GB930093A - Improvements in and relating to catalysts - Google Patents

Improvements in and relating to catalysts

Info

Publication number
GB930093A
GB930093A GB3273860A GB3273860A GB930093A GB 930093 A GB930093 A GB 930093A GB 3273860 A GB3273860 A GB 3273860A GB 3273860 A GB3273860 A GB 3273860A GB 930093 A GB930093 A GB 930093A
Authority
GB
United Kingdom
Prior art keywords
catalyst
oxides
olefines
hydration
butene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3273860A
Inventor
George Walter Bridger
John Walton Marshall
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL269502D priority Critical patent/NL269502A/xx
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3273860A priority patent/GB930093A/en
Priority to DEJ20561A priority patent/DE1202254B/en
Publication of GB930093A publication Critical patent/GB930093A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

A catalyst comprising P.T.F.E. and (1) one or more copper oxides with one or more chromium oxides, or (2) tungsten oxide is used in the hydration of olefines. The P.T.F.E. may form 1-5% of the catalyst and have a molecular weight of 500,000-5,000,000. The metallic oxides may be introduced into the catalyst by way of precursors, e.g. H2WO4, Cu(NO3)2 an H2CrO4. Examples are given.ALSO:Olefines, e.g. ethylene, propylene, butenes, pentenes, hexenes, heptenes, octenes, and nonenes are hydrated to corresponding alcohols by using a catalyst comprising P.T.F.E. (polytetrafluoroethylene) and one or more copper oxides with one or more chromium oxides or tungsten oxide. In examples propylene is hydrated to isopropanol using P.T.F.E. and WO3 pellets at 250 DEG C. and 250 atmospheres. The hydration of butene-1 and butene-2 to sec. butanol is also described.
GB3273860A 1960-09-23 1960-09-23 Improvements in and relating to catalysts Expired GB930093A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
NL269502D NL269502A (en) 1960-09-23
GB3273860A GB930093A (en) 1960-09-23 1960-09-23 Improvements in and relating to catalysts
DEJ20561A DE1202254B (en) 1960-09-23 1961-09-19 Process for the preparation of a catalyst for the addition of water to olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB3273860A GB930093A (en) 1960-09-23 1960-09-23 Improvements in and relating to catalysts
GB544561 1961-02-14

Publications (1)

Publication Number Publication Date
GB930093A true GB930093A (en) 1963-07-03

Family

ID=26239891

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3273860A Expired GB930093A (en) 1960-09-23 1960-09-23 Improvements in and relating to catalysts

Country Status (3)

Country Link
DE (1) DE1202254B (en)
GB (1) GB930093A (en)
NL (1) NL269502A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2466280A1 (en) * 1979-10-04 1981-04-10 Pennwalt Corp PACKAGED CATALYST COMPRISING A RESIN BINDER FOR THE DECOMPOSITION OF HYPOCHLORITE AND METHOD OF USE
USRE32392E (en) * 1979-10-04 1987-04-07 Pennwalt Corporation Catalyst pellets with resin binder for decomposition of hypochlorite
US4865760A (en) * 1988-04-06 1989-09-12 Ppg Industries, Inc. Calcium hypochlorite composition
US4970020A (en) * 1988-04-06 1990-11-13 Ppg Industries, Inc. Calcium hypochlorite composition
US5009806A (en) * 1988-04-06 1991-04-23 Ppg Industries, Inc. Calcium hypochlorite article
US5205961A (en) * 1991-04-18 1993-04-27 Ppg Industries, Inc. Granular calcium hypochlorite treatment process
US8558036B2 (en) 2010-11-15 2013-10-15 Saudi Arabian Oil Company Dual phase catalysts system for mixed olefin hydrations

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2466280A1 (en) * 1979-10-04 1981-04-10 Pennwalt Corp PACKAGED CATALYST COMPRISING A RESIN BINDER FOR THE DECOMPOSITION OF HYPOCHLORITE AND METHOD OF USE
USRE32392E (en) * 1979-10-04 1987-04-07 Pennwalt Corporation Catalyst pellets with resin binder for decomposition of hypochlorite
US4865760A (en) * 1988-04-06 1989-09-12 Ppg Industries, Inc. Calcium hypochlorite composition
US4970020A (en) * 1988-04-06 1990-11-13 Ppg Industries, Inc. Calcium hypochlorite composition
US5009806A (en) * 1988-04-06 1991-04-23 Ppg Industries, Inc. Calcium hypochlorite article
US5205961A (en) * 1991-04-18 1993-04-27 Ppg Industries, Inc. Granular calcium hypochlorite treatment process
US8558036B2 (en) 2010-11-15 2013-10-15 Saudi Arabian Oil Company Dual phase catalysts system for mixed olefin hydrations
US8865951B2 (en) 2010-11-15 2014-10-21 Saudi Arabian Oil Company Dual phase catalysts system for mixed olefin hydrations
US9056315B2 (en) 2010-11-15 2015-06-16 Saudi Arabian Oil Company Dual phase catalysts system for mixed olefin hydrations

Also Published As

Publication number Publication date
NL269502A (en)
DE1202254B (en) 1965-10-07

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