Plasticised linear polyethylene
ES267799A1 (en) Vulcanization bonding of olefin copolymers
ATE10652T1 (en) HIGH STRENGTH AUTOMATIC STEEL RESISTANT TO DYNAMIC STRESSES.
GB905668A (en) Improvements in and relating to filamentary products
GB815086A (en) Chlorinated polyethylene
GB761362A (en) Improvements in or relating to lubricants
GB1226145A (en)
GB1163278A (en) Process for the Stabilization of Polymers and Co-Polymers of Vinyl Chloride